Stereoselective photooxidation of enecarbamates: reactivity of ozone vs singlet oxygen

[reaction: see text]. Oxazolidinone-functionalized enecarbamates show contrasting behavior upon oxidation by singlet oxygen and by ozone. The observed stereoselectivity difference indicates that the oxidation with ozone is subject to classic steric effects, whereas the very high selectivity in the photooxidation with singlet oxygen is derived from vibrational deactivation.     

Projective embeddings of complex supermanifolds

We generalize the Kodaira Embedding Theorem and Chow's Theorem to the context of families of complex supermanifolds. In particular, we show that every family of super Riemann surfaces is a family of projective superalgebraic varieties.Research supported in part by NSF grant DMS-8704401Research supported in part by NSF grant DMS-4253943Research also supported in part by NSF grant DMS-4253943     

Algebraic recurrence relations for the finite-order scattering and transmission functions

In preceding papers (cf. Bellmanet al.(^1,2,3,), integral recurrence for the finite-order scattering and transmission functions have been given in connection with integral recurrence relations for the finite order X- and Y-functions with the aid of an initial-value method. In the present paper, it is shown how to find algebraic recurrence relations for the finite-order scattering and transmission functions in terms of finite-order X- and Y-functions without referring to an initial-value method. These recurrence relations are suitable for the numerical computation of the finite-order scattering and transmission functions by use of a digital computer. Furthermore, in Tables 1–3, a numerical example of the finite-order reflection functions for optical thickness 0·2 with albedo = 1 is listed. Table 4 furnishes an example of the cumulative reflection functions for optical thickness 0·2 with three different albedos.     

Microwave absorption of oxygen measured with a Fabry-Perot spectrometer

A Fabry-Perot interferometer in the semiconfocal configuration has been used as a microwave spectrometer by the method of Q-reduction. The Q can be determined with conventional laboratory equipment to within 2% accuracy, corresponding to 0.3 dB/km at 58.82 GHz. Absolute of pure oxygen and dry air at fixed frequencies has been measured as a function of pressure from 0 to 1 atm at room temperature. The measured absorption of dry air can be explained if the overlap of the oxygen lines is properly taken into account.     

Numerical results for finite order X and Y functions of radiative transfer

It is well known that, in the theory of radiative transfer, Chandrasekhar's X and Y functions play an important role in the diffuse reflection and transmission problem (cf. Chandrashekhar⁽¹⁾). In a preceding paper (cf. Bellmanet al.⁽¹⁰⁾), graphs and selected tables of these functions covering wide ranges of slab thickness and albedos for single scattering have been provided. In this paper, making use of a system of coupled integral recurrence relations for finite order X and Y functions (cf. Bellmanet al.⁽¹⁴⁾), numerical results for these basic functions are tabulated up to optical thickness τ = 2.0 from τ = 0.1, assuming the conservative case of isotropic scattering. The maximum order of these functions is taken to be fifteenth. It is shown that the accuracy obtained is satisfactory in the domain under consideration. Furthermore, numerical results for Chandrasekhar's approximation for X and Y functions are also tabulated for stabs of small optical thickness.     

Structure of 72,74Se at high spin

Lifetimes of high spin states up to { }=22⁺ in the yrast positive parity bands have been measured to investigate the shape evolution with increasing spin in ^{72, 74}Se. The Q _t values derived from these measurements indicate that prolate shape stabilizes for ⁷²Se, while a triaxial shape develops for ⁷⁴Se at higher spins. Comparison of the observed trend in Q _t with spin for ^{72, 74}Se with that of the corresponding kryptones isotones emphasizes the stability provided by N=38 prolate shell gap even at high rotational frequency.     

Stereocontrol within confined spaces: enantioselective photooxidation of enecarbamates inside zeolite supercages

Dye-exchanged Y zeolite is shown to be an effective medium to control the stereoselectivity in the photooxygenation of chiral oxazolidinone-functionalized Z/E-1 enecarbamates. An enantioselectivity (ee) as high as 80% was observed in the methyldesoxybenzoin (MDB) product, obtained in the methylene-blue-exchanged NaY zeolite at room temperature. The efficacy of the asymmetric induction in the MDB product depends on the Z/E geometry of the alkene, the Z-isomer being more effective than the corresponding E-isomer. The stereoselectivity is rationalized in terms of conformational effects through cationic interactions between the zeolite and the substrate.     

Physics going soft: The emergence of soft condensed matter physics

The recent development of intense, ultrashort, table top lasers in the mid-infrared opens new avenues for research in strong field atomic physics. Electrons submitted to such radiation acquire huge quiver energies, even at moderate intensity and interesting properties arise: first, the wavelength offers a convenient experimental knob to tune the ionisation regime by controlling the Keldysh parameter. Second, many processes like above-threshold ionisation or high harmonic generation, whose characteristics depend directly on this energy, can be pushed to unprecedented limits. Third, the wavelength controls the spectral phase of the harmonics and hence the possibility to improve the generation of pulses in the attosecond regime. Recent studies of rare gas and alkali atoms' photoelectron spectra and harmonic generation at 2 and 3.6 μm have begun to confirm the theoretical predictions. However, unexpected features have also been found showing that strong field interaction still keeps some secrets after more than 40 years of investigation.     

Photochromic Dithienylethene‐Containing Triarylborane Derivatives: Facile Approach to Modulate Photochromic Properties with Multi‐addressable Functions

A series of dithienylethene‐containing triarylboranes has been designed, synthesized, and characterized. The electrochemistry, photophysics, and photochromic behavior have also been studied. The photophysical and photochromic properties could be facilely tuned in this system by varying the thiophene spacers (thiophene, thienothiophene, and bithiophene) between the dithienylethene and the dimesitylboron (BMes₂) or the position of the BMes₂ substitution in the thiophene spacers. The absorption of closed form has been found to be more sensitive towards the structural modification upon incorporation of the BMes₂ unit. Moreover, multi‐addressable photochromic reactivity is obtained upon addition of Lewis base (F^?), which is due to the formation of boron–Lewis base adduct. The dependence of the photophysical and photochromic properties on the thiophene spacers and the position of the BMes₂ substitution has been further supported by computational studies.