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31.
Development of a 100 MeV CW proton LINAC has been planned at CAT. This LINAC will be needing CW rf power in the frequency
ranges of 350 MHz and 700 MHz for its RFQ and DTL/CCDTL/SFDTL structures respectively. The power to the accelerating structures
will be produced by either 1 MW CW or 250 kW CW klystrons/inductive output tubes (HOM IOTs). The power needed by respective
feed points in the structure is max. 250 kW which will be powered by splitting the power from 1 MW klystron/klystrode into
four channels by using a wave-guide system. In case of using 250 kW tubes the power to the structures will be provided directly
from each tube. Two types of wave-guide transmission system have been considered, viz, WR 2300 for 350 MHz rf needs and WR
1500 for 700 MHz rf needs. The typical wave-guide system has been designed using the 1 MW CW klystron followed by wave-guide
filter, dual directional coupler, high-power circulator, three 3 dB magic TEE power dividers to split the main channel into
four equal channels of 250 kW each. Each individual channel has dual directional couplers, flexible wave-guide sections and
high power ceramic vacuum window. The circulator and each power divider is terminated into the isolated ports by high power
CW loads. Out of the four channels three channels have phase shifters. Present paper describes the technological aspects and
design specifications-considerations for these stringent requirements. 相似文献
32.
Dhruba Gupta C Samanta R Kanungo P Basu Subinit Roy S Kailas A Chatterjee B J Roy K Mahata A Samant A Shrivastava 《Pramana》2001,57(1):209-213
Inclusive cross sections of α particles and tritons from the breakup of 42 MeV 7Li by 12C and 197Au targets are presented and analysed in the framework of the Serber model. Spectral distortions due to the targets and relevant
reaction mechanisms are discussed. 相似文献
33.
Spectroscopic studies on the mode of interaction of an anticancer drug with bovine serum albumin 总被引:3,自引:0,他引:3
The mechanism of interaction of vinblastin sulphate (VBS) with bovine serum albumin (BSA) has been reported. Association constant for VBS-BSA binding was found to be 3.146+/-0.06 x 10(4) M(-1). Stern-Volmer analysis of fluorescence quenching data showed that the fraction of fluorophore (protein) accessible to the quencher (drug) was close to unity indicating thereby that both tryptophan residues of BSA are involved in drug-protein interaction. The rate constant for quenching, greater than 10(10) M(-1) S(-1), indicated that the drug-binding site is in close proximity to tryptophan residues of BSA. Binding studies in the presence of an hydrophobic probe, 8-anilino-1-naphthalein-sulphonic acid, sodium salt (ANS) indicated that there is hydrophobic interaction between VBS and probe and they do not share common sites in BSA. Thermodynamic parameters obtained from data at different temperatures showed that the binding of VBS to BSA involves predominant hydrophobic forces. The effects of some additives and paracetamol on binding of VBS-BSA have also been investigated. The CD spectrum of BSA in presence of VBS shows that the binding of VBS leads to change in the helicity of BSA. 相似文献
34.
The results of measurements of substituent induced chemical shifts of carboxyl carbons (deltaCO) of dichloro- and difluorobenzoic acids, including the monosubstituted ones with substituents at meta- and/or ortho- positions, in chloroform-d and strengths of these acids (log K) in chlorobenzene show an anomalous reverse trend between deltaCO and log K, while the electron density at carboxyl carbons should influence similarly both deltaCO and log K. A detailed chemometric analysis of comparison of disubstituent effects between deltaCO and log K on the basis of Fujita-Nishioka's multiparameter approach and assumption of additivity of substituent effects shows a dominance of the localized pi-polarization mechanism relative to simple electrostatic effects upon deltaCO. Further, steric factors play a significant role in determining deltaCO whereas with respect to log K they were insignificant. The overall anomaly has been rationalized keeping in mind that, while log K is a gross measure of energy differences between the ionized and unionized forms of the acids, deltaCO is a very sensitive probe for determining changes in electron density at the carboxyl carbon of the unionized acid. 相似文献
35.
