Thermally activated transformation of magnetization-reversal modes in ultrathin nanoparticles

The influence of thermal fluctuations on magnetization-reversal processes in ultrathin magnetic particles is investigated on the basis of a numerical solution of the Landau-Lifshitz-Gilbert equations taking account the thermal-activation fluctuation field. It is shown that for nanoparticles there exists a region of magnetic and geometric parameters where a strong jump-like instability of the critical field for magnetization reversal arises. This instability is due to the thermally activated transformation of magnetization configurations far from the switching threshold. The thermal-instability mechanism described is important for particles of much larger sizes than for the single-mode Néel-Brown instability. Pis’ma Zh. éksp. Teor. Fiz. 69, No. 8, 555–560 (25 April 1999)     

Temperature behavior of the antiferromagnetic susceptibility of nanoferrihydrite from the measurements of the magnetization curves in fields of up to 250 kOe

The cross-breeding problem of the temperature dependence of the antiferromagnetic susceptibility of ferrihydrite nanoparticles is considered. Iron ions Fe3+ in ferrihydrite are ordered antiferromagnetically; however, the existence of defects on the surface and in the bulk of nanoparticles induces a noncompensated magnetic moment that leads to a typical superparamagnetic behavior of ensemble of the nanoparticles with a characteristic blocking temperature. In an unblocked state, magnetization curves of such objects are described as a superposition of the Langevin function and the linear-in-field contribution of the antiferromagnetic “core” of the nanoparticles. According to many studies of the magnetization curves performed on ferrihydrite (and related ferritin) nanoparticles in fields to 60 kOe, dependence χ_AF(T) decreases as temperature increases, which was related before to the superantiferromagnetism effect. As the magnetic field range increases to 250 kOe, the values of χ_AF obtained from an analysis of the magnetization curves become lower in magnitude; however, the character of the temperature evolution of χ_AF is changed: now, dependence χ_AF(T) is an increasing function. The latter is typical for a system of AF particles with random orientation of the crystallographic axes. To correctly determine the antiferromagnetic susceptibility of AF nanoparticles (at least, ferrihydrite) and to search for effects related to the superantiferromagnetism effect, it is necessary to use in experiments the range of magnetic field significantly higher than that the standard value 60 kOe used in most experiments. The study of the temperature evolution of the magnetization curves shows that the observed crossover is due to the existence of small magnetic moments in the samples.     

Field-Induced Spin-Modulated Transitions in Epitaxial (001) BiFeO3 Films

Physics of the Solid State - Alterations in the ground state of thin (001) films of a BiFeO3 (BFO)-type multiferroic in a magnetic field are studied theoretically, with changes in the energy of...     

A Water Rich Crystalline Hydrate Formed by 1,4,7,10-Tetraazacyclododecane, Siliconhydrofluoric Acid and Water: Structure and Properties

Novel complementary associations have been found in a crystalline ternarycomplex of the macrocyclic tetramine, [12]aneN₄ (e.g. =1,4,7,10-tetraazacyclododecane, cyclen, L), hexafluorosilicate ions andwater (I). The final compound belongs to the host—guest type with themacrocycle as the host (H), the inorganic entity as a guest (G) and watermolecules. It was characterized by X-ray techniques, IR spectroscopy andthermogravimetric study. X-ray crystal analysis revealed that the structureis built of the charged entities, with a 3D-network uniting thequadriprotonated form of the macrocycle, hexafluorosilicate as counterionsand lattice water molecules viaN—H⁺...F^-,N—H⁺...O(w),OH...F^- and O—-H(w)...O(w)hydrogen bonds. The overall complex stoichiometry comprises fourSiF₆ ^2- anions and seven water molecules per two[LH₄]⁴⁺ cations. Crystals of (I) are monoclinic,space group P2₁/n with a = 14.585(3), b = 16.384(2), c =16.500(3) Å, = 92.84(3)°, V = 3938(1)ų and Z = 8 forC₈H₃₁F₁₂N₄O_3.5Si₂.     

Asymmetric synthesis of S-5-benzyloxytryptophan,S-α-allylglycine and S-β-(2-naphthyl)alanine

Conclusions The synthesis of optically pure S-5-benzyloxytryptophan, S--(2-naphthyl)alanine, and S--allylglycine was carried out by alkylating glycine in the Ni(II) complex of its Schiff base with S-2-N-(N-benzylpropyl)aminobenzophenone, followed by Chromatographic separation of the mixture of diastereomeric alkylated complexes.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2818–2821, December, 1988.