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51.
An efficacious synthesis of N-1–, C-3–substituted indole derivatives and their antimicrobial studies
A novel series of 11 C-3– and N-1–substituted oxoacetamide indole derivatives were synthesized by reacting with various aromatic amines and alkyl halides. These compounds were characterized by using various spectral techniques, ie, 1HNMR, 1HNMR-D2O, 13CNMR, UV, elemental analysis, IR, and mass spectrometery. In vitro, antimicrobial studies of resultant compounds were carried out against two bacterial strains, Pseudomonas aeruginosa and Pseudomonas oryzihabitans using disc plate method. All the tested compounds showed vital efficiency as antimicrobial agents against both the bacterial strains. The results revealed that synthesized indole derivative 2-(1-(3-bromopropyl)-1H-indol-3-yl)-N-(2-nitrophenyl)-2-oxoacetamide displayed the best antimicrobial activity as compared with all other synthesized compounds. 相似文献
52.
Apparent molar volumes \((\phi_{V})\) of glycine/l-alanine in water and in aqueous citric acid (CA) solutions of varying concentrations, i.e. (0.05, 0.10, 0.20, 0.30, 0.40 and 0.50) mol·kg?1 were determined from density measurements at temperatures T?=?(288.15, 298.15, 308.15, 310.15 and 318.15) K and at atmospheric pressure. Limiting partial molar volumes \((\phi_V^{\text{o}})\) and their corresponding partial molar volumes of transfer \((\Delta_{\text{tr}} \phi_{V} )\) have been calculated from the \(\phi_{V}\) data. The negative \(\Delta_{\text{tr}} \phi_{V}\) values obtained for glycine/l-alanine from water to aqueous CA solutions indicate the dominance of hydrophilic–hydrophobic/hydrophobic–hydrophilic and hydrophobic–hydrophobic interactions over ion/hydrophilic–dipolar interactions. Further, pair and triplet interaction coefficients, i.e. \((V_{\text{AB}} )\;{\text{and}}\; (V_{\text{ABB}} )\) along with hydration number \((n_{\text{H}} )\) have also been calculated. The effect of temperature on the volumetric properties of glycine/l-alanine in water and in aqueous CA solutions has been determined from the limiting partial molar expansibilities \((\partial \phi_{V}^{\text{o}} /\partial T)_{p}\) and their second-order derivative \((\partial^{2} \phi_{V}^{\text{o}} /\partial T^{2} )_{{P}}\). The apparent specific volumes \((\nu_{\phi} )\) for glycine and l-alanine tend to approach sweet taste behavior both in the presence of water and in aqueous CA solutions. The \(\nu_{\phi}\) values for glycine/l-alanine increase with increase in concentration of CA at all temperatures studied. This reveals that CA helps in enhancing the sweet taste behavior of glycine/l-alanine which also supports the dominance of hydrophobic–hydrophobic interactions. 相似文献
53.
Poonam Gupta Dr. Durga Prasad Karothu Dr. Ejaz Ahmed Prof. Panče Naumov Prof. Naba K. Nath 《Angewandte Chemie (International ed. in English)》2018,57(28):8498-8502
The first example of a smart crystalline material, the 2:1 cocrystal of probenecid and 4,4′‐azopyridine, which responds reversibly to multiple external stimuli (heat, UV light, and mechanical pressure) by twisting, bending, and elastic deformation without fracture is reported. This material is also able to self‐heal on heating and cooling, thereby overcoming the main setbacks of molecular crystals for future applications as crystal actuators. The photo‐ and thermomechanical effects and self‐healing capabilities of the material are rooted in reversible trans–cis isomerization of the azopyridine unit and crystal‐to‐crystal phase transition. Fairly isotropic intermolecular interactions and interlocked crisscrossed molecular packing secure high elasticity of the crystals. 相似文献
54.
In this paper, we introduce and study a new fractional operator and its implications in terms of the Ruscheweyh derivative operator, the Sălăgean operator and a certain fractional differintegral operator. Some geometric properties of the analytic functions involving this operator are derived. We also consider some applications and derive certain corollaries of our main results. Some useful consequences and relationship of certain results with known results are also pointed out.
相似文献55.
Poonam Tandon V. D. Gupta O. Prasad Shantanu Rastogi V. P. Gupta 《Journal of Polymer Science.Polymer Physics》1997,35(14):2281-2292
Poly(L -methionine) (PMet) is one of the two sulfur containing polyamino acids. Raman, FTIR spectra, and heat capacity measurements of PMet have been well interpreted through the normal mode analysis and the density of states derived therefrom. Earlier interpretation of heat capacity data is limited because it is based on the Tarasov model, wherein the concept of group frequency and skeletal similarity are used. A special feature of some dispersion curves is their tendency to bunch in the neighborhood of the helix angle. This has been attributed to the presence of strong intramolecular interactions. Repulsion between the dispersion curves is also observed. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35 : 2281–2292, 1997 相似文献
56.
