全文获取类型
收费全文 | 544篇 |
免费 | 30篇 |
国内免费 | 6篇 |
专业分类
化学 | 466篇 |
晶体学 | 2篇 |
力学 | 4篇 |
数学 | 21篇 |
物理学 | 87篇 |
出版年
2023年 | 5篇 |
2022年 | 11篇 |
2021年 | 16篇 |
2020年 | 25篇 |
2019年 | 19篇 |
2018年 | 16篇 |
2017年 | 25篇 |
2016年 | 24篇 |
2015年 | 20篇 |
2014年 | 24篇 |
2013年 | 45篇 |
2012年 | 37篇 |
2011年 | 38篇 |
2010年 | 30篇 |
2009年 | 29篇 |
2008年 | 42篇 |
2007年 | 27篇 |
2006年 | 15篇 |
2005年 | 11篇 |
2004年 | 13篇 |
2003年 | 5篇 |
2002年 | 6篇 |
1998年 | 8篇 |
1997年 | 4篇 |
1996年 | 9篇 |
1995年 | 4篇 |
1994年 | 6篇 |
1993年 | 1篇 |
1992年 | 4篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 8篇 |
1983年 | 1篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1977年 | 5篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1972年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1968年 | 2篇 |
1964年 | 2篇 |
1947年 | 1篇 |
排序方式: 共有580条查询结果,搜索用时 31 毫秒
81.
Summary A method is described for the synergetic extraction and subsequent spectrophotometric determination of gold(III). The gold--furil dioxime-pyridine complex extracted into chloroform has a characteristic yellow colour with an absorption maximum at 330 nm. Beer's law is obeyed in the concentration range [Au(III)]45g/ 10 ml organic phase. A scheme to separate gold from interfering elements by extraction with 4-methyl-2-pentanol in benzene has been proposed.
Zusammenfassung Ein Verfahren zur synergetischen Extraktion und nachfolgenden spektrophotometrischen Bestimmung von Gold(III) wurde beschrieben. Die Komplexverbindung des Goldes mit-Furildioxim und Pyridin ist in chloroformischer Lösung gelb gefärbt. Ihr Absorptionsmaximum liegt bei 330 nm. Bis 45g Au(III)/10 ml organischer Phase wird das Beersche Gesetz befolgt. Die Trennung des Goldes von störenden Elementen durch Extraktion mit 4-Methyl-2-pentanol in Benzol wurde vorgeschlagen.相似文献
82.
Sanjay Pralhadrao Jadhav Bhagwan Ghanshamji Toksh Kamalakar Marutirao Jadhav Narayan Dadarao Shinde 《化学物理学报》2010,23(4):459-464
采用湿化学共沉淀法合成了Ni1-xCdxFe2O4 (0≤x≤0.5)的混合铁氧体,利用X射线衍射对其结构和晶相进行表征.结果表明:随着镉Cd浓度的增加晶格参数逐渐增大.扫描电子显微镜研究微观结构,TG/DTA研究了硫酸共沉淀物.揭示了在650 oC合成铁氧体同时进行分解.测量了纳米粒子的磁化强度和交流磁化率.结果表明,Ni1-xCdxFe2O4混合铁氧体的磁化率、居里温度和有效磁矩随着镉含量的增加下降。 相似文献
83.
The volatile constituents of Annona squamosa L. bark were identified from the essential oil obtained by steam distillation and studied by GC/MS. Six major components were identified as 1H-Cycloprop(e)azulene (3.46%), germacrene D (11.44%), bisabolene (4.48%), caryophyllene oxide (29.38%), bisabolene epoxide (3.64%) and kaur-16-ene (19.13%). The oil was also screened for its antimicrobial activity, which exhibited a significant antimicrobial activity against Bacillus subtilis and Staphylococcus aureus. 相似文献
84.
In the past two decades a large initiative has been put forth to understand the biological and pathogenic properties of the human T-cell lymphotropic virus type 1 (HTLV-1); this has ultimately led to the development of various experimental vaccination and therapeutic strategies to combat HTLV-1 infection. The focus of this work is to outline key targets for the design of therapeutics for HTLV-1, such as fusion mediated by the envelope glycoprotein, and to discuss reports of novel vaccines or therapeutics. These strategies include peptide, recombinant protein, DNA, and viral vectors. The final focus of this review is to acquaint the reader with vaccine approaches developed in our laboratory over the last decade. These strategies include the development of envelope glycoprotein derived B-cell epitopes for the induction of neutralizing antibodies, as well as a strategy to generate a multivalent cytotoxic T-lymphocyte (CTL) response against the HTLV-1 Tax antigen. 相似文献
85.
