全文获取类型
收费全文 | 1699篇 |
免费 | 60篇 |
国内免费 | 10篇 |
专业分类
化学 | 841篇 |
晶体学 | 41篇 |
力学 | 74篇 |
数学 | 400篇 |
物理学 | 413篇 |
出版年
2023年 | 13篇 |
2022年 | 34篇 |
2021年 | 37篇 |
2020年 | 18篇 |
2019年 | 32篇 |
2018年 | 38篇 |
2017年 | 56篇 |
2016年 | 58篇 |
2015年 | 35篇 |
2014年 | 65篇 |
2013年 | 148篇 |
2012年 | 109篇 |
2011年 | 115篇 |
2010年 | 88篇 |
2009年 | 67篇 |
2008年 | 97篇 |
2007年 | 76篇 |
2006年 | 76篇 |
2005年 | 60篇 |
2004年 | 51篇 |
2003年 | 41篇 |
2002年 | 35篇 |
2001年 | 19篇 |
2000年 | 22篇 |
1999年 | 18篇 |
1998年 | 11篇 |
1996年 | 17篇 |
1995年 | 8篇 |
1994年 | 11篇 |
1993年 | 16篇 |
1992年 | 10篇 |
1991年 | 13篇 |
1990年 | 7篇 |
1988年 | 8篇 |
1987年 | 10篇 |
1986年 | 7篇 |
1985年 | 20篇 |
1984年 | 14篇 |
1983年 | 15篇 |
1982年 | 21篇 |
1981年 | 10篇 |
1980年 | 19篇 |
1979年 | 18篇 |
1978年 | 10篇 |
1977年 | 11篇 |
1976年 | 13篇 |
1975年 | 11篇 |
1974年 | 7篇 |
1973年 | 11篇 |
1972年 | 7篇 |
排序方式: 共有1769条查询结果,搜索用时 15 毫秒
41.
Kumaraswamy S Kommana P Kumar NS Swamy KC 《Chemical communications (Cambridge, England)》2002,(1):40-41
New modes of 1,3-dipolar cycloaddition are uncovered by the isolation of [CH2(6-t-Bu-4-Me-C6H2O)2]P(C(CO2Me)C(CO2Me)N[NP(N3)(OC6H2-6-t-Bu-4-Me)2CH2]N) (3) and [CH2(6-t-Bu-4-Me-C6H2O)2]P(C(CO2Me)C(CO2Me)C(O)N) (4) on treating [CH2(6-t-Bu-4-Me-C6H2O)2]P-X [X = N3 (1) and NCO (2)] with the dipolarophile MeO2CC identical to CCO2Me; compound 4 undergoes an unprecedented ring expansion upon addition of 2-(methylamino)ethanol to afford the spirocycle [CH2(6-t-Bu-4-Me-C6H2O)2]P(OCH2CH2N(Me)CH(CO2Me)CH(CO2Me)C(O)N) (5). 相似文献
42.
Gerard de Leeuw John S. Field Raymond J. Haines Beth McCulloch Elsie Meintjies Christiaan Monberg Gillian M. Olivier Praveen Ramdial Clifford N. Sampson Beate Sigwarth Nick D. Steen Kandasamy G. Moodley 《Journal of organometallic chemistry》1984,275(1):99-111
Reaction of [Fe2(CO)9] with a half molar amount of R2PYPR2 (Y = CH2, R = Ph, Me, OMe or OPri; Y = N(Et), R = OPh, OMe or OCH2; Y = N(Me), R = OPri or OEt) leads to the ready formation of a product which on irradiation with ultraviolet light rapidly decarbonylates to the heptacarbonyl derivative [Fe2(μ-CO)(CO)6{μ-R2PYPR2}]. Treatment of the latter with a slight excess of the appropriate ligand results, under photochemical conditions, in the formation of the dinuclear pentacarbonyl complex [Fe2(μ-CO)(C))4{μ-R2PYPR2}2] but under thermal conditions in the formation of the mononuclear species [Fe(CO)3{R2PYPR2}]. Reaction of [Ru3(CO)12] with an equimolar amount of (RO)2PN(R′)P(OR)2 (R′ = Me, R = Pri or Et; R′ = Et, R = Ph or Me) under either thermal or photochemical conditions produces [Ru3(CO)10{μ-(RO)2PN(OR)2}] which reacts further with excess (RO)2PN(R′)P(OR)2 on irradiation with ultraviolet light to afford the dinuclear compound [Ru2(μ-CO)(CO4{μ-(RO)2PN(R′)P(OR)2}2]. The molecular structure of [Ru2(μ-CO)(CO)4{μ-(MeO)2PN(Et)P(OMe)2}2], which has been determined by X-ray crystallography, is described. 相似文献
43.
44.