Navina Wadhwani Poonam Tandon Vishwambhar D. Gupta Shantanu Rastogi 《Macromolecular Symposia》1997,119(1):113-117
Among the synthetic polymers of commercial potential, poly-butadiene is an important rubbery material and it encompasses the bulk elastomers in use. To the best of our knowledge, a complete normal coordinate analysis with full phonon dispersion curves for cis 1,4 polybutadiene (CPBD) have not been reported so far. In the present communication, we report a complete normal coordinate analysis with full dispersion curves, density-of-states and calculation of heat capacity. The normal coordinate analysis has been carried out using the Urey-Bradley force field and the Wilson's GF matrix method as modified by Higgs. A comparison has been made with trans 1,4 polybutadiene (TPBD). The prominent features of the dispersion curves like crossing over and regions of zero-slope away from the zone centre are discussed. To check the validity of the force field used and the assignments, normal mode calculations are also performed for unsaturated C-deuterated and fully deuterated CPBD. 相似文献
57.
A statistical analysis has been carried out to determine the configurationally preference of a pair of 5OCB (4′‐n‐pentyloxy‐4‐biphenylcarbonitrile) molecules with respect to translatory and orientational motions. The CNDO/2 method has been employed to evaluate the net atomic charge and atomic dipole components at each atomic centre of the molecule. Modified Rayleigh‐Schrodinger perturbation theory along with multicentered‐multipole expansion method has been employed to evaluate long‐range intermolecular interactions, while a ‘6‐exp’ potential function has been assumed for short‐range interactions. The total interaction energy values obtained through these computations were used to calculate the probability of each configuration in vacuum and in a dielectric medium at phase transition temperature using Maxwell‐Boltzmann formula. It has been observed that the probabilities are redistributed in dielectric medium and there is considerable rise in the probabilities of interactions, although the order of preference remains the same. On the basis of stacking, in‐plane and terminal interaction energy calculations, all possible geometrical arrangements of the molecular pairs have been considered. The results are discussed in the light of experimental as well as other theoretical observations. 相似文献
58.
A computational Analysis has been carried out to determine the configurational preference of a pair of a nematogen, 4,4′‐azodiphenetole (C2H5‐O‐C6H4‐N=N‐C6H4‐O‐C2H5) [AZO] molecules with respect to translatory and orientational motions. The CNDO/2 method has been employed to compute the atomic charge and atomic dipole at each atomic centre. Configurational energy has been computed using modified Rayleigh‐Schrodinger perturbation method. The interaction energy values obtained through these computations were used to calculate the probability of each configuration at phase transition temperature using Maxwell‐Boltzmann formula. Further, the flexibility of various configurations has been studied in terms of variation of probability due to small departures from the most probable configuration. Molecular parameters like total energy, binding energy and total dipole moment have been given. Results have been discussed in the light of experimental as well as other theoretical observations. 相似文献
59.
60.
Poonam Nandal S. P. Khatkar Rajesh Kumar Avni Khatkar V. B. Taxak 《Journal of fluorescence》2017,27(1):1-11
Synthesis and photoluminescence behaviour of six novel europium complexes with novel β-hydroxyketone ligand, 2-(4-chlorophenyl)-1-(2-hydroxy-4-methoxyphenyl)ethan-1-one (CHME) and 2,2′-bipyridine (bipy) or neocuproine (neo) or 1,10-phenanthroline (phen) or 5,6-dimethyl-1,10-phenanthroline (dmphen) or bathophenanthroline (bathophen) were reported in solid state. The free ligand CHME and europium complexes, Eu(CHME)3.2H2O [1] Eu(CHME)3.bipy [2], Eu(CHME)3.neo [3], Eu(CHME)3.phen [4], Eu(CHME)3.dmphen [5] and Eu(CHME)3.bathophen [6]were characterized by elemental analysis, FT-IR and 1H-NMR. The photoluminescence emission spectra exhibited four characteristic peaks arising from the 5D0 → 7FJ (J = 1–4) transitions of the europium ion in the solid state on monitoring excitation at λex = 395 nm. The luminescence decay curves of these europium complexes possess single exponential behaviour indicating the presence of a single luminescent species and having only one site symmetry in the complexes. The luminescence quantum efficiency (η) and the experimental intensity parameters, Ω 2 and Ω 4 of europium complexes have also been calculated on the basis of emission spectra and luminescence decay curves. In addition, the antimicrobial and antioxidant activities were also studied of the investigated complexes. 相似文献