全文获取类型
收费全文 | 1749篇 |
免费 | 25篇 |
国内免费 | 2篇 |
专业分类
化学 | 1135篇 |
晶体学 | 11篇 |
力学 | 24篇 |
数学 | 310篇 |
物理学 | 296篇 |
出版年
2022年 | 20篇 |
2021年 | 15篇 |
2020年 | 17篇 |
2019年 | 21篇 |
2018年 | 21篇 |
2017年 | 30篇 |
2016年 | 24篇 |
2015年 | 18篇 |
2014年 | 38篇 |
2013年 | 94篇 |
2012年 | 92篇 |
2011年 | 85篇 |
2010年 | 54篇 |
2009年 | 57篇 |
2008年 | 114篇 |
2007年 | 92篇 |
2006年 | 84篇 |
2005年 | 72篇 |
2004年 | 70篇 |
2003年 | 47篇 |
2002年 | 55篇 |
2001年 | 23篇 |
2000年 | 18篇 |
1999年 | 12篇 |
1997年 | 14篇 |
1996年 | 26篇 |
1995年 | 18篇 |
1994年 | 22篇 |
1993年 | 17篇 |
1992年 | 22篇 |
1991年 | 13篇 |
1990年 | 15篇 |
1989年 | 19篇 |
1988年 | 24篇 |
1987年 | 21篇 |
1986年 | 10篇 |
1985年 | 31篇 |
1984年 | 34篇 |
1983年 | 22篇 |
1982年 | 38篇 |
1981年 | 29篇 |
1980年 | 23篇 |
1979年 | 19篇 |
1978年 | 28篇 |
1977年 | 18篇 |
1976年 | 21篇 |
1974年 | 15篇 |
1973年 | 30篇 |
1972年 | 13篇 |
1971年 | 12篇 |
排序方式: 共有1776条查询结果,搜索用时 0 毫秒
111.
Ester Abtew Abraham J. Domb Arijit Basu 《Journal of polymer science. Part A, Polymer chemistry》2017,55(16):2657-2662
We report on the synthesis of polypeptides with saccharide side chains starting from d ‐glucosaminic acid. The hydroxyl groups were first protected by benzylation, followed by N‐carboxyanhydride formation, which was polymerized by ring opening to form a high molecular weight polyamide. De‐protection of the benzyl groups yields a polypeptide with fully de‐protected saccharide side chains. The resulting new non‐ionic, water soluble, and optically active polymers possessing the properties of both peptides and saccharides have potential use as scaffolds for tissue engineering and drug carriers. The method described here may be extended to any saccharide α‐amino acid. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 2657–2662 相似文献
112.
Yixuan Xie Chao Peng Yunyi Gao Xiaohong Liu Tianbo Liu Abraham Joy 《Journal of polymer science. Part A, Polymer chemistry》2017,55(23):3908-3917
Glycopolymers have been widely used to understand the interactions between carbohydrates and lectins, which facilitate the diagnosis and detection of disease and pathogens as well as the development of vaccines. While studies have been focused on the correlation of glycopolymer structure and their binding to lectins, graft‐type glycopolyesters are uncommon. Herein, we report the design and synthesis of mannose‐based graft polyesters by “grafting‐from” method and investigate their interactions with Concanavalin A (Con A). As confirmed by 1H NMR spectroscopy and sulfuric acid‐UV method, graft polyesters with different lengths of mannose graft were successfully synthesized. Our results from turbidimetry binding assay showed that graft polyesters with longer mannose graft exhibit higher initial binding rate (ki). Isothermal titration calorimetry measurements of these graft polyesters with Con A showed that polymers exhibit higher binding affinity (ka) with the number of side chain mannose. This study provides understanding of the interaction between Con A and mannose‐based graft polyesters, which can be employed for the development of glycopolymeric therapeutics. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 3908–3917 相似文献
113.
