微通道SERS器件的制备及对有害化学品的检测

在微通道内表面通过化学吸附组装上银纳米粒子制成了微通道表面增强拉曼散射(SERS)器件,其对常见探针分子罗丹明6G(R6G)和4-巯基吡啶(4-MPY)的最低检测浓度分别达到10-11和10-8mol/L,说明其具有很好的增强效果.用该器件对2种有害化学药品进行了检测,三聚氰胺的最低检测浓度可到10-6mol/L,而福美双的最低检测浓度可达到10-7mol/L,说明所制备的微通道器件可用于对有害化学品的检测.微通道SERS器件具有体积小、取样少、制备简单、能够进行现场实时动态检测等特点,具有广阔的应用前景.     

碳纳米管修饰电极分子印迹传感器快速测定沙丁胺醇

以单壁碳纳米管(SWNTs)为电极材料,应用分子印迹技术,以邻苯二胺为功能单体、沙丁胺醇为模板,采用电化学聚合法制备了一种新型的快速检测沙丁胺醇分子印迹传感器,并运用电化学方法去除模板.在磷酸盐缓冲溶液(PBS)中,利用线性溶出伏安法对印迹和非印迹膜的性能进行了比较,对分子印迹膜的影响因素进行了优化.实验表明,本传感器...     

求解CPM网络计划的最大网络时差

CPM网络计划的网络时差表示项目中各工序实际可使用的机动时间的总和(绝非理论上机动时间的简单加总),即CPM网络计划的总机动时间,它决定着在总工期不变的前提下,所有工序实际可以达到的最大工期的总和,与项目的成本管理和时间管理密切相关。网络时差是变量,取决于各工序的时间进度安排,说明可以通过调整工序的时间进度来决定该时差的取值,特别是其最大值,进而实现成本和时间优化。本文首先从新的角度分析了网络时差的含义;然后,在此基础上设计了求解最大网络时差的算法,其思路为,通过建立和分析最大网络时差模型,将其转化为特殊的“时间-费用权衡问题”,进而可运用Fulkerson算法等经典算法求解;最后,通过应用举例对该算法进行了演示。     

Tensor Bernstein concentration inequalities with an application to sample estimators for high-order moments

This paper develops the Bernstein tensor concentration inequality for random tensors of general order,based on the use of Einstein products for tensors.This establishes a strong link between these and matrices,which in turn allows exploitation of existing results for the latter.An interesting application to sample estimators of high-order moments is presented as an illustration.     

贝纳德对流产生的温差条件

在Boussinesq近似的基础上,忽略贝纳德对流扰动方程二阶和更高阶的扰动,建立速度场和温度场的扰动方程.通过无量纲处理得到控制贝纳德对流的超越方程,利用MATLAB求解超越方程,得到实验室产生贝纳德对流的参数,为贝纳德对流实验提供参考和指导.     

同步双转镜调Q激光器

用双转镜装置这种最简单、有效的方法，实现了调Q激光输出，得到了平缓、光滑的脉冲，大大改善了以往转镜调Q激光器的不足。     

The Characterization of Comblike Polymer Electrolyte by Means of NMR

Polymer solid electrolytes are a class of solid materials whose properties lie betweenthose of solids and liquids, and they have been widely used in energy resources,. metallurgy, environmental protection, electro-chemistry device and so on' '2.Inoue had pointed out that polystyrene derivative with many poly (ethylene oxide)PEO side chain could make conductivity reach 10-' S/cm. They think that the flexibilityo f the backbone is not necessarily the impoFtant factor to achieve a high conducti…     

基于核磁共振代谢组学技术比较不同产地铁棍山药的化学成分差异

该研究阐明了不同产地铁棍山药中化学成分的差异,为道地山药的产地鉴别提供了理论依据。利用核磁共振氢谱（1H NMR）对铁棍山药进行分析,指认、归属了图谱中的30种主要代谢物后,通过主成分分析（PCA）、正交偏最小二乘法判别分析（OPLS－DA）对7种不同产地铁棍山药中的化学成分进行了比较。结果显示,温县垆土山药中精氨酸的含量最高,蔗糖含量最低,孟州垆土山药中苏氨酸、谷氨酰胺的含量最高;温县沙土山药的丙氨酸和苹果酸含量最高,武陟沙土山药的尿囊素含量最高;沙土地的铁棍山药中2-羟基异丁酸的含量均高于垆土地山药。7种铁棍山药葡萄糖和果糖的变量重要性投影（VIP）均小于1.0,并不是主要成分。液相色谱检测蔗糖、柠檬酸、苹果酸的结果与OPLS－DA载荷图结果一致;7种铁棍山药的葡萄糖和果糖含量均低于液相色谱检出限（2.0 mg/g）,表明可以利用葡萄糖、果糖的含量和葡萄糖显色试剂鉴别铁棍山药是否为道地怀山药。     

一类无界三对角型算子矩阵的谱估计*

本文研究了一类 n × n阶无界三对角型对角占优算子矩阵的可闭 (闭) 性和谱估计问题.首先通过分析算子矩阵内部元素之间的关系, 给出了该类算子矩阵可闭 (闭)的一个充分条件, 并在此基础上利用 Schur 补刻画了其谱的范围.最后将所得结果应用于量子力学中的三通道 Hamilton 算子矩阵中,说明了结果的合理性.     

Passive source range estimation with a single receiver in shallow water

An approach for long-range passive impulsive source ranging with a single receiver in shallow water is proposed,which utilizes the frequency spectrum of the warped signal autocorrelation function via warping transform.For an ideal waveguide,there are invariable frequency features both in the frequency spectrum of the warped signal corresponding to modal cut-off frequencies and the warped signal autocorrelation function due to modal interference.These intrinsic frequency features can be used to passive source ranging.So,the approximate relationship between the frequency of warped signal at an unknown source range and the intrinsic frequency extracted by the time warping transform is derived.These rules can be generalized to an actual shallow water waveguide.Employing an acoustic model to offer the invariable frequency spectrum features,the impulsive signal data collected by a single hydrophone in the North Yellow Sea in December 2011 are analyzed to verify the proposed source ranging approach.The estimated ranges are in good agreement with the ranges measured by GPS,and the mean relative error of range estimation is less than 10%.