Ashok B. Gadkari Tukaram J. Shinde 《Journal of magnetism and magnetic materials》2010,322(24):3823-972
Nanocrystalline ferrite powder having the general formula Mg1−xCdxFe2O4+5% Sm3+ (x=0, 0.2, 0.4, 0.6, 0.8 and 1.0) was synthesized by chemical oxalate co-precipitation technique. The synthesized powder was characterized by X-ray, IR and SEM techniques. The XRD analysis confirms cubic spinel phase with orthoferrite secondary phase. The lattice constant increases with increase in Cd2+ content (x). It is smaller than that for pure Mg-Cd ferrites. The average crystallite size lies in the range 28.69-32.66 nm. Saturation magnetization and magnetic moment increase with cadmium content up to x=0.4 and decrease thereafter. This is attributed to the existence of localized canted spin. The decrease in saturation magnetization and magnetic moment beyond x=0.4 is due to the presence of triangular spin arrangement on B-site. Coercivity and remanent magnetization decrease while Y-K angles increase with Cd2+ content. The Sm3+ addition improves the magnetic properties. 相似文献
86.
87.
Consider a tandem queue model with a single server who can switch instantaneously from one queue to another. Customers arrive according to a Poisson process with rate λ . The amount of service required by each customer at the ith queue is an exponentially distributed random variable with rate μi. Whenever two or more customers are in the system, the decision as to which customer should be served first depends on the optimzation criterion. In this system all server allocation policies in the finite set of work conserving deterministic policies have the same expected first passage times (makespan) to empty the system of customers from any initial state. However, a unique policy maximizes the first passage probability of empty-ing the system before the number of customers exceeds K, for any value of K, and it stochastically minimizes (he number of customers in the system at any time t > 0 . This policy always assigns the server to the non empty queue closest to the exit 相似文献
88.
R.N. Bulakhe N.M. Shinde R.D. Thorat S.S. Nikam C.D. Lokhande 《Current Applied Physics》2013,13(8):1661-1667
In this paper, we report structural, morphological, electrical studies of copper iodide (CuI) thin films deposited onto glass substrates by chemical bath deposition (CBD) and successive ionic layer adsorption and reaction (SILAR) methods. CuI thin films were characterized for their structural, morphological and wettability studies by means of X-ray diffraction (XRD), FT-Raman spectroscopy, scanning electron microscopy (SEM), optical absorption, and contact angle measurement methods. Thickness of thin films was 1 ± 0.1 μm measured by gravimetric weight difference method. The CuI thin films were nanocrystalline, with average crystal size of ~60 nm. The FT-IR study confirmed the formation of CuI on the substrate surface. SEM images revealed the compact and cube like structure for CuI thin films deposited by CBD and SILAR methods, respectively. Optical absorption study revealed optical energy gaps as 2.3 and 3.0 eV for CBD and SILAR methods, respectively. Wettability study indicated that CuI thin films deposited by SILAR method are more hydrophobic as compared to CBD method. 相似文献
89.
We demonstrate, analytically and experimentally, a simple, but effective method to determine the topological charge of an optical vortex by using a spherical bi-convex lens, a ubiquitous optical element found in any optics laboratory. Just by tilting the lens and recording the intensity distribution of a propagating vortex at a predicted position past the lens, we have been able to measure both the sign and the magnitude of the topological charge m up to m=±14. Our experimental results are in excellent agreement with analytical predictions. 相似文献
90.
Here we report the results of combined powder X-ray and neutron diffraction studies of Bi4?x Nd x Ti3O12 (0.0 ≤ x ≤ 2.0) compositions. The parent Bi4Ti3O12 has an orthorhombic lattice (space group: B2cb) with unit cell parameters a = 5.4432(5) Å, b = 5.4099(5) Å and c = 32.821(2) Å, and V = 966.5(1) Å3. This orthorhombic lattice is retained in all the studied compositions. The unit cell parameters gradually decrease with Nd3+ ion concentration with a discontinuity at x = 0.75. Orthorhombicity of the lattice decreases with increase in Nd3+ content in the lattice. The orthorhombic unit cell parameters for a representative Bi2Nd2Ti3O12 composition are: a = 5.3834(9), b = 5.3846(9) and c = 32.784(1) Å. The observed orthorhombic distortion at x = 2.0 is very small and thus the crystal structure apparently has a pseudo-tetragonal lattice. In addition, Nd3+ preferentially substitutes in the perovskite slab of the Aurivillius structure. The fraction of Nd3+ in the fluorite slab increases with increase in Nd3+ contents. 相似文献