A one-dimensional approximate analytical model, which preserves the main features of soil-crop-atmospheric hydrodynamics,
has been suggested for plant roots of low soil-root conductivity ratio (SRCR). The proposed approach involves physically based
concepts, such as mass balance equation, Darcy’s law, and related water uptake and plant transpiration functions. Two main
assumptions have been made to derive the analytical solution: (1) gravitational flow is adopted and (2) the uniform soil moisture
distribution within the root water activity zone is supposed. The mass balance equation in its integral form is solved by
the method of characteristics. This leads to the two functional equations for soil pressure head and root potential, which
can be solved simultaneously by using common software. The model has been further verified against the numerical one. The
model represents a reasonable compromise between the complicated mechanism of unsaturated water flow with root water uptake
(RWU) and still insufficient knowledge of the soil-plant-atmospheric continuum. It is able to account for temporal fluctuations
in root activity zone and provides a relatively simple algorithm for investigation of RWU-mechanism. Besides the theoretical
and applicative importance, this flow model yields water and velocity distributions within soil profile, and, thereby, constitutes
a preliminary step toward solution of contaminant transport problems in vadose zone.
Deceased 相似文献
114.
115.
116.
Reaction of N,N'-bis(phosphonomethyl)-1,10-diaza-18-crown-6 (H(4)L) with copper(II) acetate in 1:1 ethanol/water mixed solvents afforded a new crystal-engineered supramolecular metal phosphonate, Cu(H(2)L) (complex 1). By reaction of the same ligand with cadmium(II) nitrate in a 2:1 (M/L) ratio in methanol, a cadmium(II) complex with a 3D network structure was isolated, Cd(2.75)(L)(H(2)O)(7) x 1.5NO(3) x 7H(2)O x MeOH (complex 2). The copper(II) complex crystallized in the monoclinic space group P2(1)/c, with a =10.125(4), b = 14.103(6), and c = 14.537(6) A, beta = 91.049(8) degrees, V = 2075.4(16) A(3), and Z = 2. The Cu(II) ions in complex 1 are 6-coordinated by two phosphonate oxygen atoms, two nitrogen, and two oxygen atoms from the crown ether ring. Their coordination geometry can be described as Jahn-Teller-distorted octahedral, with elongated Cu-O(crown) distances (2.634(4) and 2.671(4) A for Cu(1) and Cu(2), respectively). The other two crown oxygen atoms remain uncoordinated. Neighboring two Cu(H(2)L) units are further interlinked via a pair of strong hydrogen bonds between uncoordinated phosphonate oxygen atoms, resulting in a one-dimensional supramolecular array along the a axis. The cadmium(II) complex is tetragonal, P4(2)/n (No. 86) with a = 20.8150(9) and c = 18.5846(12) A, V = 8052.0(7) A(3), and Z = 8. Among four cadmium(II) atoms in an asymmetric unit, one is 8-coordinated by four chelating phosphonate groups, the second one is 8-coordinated by 6 coordination atoms from a crown ring and two oxygen atoms from two phosphonate groups, the third Cd(II) atom is octahedrally coordinated by three aqua ligands and three phosphonate oxygen atoms from three phosphonate groups, and the fourth one is 6-coordinated by four aqua ligands and two oxygen atoms from two phosphonate groups in a distorted octahedral geometry. These cadmium atoms are interconnected by bridging phosphonate tetrahedra in such a way as to form large channels along the c direction, in which the lattice water molecules, methanol solvent, and nitrate anions reside. The effect of extent of deprotonation of phosphonic acids on the type of complex formed is also discussed. 相似文献
117.
Langlet A Latypov NV Wellmar U Bemm U Goede P Bergman J Romero I 《The Journal of organic chemistry》2002,67(22):7833-7838
Nitration of some 2-substituted pyrimidine-4,6-diones in sulfuric acid was studied, which afforded previously unknown 5,5-gem-dinitropyrimidine-4,6-diones in high yields. The gem-dinitro products were easily attacked by nucleophiles with concomitant formation of gem-dinitroacetyl derivatives, which in turn could be further hydrolyzed to salts of dinitromethane and triureas. 相似文献
118.
119.
Equations for the solubility of gases and vapours into dry alcohols from methanol to decan‐1‐ol and into water‐saturated alcohols from butan‐1‐ol to decan‐1‐ol have been compared through the use of the Abraham solvation equation. It is shown that there are noticeable differences in solvation into the dry and wet alcohols, and that these differences become larger as the alcohols become smaller and take up more water. The two main factors that lead to the differences in solvation are the solute hydrogen‐bond basicity, B, and solute size, L. Increase in solute hydrogen‐bond basicity favours the wet alcohols and increase in solute size favours the dry alcohols. Solute hydrogen‐bond acidity plays no part, because the hydrogen‐bond basicity of water, wet alcohols and dry alcohols is almost the same. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
120.