The first example of palladium catalysed non-perfectly alternating copolymerisation of ethene and carbon monoxide

Non-alternating ethene-CO copolymerisation is catalysed by a new series of [P-O]Pd catalysts based on o-alkoxy derivatives of diphenylphosphinobenzene sulfonic acid.     

Stable ergodicity and julienne quasi-conformality

In this paper we dramatically expand the domain of known stably ergodic, partially hyperbolic dynamical systems. For example, all partially hyperbolic affine diffeomorphisms of compact homogeneous spaces which have the accessibility property are stably ergodic. Our main tools are the new concepts – julienne density point and julienne quasi-conformality of the stable and unstable holonomy maps. Julienne quasi-conformal holonomy maps preserve all julienne density points. Received June 14, 1999 / final version received October 25, 1999     

A one-pot oxidation/allylation/oxidation sequence for the preparation of β,γ-unsaturated ketones directly from primary alcohols

A one-pot oxidation/allylation/oxidation procedure has been developed for the conversion of primary alcohols into β,γ-unsaturated ketones. The methodology has been applied to a range of alcohols, and in some cases, isomerisation to produce the corresponding α,β-unsaturated ketones has been carried out.     

The C1 Connecting Lemma

Given a smooth flow and two orbits such that theω-limit set of the first meets theα-limit set of the second, can the flow be C¹-perturbed to make the orbits coincide? The answer is shown to be “not always.”     

Breakfast cereal sampling study for nutritional elements

The National Institute of Standards and Technology (NIST) has established a Dietary Supplement Laboratory Quality Assurance Program (DSQAP) in collaboration with the National Institutes of Health Office of Dietary Supplements (NIH-ODS). The DSQAP invites laboratories twice annually to participate in interlaboratory studies where participants elect to measure concentrations of nutritional and/or toxic elements as well as active and/or marker compounds. One of these studies was designed to determine the effects of material granularity and sample processing techniques on measurement variability (precision) as well as to provide participating laboratories information on their performance relative to the NIST assigned values (bias) and to the other participants (concordance). Participants were asked to determine the mass fractions of Ca, Fe, and Zn, in mg/kg, in six breakfast cereal samples. Cereal samples consisted of three ground materials (homogenized wheat, wheat, and rice), two flake materials (wheat and rice) and a partially crushed material (a wheat/rice mixture). In general, approximately 25 % of the laboratories processed and analyzed the suite of six cereal materials with adequate to exemplary measurement precision. Over half of the laboratories (60 %) experienced measurement issues related to only a particular type of cereal matrix or for only a single element. A small number (15 %) of laboratories experienced significant sample processing or measurement problems. Future studies planned by the DSQAP may be designed to use commercial products to aid laboratories with their sampling and analytical techniques.

Synthesis,isolation, and thermal behavior of polybutadiene grafted with poly(2,3,4,5,6‐pentafluorostyrene)

2,3,4,5,6‐Pentafluorostyrene (PFS) was copolymerized with polybutadiene (PB) in tetrahydrofuran using benzoyl peroxide as the initiator at 50, 60, and 80 °C. The copolymerizations follow typical radical polymerization kinetics and behavior. The grafting parameters were evaluated as a function of monomer conversion, initiator concentration, and/or temperature by gel permeation chromatography of directly injected copolymerization mixtures. The grafting efficiencies and grafting ratios are most consistent with a system that terminates by combination and whose graft sites are generated by hydrogen abstraction of allylic radicals by primary initiator radicals. Pure graft copolymers were isolated by extracting unreacted PB into hexanes and PPFS homopolymer into acetone. The similarity of the glass transition temperatures of the PPFS grafts and the corresponding extracted PPFS homopolymers confirms that their lengths are approximately equal. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 2874–2891, 2005     

Experimentelle Bestätigung einer selektiven Koagulation in gemischten kolloidalen Suspensionen

Colloid and Polymer Science -