Ravinder Agarwal V. R. Singh M. M. Pradhan Ved Singh 《International Journal of Infrared and Millimeter Waves》1991,12(2):115-123
The occurance of the urinary stones varies according to the geographical regions. The presence of stones in the urinary system causes pain and discomfort. These generate colics and hence are sometimes life threatening. In the present study, infrared measurements have been made on several stone samples. It has been found that calcium oxalate, calcium phosphate, magnesiunm ammonium phosphate, calcium carbonate, uric acid, -cystine and xanthin are present, as expected. Also, silicon dioxide is found to be present in some of the stones but in small quantity, in addition to the above constituents. This constituent is responsible to exhibit piezoelectricity in the urinary calculi. 相似文献
45.
A new chelating polymeric sorbent has been developed using Merrifield chloromethylated resin anchored with quinoline-8-ol (HQ). The modified polymeric resin was characterized by FT-IR spectroscopy and elemental analysis. The HQ anchored resin showed superior binding affinity for U(VI) over Th(IV) and La(III). The influence of various physicochemical parameters on the recovery of U(VI) were optimized by both static and dynamic methods. The phase exchange kinetic studies performed for U(VI) revealed that <5 min was sufficient for reaching equilibrium metal ion sorption. The maximum sorption capacity of HQ anchored resin for U(VI) was found to be 120.30 mg g−1 of resin which is higher than other solid phase extraction sorbents reported so far excepting N,N-dibutyl, N′-benzoyl thiourea sorbed Amberlite XAD-16. The developed HQ anchored polymeric resin is highly selective as none of the extraneous species were found to have any deleterious effect. Solid phase extraction (SPE) studies performed using HQ anchored polymeric resin offered enrichment factor of 100 and the lowest concentration below which recoveries become non-quantitative is 5 μg l−1. The accuracy of the developed SPE method in conjunction with Arsenazo III procedure was tested by analyzing marine sediment (MESS-3) and soil (IAEA–Soil 7) reference materials. Furthermore, the above procedure has been successfully employed for the analysis of real soil and sediment samples. 相似文献
46.
Sushma Agarwal 《Journal of solution chemistry》1978,7(10):795-798
The excess volume of mixing of some electron-donating aromatic hydrocarbons like benzene, toluene,p-xylene, and mesitylene with an electronaccepting liquid 1,2,4-trichlorobenzene have been measured at 30°C. The results indicate that the interaction between the components increases as the electron-donating power of the hydrocarbons increases. The V
m
e
values are related to the ionization potentials of the hydrocarbons. 相似文献
47.
In this paper we establish some new dynamic inequalities on time scales which contain in particular generalizations of integral and discrete inequalities due to Hardy, Littlewood, P′olya, D'Apuzzo, Sbordone and Popoli. We also apply these inequalities to prove a higher integrability theorem for decreasing functions on time scales. 相似文献
48.
Jinesh M. Kuthanapillil A. Nijamudheen Nayana Joseph Praveen Prakash E. Suresh Ayan Datta K.V. Radhakrishnan 《Tetrahedron》2013
A detailed investigation on the effect of solvent polarity, temperature, and microwave irradiation on periselectivity in cycloaddition reactions of pentafulvenes with 3-oxidopyrylium betaine is described. The base catalyzed generation of 3-oxidopyrylium betaine in CHCl3 resulted in the exclusive formation of [6+3] adducts. With increase in solvent polarity and temperature, mixtures of [6+3] and [3+2] adducts were formed, where as under microwave irradiation, [3+2] adducts were formed exclusively. The experimental results have been rationalized on the basis of theoretical calculations. 相似文献
49.
P. Lakshmi Praveen 《Liquid crystals》2013,40(6):872-882
The substituent- and solvent-induced shifts in UV-visible absorption bands of naphthyl-ester nematic liquid crystals, viz., 4-octylphenyl-6-octyloxy-2-naphthoate (NAPHE1) and 6-octyloxy-2-naphthylyl-4-octyloxybenzoate (NAPHE2), have been investigated using the DFT, CNDO/S and INDO/S methods. A correlation has been made between molecular charge distribution and phase stability based on Mulliken, Loewdin, AM1, PM3, MNDO, CNDO/S and INDO/S methods. The observed π→π* and n→π* electronic transitions have been reported. The substituent- and solvent-induced shifts in absorption bands, transition energies and energy gaps have been discussed. The photosensitivity of the molecules has been analysed based on these shifts. It has been observed that the substituent has a dominant role on both absorption maxima and energy band gap, whereas the solvent has a dominant role only on absorption maxima, and no effect has been observed on the energy gap. These shifts may provide beneficial consequences in determining the end use of compounds. 相似文献
50.
By establishing a comparison result and using the monotone iterative technique combined with the method of upper and lower solutions, we investigate the existence of solutions for systems of nonlinear fractional differential equations. 相似文献