Superconducting and magnetically long-range ordered states were believed to be mutually exclusive phenomena. The discovery of rare-earth compounds in recent years, which exhibit both superconductivity and magnetic ordering (ferromagnetic, antiferromagnetic or sinusoidal), has led to considerable theoretical and experimental work on such systems.In the present article, we give a review of various theoretical models and important experimental results. In the theoretical sections, we start with the Abrikosov-Gorkov pair breaking theory for dilute alloys and discuss its improvement in the work of Müller-Hartmann and Zittartz. Then, in the context of magnetic superconductors, various microscopic theories that have been advanced are presented. These predict re-entrant behaviour in some systems (ferromagnetic superconductors) and coexistence regions in others (particularly antiferromagnetic superconductors). Following this, phenomenological generalized Ginzburg-Landau theories for two kinds of orders (superconducting and magnetic) are presented. A section dealing with renormalization group analysis of phase diagrams in magnetic superconductors is given.In experimental sections, the properties of each rare-earth compounds (ternary as well as some tetranery) are reviewed. These involve susceptibility, heat capacity, resistivity, upper critical field, neutron scattering and magnetic resonance measurements. The anomalous behaviour of the upper critical field of antiferromagnetic superconductors near the Néel temperature is discussed both in theory sections and experimental section for various systems. 相似文献
36.
37.
The electron spin resonance spectra of Mn2+ in NaCl single crystals are investigated in detail. Seven different spectra (I, II, III1, III2, IV, V and VI) are observed. The spectra I–IV are the same as those observed by earlier workers, while the spectra V and VI are observed here for the first time. The local symmetry at the paramagnetic ion is orthorhombic for the spectra IV and V and tetragonal for the spectrum VI about the crystallographic [001] direction. The properties of the spectrum IV are explained in terms of an associated pair Mn2+: O2 2? with O2 2? molecular ion at the nearest neighbour anion site in the [001] direction with its internuclear axis in the (001) plane. The spectrum V is assigned to the associated pair Mn2+: O2 2? coupled with a nearby cation vacancy in the [001] direction and the spectrum VI to Mn2+ ion associated with OH? ion at the anion site in the [001] direction with a probable second neighbour cation vacancy. All the observed spectra are analysed in terms of the parameters of the usual spin-Hamiltonian. 相似文献
38.
The dependence of mechanoluminescence in rochelle-salt crystals on the charge-produced during their fracture is found to be linear up to the applied stress of 344 kg/cm2. This fact is discussed on the basis of the instability of cracks in a crystal and it is concluded that the new surfaces created by mobile cracks are responsible for the appearance of mechanoluminescence in rochelle-salt crystals. 相似文献
39.
Shridhar R. Gadre Savita S. Pundlik Indira H. Shrivastava 《Journal of Chemical Sciences》1994,106(2):303-314
The conventional electrostatic charge models (PD-AC) are constructed so as to reproduce the molecular electrostatic potential
(MESP) on and beyond the van der Waals’ (vdW) surface. The MESP distribution has recently [S R Gadre, S A Kulkarni and I H
Shrivastava (1992)J. Chem. Phys.
96 5253] been shown to exhibit rich topographical features. With this in view, a detailed topographical comparison of the MESP
derived from the charge models, with the respectiveab initio (MO) ones is taken up for water, hydrogen sulphide, methane and benzene molecules as test cases. It is shown that the point
charge models have a fundamental lacuna, viz. they fail to mimic the essential topographical features of MESP. A new model
incorporating a small number of floating spherical Gaussians is shown to restore all the critical features of the molecules
under study. A comparative study of the standard deviations of MESP derived from charge models on scaled vdW surfaces further
reveals that the present model leads to a better representation ofab initio MESP. 相似文献
40.
The von Mises equivalent strain increment is derived for the case of large strain simple shear (torsion testing). This is used, in conjunction with the von Mises yield surface, to define the von Mises equivalent stress as well as the incremental work per unit volume. Integration of the equivalent strain increment leads to the definition of the von Mises equivalent strain for torsion. The Hencky equivalent strain increment is derived from the Hencky strain defined as the logarithm of the semi major and minor axes of the strain ellipse. This is then used, via the incremental work, to derive the ‘Hencky equivalent stress’. In the Onaka approach, the numerical values of the principal strain increments were integrated without taking into account the continuous rotation of the strain ellipse. This invalid operation leads to an expression for the equivalent strain increment that cannot be applied to the large strains considered by Onaka. Using the correct increments of the Hencky strain, it is shown that the shear strain increments turn negative and consequently, the incremental work becomes negative when the shear is large. 相似文献