The instantaneous slow flow of a visco-elastic fluid between two concentric spheres

Summary A theoretical analysis is made of the flow of an incompressible viscoelastic fluid contained between two concentric spheres when the outer sphere is moved instantaneously in a given direction, whilst the inner sphere remains at rest. The solution is developed by successive approximations, the first corresponding to the instantaneous slow flow of a Newtonian viscous fluid. By allowing the radius of the outer sphere to approach infinity, the result obtained can be used to give an approximate solution to the equations of motion of a visco-elastic fluid flowing slowly past a fixed sphere.     

A family of double-bowl pseudo metallocalix[6]arene discs

We report the synthesis and magnetic characterisation of a series of planar [M?] (M= Ni(II), Zn(II)) disc complexes [Ni?(OH)?(L?)?](NO?)? (1), [Ni?(OH)?(L?)?](NO?)?·2MeOH (2), [Ni?(OH)?(L?)?](NO?)?·3MeNO? (3), [Ni?(OH)?(L?)?](NO?)?·2MeCN (4), [Zn?(OH)?(L?)?](NO?)?·2MeOH·H?O (5) and [Zn?(OH)?(L?)?](NO?)?·3MeNO? (6) (where HL? = 2-iminomethyl-6-methoxy-phenol, HL? = 2-iminomethyl-4-bromo-6-methoxy-phenol). Each member exhibits a double-bowl pseudo metallocalix[6]arene topology whereby the individual [M?] units form molecular host cavities which are able to accommodate various guest molecules (MeCN, MeNO? and MeOH). Magnetic susceptibility measurements carried out on complexes 1 and 4 indicate weak exchange between the Ni(II) centres.     

A donor-stabilization strategy for the preparation of compounds featuring P=B and As=B double bonds

A new class of heavier group 15 compounds demonstrating multiple bonding with boron has been synthesized using a simple donor-stabilization protocol.     

Density functional theory (DFT)-based modified embedded atom method potentials: Bridging the gap between nanoscale theoretical simulations and DFT calculations

A density functional theory (DFT)-calculation scheme for constructing the modified embedded atom method (MEAM) potentials for face-centered cubic (fcc) metals is presented. The input quantities are carefully selected and a more reliable DFT approach for surface energy determination is introduced in the parameterization scheme, enabling MEAM to precisely predict the surface and nanoscale properties of metallic materials. Molecular dynamics simulations on Pt and Au crystals show that the parameterization empl...     

Bei der H?rtebestimung von Schleifmitteln

Ohne Zusammenfassung