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941.
S. V. Lev R. P. Zakirova Z. Saatov M. V. Gorovits N. K. Abubakirov 《Chemistry of Natural Compounds》1990,26(1):40-41
The possibility has been studied of obtaining ecdysteroids — ecdysterone and turkesterone — with the aid of a culture of the tissues and cells of the plantAjuga turkestanica. Conditions have been selected under which the yield of ecdysteroids in the culture of tissues and cells is comparable with amounts of the same substances in the organs of the whole plant.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 51–52, January–February, 1990. 相似文献
942.
943.
(2-Quinoxalylthio)acetic acids have been found to cyclize on treatment with acetic anhydride to give the mesoionic thiazolo[3,2-a]quinoxalinium oxides. Some reactions of these compounds have been studied, and the relationship of the color of the compounds to their chemical structure examined.For Communication 18, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1680–1684, December, 1989. 相似文献
944.
U. Kreibig K. Fauth M. Quinten D. Schönauer 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1989,12(1-4):505-514
First, some general remarks concerning macroscopic “cluster matter” are given. In the second part, three recent, mainly optically and electron-microscopically performed investigations are discussed which deal with special properties of noble metal cluster systems forming the building units of this kind of matter:(1) dressed Au-55 clusters,(2) electromagnetic coupling effects among coagulated clusters,(3) the transition towards compact inhomogeneous matter caused by coalescence of clusters. 相似文献
945.
946.
947.
V. G. Kokacheva L. V. Menshikova S. K. Talitskikh P. G. Khalatur 《Journal of Structural Chemistry》1995,36(5):734-738
A system of Ornstein-Zernike integral equations is solved numerically to determine the heats of vaporization ΔHV of liquid ethane, propane, and n-butane. It is shown that the calculations (the deformations of valence bonds and bond angles
in the liquid-phase molecules are ignored) give rather accurate values of ΔHV, which are in agreement with the corresponding experimental data. On the other hand, it is established that if there are
intramolecular rotational degrees of freedom, ΔHV depends on the angle of internal rotation ϕ. The function ΔHV(ϕ) is minimum for trans-conformations (ϕ=0) and maximum for cis-conformations (ϕ=180°). Hence, intermolecular interactions
stabilize compact (convolute) conformations. The energy of this effect is of the order of 1 kJ/mole.
Tver State University. Translated fromZhurnal Strukturnoi Khimii, Vol. 36, No. 5, pp. 808–813, September–October, 1995.
Translated by I. Izvekova 相似文献
948.
949.
A. Gopalan S. Paulrajan S. Vaidyanathan K. Venkatarao N.R. Subbaratnam 《European Polymer Journal》1984,20(10):971-973
The kinetics of polymerization of acrylamide initiated by potassium peroxomonosulphate, in the presence and absence of Ag+, were studied. Rates of polymerization and oxone disappearance were followed. From the rate law for the polymerization, a mechanism has been proposed. 相似文献
950.