Water clusters in supramolecular inclusion hydrates. Crystal structure of decaazatricyclo[28.2.2.213.16]tetratriacontane nanohydrate

Inclusion compounds of solvate water molecules in a crystal matrix are investigated by X-ray diffraction analysis of a macrocyclic polyamine decaazatricyclo[28.2.2.2^13.16]tetratriacontane nanohydrate (I). When included in a crystal, water molecules are bonded by water-water (O-H...O) and water—macrocycle (0-H...N and N-H...O) hydrogen bonds, forming a linear cluster. Translated fromZhurnal Strukturnoi Khimii, Vol. 40, No. 5, pp. 993–1001, September–October, 1999.     

Exact Results for the Isotropic Spin-1/2 Heisenberg Chain With Dissipative Boundary Driving

Theoretical and Mathematical Physics - We consider the open isotropic spin-1/2 Heisenberg quantum spin chain with a finite number N of sites coupled at the ends to a dissipative environment that...     

Reduced Density Matrix of Permutational Invariant Many-body Systems

We consider density matrices which are sums of projectors on states spanning irreducible representations of the permutation group of L sites (eigenstates of permutational invariant quantum system with L sites) and construct reduced density matrix ρ _n for blocks of size n<L by tracing out L−n sites, viewed as environment. Explicit analytic expressions of the elements of ρ _n are given in the natural basis and the corresponding spectrum of the reduced density matrix is derived. Results apply to other quantum many-body systems with permutational symmetry.     

Use of chromatography-mass spectrometry to study the composition of pharmacopoeial types of medicinal plant raw material

The composition of the volatile fraction of extracts for pharmacopoeial types of medicinal plant raw materials was studied using chromatography-mass spectrometry to identify specific compounds characteristic of a specific plant. Forty pharmacopoeial types of medicinal plant raw material were analyzed. It is shown that 14 of them contain specific volatile compounds (markers) allowing unambiguous identification.     

Synthesis of vinyl-substituted oxiranes and their transformation to dihydrofurans

The reaction of dimethylsulfonium methylide with the carbonyl function of 2-arylidene-cyclohexanones obtained from 2-methylcyclohexanone affords the corresponding spirooxiranes. The application of this reaction to 2,2-dimethyl-6-(5-methylfurfurylidene)cyclohexanone and 2,2-dimethyl-6-(5-chlorofurfurylidene)cyclohexanone leads to substituted 4,4-dimethyl-1-furyl-1,-3,4,5,6,7-hexahydroisobenzofurans.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1439–1443, August, 1994.