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191.
J Mondal A Modak A Dutta S Basu SN Jha D Bhattacharyya A Bhaumik 《Chemical communications (Cambridge, England)》2012,48(64):8000-8002
Surface functionalization of SBA-15 followed by its reaction with Cu(OAc)(2) has been carried out to develop a new Cu-grafted functionalized mesoporous material, which catalyzes one-pot three component coupling of different aryl halides with thiourea and benzyl bromide in aqueous medium to produce aryl thioethers in very good yields (80-88%). 相似文献
192.
Ranjan K. Bhatt Satyasheel Sharma Mahendra Nath 《Monatshefte für Chemie / Chemical Monthly》2012,54(1):309-316
Abstract
An improved synthetic procedure is developed for the regioselective nitration of a phenyl group of meso-tetraphenylporphyrin by using NaNO2 in a mixture of trichloroacetic acid and AcOH. The meso-(4-nitrophenyl)porphyrins are successfully reduced to corresponding meso-(4-aminophenyl)porphyrins by SnCl2 under acidic conditions. In addition, an efficient one-pot methodology for synthesizing a series of novel meso-substituted porphyrinic thiazolidinone conjugates is developed by reacting meso-(4-aminophenyl)porphyrins with various aromatic aldehydes and mercaptoacetic acid in refluxing toluene using La(OTf)3 as a catalyst. The products obtained are characterized on the basis of their spectral data. Preliminary photophysical properties of the newly synthesized compounds are reported. 相似文献193.
J.S. Yadav Sandip Sengupta Nagendra Nath Yadav D. Narasimha Chary Ahmad Alkhazim Al Ghamdi 《Tetrahedron letters》2012,53(44):5952-5954
(−)-Lardolure and (2R,4R,6R,8R)-2,4,6,8-tetramethylundecanoic acid have been synthesized via lipase catalyzed desymmetrization strategy to create two methyl chiral centers. Other key steps involved in the synthesis are Wittig reaction, Evan’s asymmetric alkylation, Grignard reaction, Pd-catalyzed isomerization of primary allylic alcohol to corresponding saturated aldehyde, and PhNO/proline catalyzed MacMillan α-hydroxylation. 相似文献
194.
Patcharin Kaewmati Ekasith Somsook Raghu Nath DhitalHidehiro Sakurai 《Tetrahedron letters》2012,53(45):6104-6106
Oxygenation of phenylboronic acid to phenol is promoted by thiol derivatives such as 2-aminothiophenol under aerobic conditions in water without metal catalyst. A plausible mechanism involves autoxidation of thiol to generate hydrogen peroxide in situ, which converts phenylboronic acid into phenol under basic conditions. Since thiols are often utilized as protective ligands for gold nanoparticles (AuNPs), this result is a warning that excess thiols and free thiols liberated from the Au surface could participate in aerobic oxidations catalyzed by thiol-protected AuNPs. 相似文献
195.
Basi V. Subba Reddy Nagendra Nath Yadav Nikhil Srivastava Jhillu S. Yadav Balasubramanian Sridhar 《Helvetica chimica acta》2012,95(1):76-86
Ionic liquids were found to be a suitable reaction medium for 1,4‐dipolar cycloaddition reactions of an isoquinoline, an activated alkyne, and a 4‐oxo‐4H‐1‐benzopyran‐3‐carboxaldehyde at room temperature to afford [1]benzopyrano‐pyrido‐isoquinoline (=9aH,15H‐benzo[a][1]benzopyrano[2,3‐h]quinolizine) derivatives selectively in good yields. The ionic liquid can be recovered and recycled in further runs without loss of activity. 相似文献
196.
Hélio A. Stefani Nathália C.S. Silva Flávia Manarin Diogo S. Lüdtke Julio Zukerman-Schpector Lucas Sousa Madureira Edward R.T. Tiekink 《Tetrahedron letters》2012,53(14):1742-1747
We have developed an efficient method for the synthesis of functionalized C-glycosyl 1,2,3-triazoles through a Cu(I)-promoted azide–alkyne 1,3-dipolar cycloaddition between a TMS-protected C-alkynyl-glycoside and organic azides. The reaction was accelerated by ultrasound irradiation and the addition of a base was not necessary to obtain the 1,2,3-triazole product. Moreover, further manipulation of the products led to chiral molecules with a C-glycoside linkage. 相似文献
197.
If s and t are relatively prime integers, J.B. Olsson proved in (J. Comb. Theory, Ser. A 116:733–740, 2009) that the s-core of a t-core partition is again a t-core partition, and that the s-bar-core of a t-bar-core partition is again a t-bar-core partition. Here generalised results are proved for partitions and bar partitions when the restriction that s and t be relatively prime is removed. 相似文献
198.
The transient boundary layer flow and heat transfer of a viscous incompressible electrically conducting non-Newtonian power-law fluid in a stagnation region of a two-dimensional body in the presence of an applied magnetic field have been studied when the motion is induced impulsively from rest. The non-linear partial differential equations governing the flow and heat transfer have been solved by the homotopy analysis method and by an implicit finite-difference scheme. For some cases, analytical or approximate solutions have also been obtained. The special interest are the effects of the power-law index, magnetic parameter and the generalized Prandtl number on the surface shear stress and heat transfer rate. In all cases, there is a smooth transition from the transient state to steady state. The shear stress and heat transfer rate at the surface are found to be significantly influenced by the power-law index N except for large time and they show opposite behaviour for steady and unsteady flows. The magnetic field strongly affects the surface shear stress, but its effect on the surface heat transfer rate is comparatively weak except for large time. On the other hand, the generalized Prandtl number exerts strong influence on the surface heat transfer. The skin friction coefficient and the Nusselt number decrease rapidly in a small interval 0<t*<1 and reach the steady-state values for t*≥4. 相似文献
199.
The steady natural convection flow on a horizontal cone embedded in a saturated porous medium with non-uniform wall temperature/concentration
or heat/mass flux and suction/injection has been investigated. Non-similar solutions have been obtained. The nonlinear coupled
differential equations under boundary layer approximations governing the flow have been numerically solved. The Nusselt and
Sherwood numbers are found to depend on the buoyancy forces, suction/injection rates, variation of wall temperature/concentration
or heat/mass flux, Lewis number and the non-Darcy parameter. 相似文献
200.
The unsteady flow and heat transfer of a viscous incompressible electrically conducting fluid in the forward stagnation point
region of a rotating sphere in the presence of a magnetic field are investigated in this study. The unsteadiness in the flow
field is caused by the velocity at the edge of the boundary layer and the angular velocity of the rotating sphere, both varying
continuously with time. The system of ordinary differential equations governing the flow is solved numerically. For some particular
cases, an analytical solution is also obtained. It is found that the surface shear stresses in x- and y-directions and the surface heat transfer increase with the acceleration, the magnetic and the rotation parameters whether
the magnetic field is fixed relative to the fluid or body, except that the surface shear stress in x-direction and the surface heat transfer decrease with increasing the magnetic parameter when the magnetic field is fixed
relative to the body. For a certain value of the acceleration parameter, the surface shear stress in the x-direction vanishes while the surface shear stress in the y-direction and the surface heat transfer remain finite. Also, below a certain value of the acceleration parameter, reverse
flow occurs in the x-component of the velocity profile.
Received on 18 May 1998 相似文献