全文获取类型
收费全文 | 111篇 |
免费 | 1篇 |
专业分类
化学 | 86篇 |
物理学 | 26篇 |
出版年
2021年 | 2篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2016年 | 2篇 |
2014年 | 1篇 |
2013年 | 4篇 |
2012年 | 3篇 |
2010年 | 2篇 |
2009年 | 2篇 |
2008年 | 2篇 |
2007年 | 1篇 |
2006年 | 3篇 |
2004年 | 6篇 |
2003年 | 2篇 |
2002年 | 2篇 |
2001年 | 2篇 |
2000年 | 5篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1994年 | 5篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 8篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1975年 | 5篇 |
1974年 | 1篇 |
1973年 | 4篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1968年 | 1篇 |
1908年 | 1篇 |
1907年 | 2篇 |
排序方式: 共有112条查询结果,搜索用时 15 毫秒
11.
There is considerable interest in polyazine N-oxides as potential frameworks for energetic compounds with relatively high enthalpies of formation and crystal densities. The N+→O? linkages, if appropriately located, may diminish the destabilization associated with nitrogen catenation. We have computationally characterized 40 N-oxides of the isomeric diazines, triazines, and tetrazines in terms of their geometries, relative energies, and (for a representative selection) electrostatic potentials. The presence of N+→O? linkages does partially counteract the destabilizing effects of nitrogen catenation, although the isomers with complete catenation remain the least stable. The stabilizing influence of N+→O? groups, and the accompanying changes in bond lengths, can be understood in terms of resonance charge delocalization to the polyazine rings. The N(O)–N(O) bonds between nitrogens that both bear oxygens tend to be relatively weak. The electrostatic potentials above the polyazine rings become increasingly positive as there are more nitrogens and oxygens; eventually they are positive above all of the carbons and nitrogens and possibly even the oxygens, with negative regions only on the peripheries of the molecules. However, the nitrogens that bear oxygens always have more positive potentials than those that do not. 相似文献
12.
Chun M. Lau Kannappan Thangaraj Govindarajulu Kumar Vayalakkavoor T. Ramakrishnan Edwin D. Stevens Joseph H. Boyer Ieva R. Politzer Theodore G. Pavlopoulos 《Heteroatom Chemistry》1990,1(3):195-209
The conversion of 3-methyl-4-benzyl-4-chloro-2-pyrazolin-5-one 10b was catalyzed by a mixture of potassium fluoride and alumina to give syn-(methyl, benzyl)bimane 6 (62%) without detectable formation of the anti isomer, A6 [a 1 : 1 mixture (87%) of the isomers 6 and A6 was obtained when the catalyst was potassium carbonate]. In a similar reaction syn-(methyl,carboethoxymethyl)bimane 7 (15%) with the anti isomer A7 (36%) was obtained from 3-methyl-4-carboethoxymethyl-4-chloro-2-pyrazolin-5-one 10c . syn-(Methyl, β-acetoxyethyl)bimane 8 (70%) was obtained from 3-methyl-4-β-acetoxyethyl-4-chloro-2-pyrazolin-5-one 10d (potassium carbonate catalysis) and was converted by hydrolysis to syn-(methyl, β-hydroxyethyl)bimane 9 (40%). Acetyl nitrate (nitric acid in acetic anhydride) converted anti-(amino,hydrogen)bimane 11 to anti-(amino,nitro)bimane 15 (91%), anti-(methyl,hydrogen)bimane 13 to anti-(methyl,nitro)(methyl,hydrogen)bimane 16 (57%), and degraded syn-(methyl,hydrogen)bimane 12 to an intractable mixture. Treatment with trimethyl phosphite converted syn-(bromomethyl,methyl)bimane 17 to syn-(dimethoxyphosphinylmethyl,methyl)bimane 18 (78%) that was further converted to syn-(styryl,methyl)bimane 19 (29%) in a condensation reaction with benzaldehyde. Treatment with acryloyl chloride converted syn-(hydroxymethyl,methyl)bimane 20 to its acrylate ester 21 (22%). Stoichiometric bromination of syn-(methyl,methyl)bimane 1 gave a monobromo derivative that was converted in situ by treatment with potassium acetate to syn-(acetoxymethyl,methyl)(methyl,methyl)bimane 47 . N-Amino-μ-amino-syn-(methylene,methyl)bimane 24 (68%) was obtained from a reaction between the dibromide 17 and hydrazine. Derivatives of the hydrazine 24 included a perchlorate salt and a hydrazone 25 derived from acetone. Dehydrogenation of syn-(tetramethylene)bimane 26 by treatment with dichlorodicyanobenzoquinone (DDQ) gave syn-(benzo,tetramethylene)bimane 27 (58%) and syn-(benzo)bimane 28 (29%). Bromination of the bimane 26 gave a dibromide 29 (92%) that was also converted by treatment with DDQ to syn-(benzo)bimane 28 . Treatment with palladium (10%) on charcoal dehydrogenated 5, 6, 10, 11-tetrahydro-7H,9H-benz [6, 7] indazol [1, 2a]benz[g]indazol-7,9-dione 35 to syn-(α-naphtho)bimane 36 (71%). The bimane 35 was prepared from 1,2,3,4-tetrahydro-1-oxo-2-naphthoate 37 by stepwise treatment with hydrazine to give 1,2,4,5-tetrahydro-3H-benz[g]indazol-3-one 38 , followed by chlorine to give 3a-chloro-2,3a,4,5-tetrahydro-3H-benz[g]indazol-3-one 39 , and base. Dehydrogenation over palladium converted the indazolone 34 to 1H-benz[g] indazol-3-ol 36 . Helicity for the hexacyclic syn-(α-naphtho)bimane 36 was confirmed by an analysis based on molecular modeling. The relative efficiencies (RE) for laser activity in the spectral region 500–530 nm were obtained for 37 syn-bimanes by reference to coumarin 30 (RE 100): RE > 80 for syn-bimanes 3, 5, 18 , and μ-(dicarbomethoxy)methylene-syn-(methylene,methyl)bimane 22 : RE 20–80: for syn-bimanes 1,2,4,20,24,26 , and μ-thia-syn-(methylene,methyl)bimane 50 : and RE 0-20 for 26 syn-bimanes. The bimane dyes tended to be more photostable and more water-soluble than coumarin 30. The diphosphonate 18 in dioxane showed laser activity at 438 nm and in water at 514 nm. Presumably helicity, that was demonstrated by molecular modeling, brought about a low fluorescence intensity for syn-(α-naphtho)bimane 36 , Φ0.1, considerably lower than obtained for syn-(benzo)bimane 28 , Φ0.9. 相似文献
13.
14.
15.
16.
Jane S. Murray Pat Lane Anian Nieder Thomas M. Klapötke Peter Politzer 《Theoretical chemistry accounts》2010,127(4):345-354
Si-pentaerythritol tetranitrate (PETN), Si[CH2ONO2]4, is a silicon analog of the widely used explosive PETN, C[CH2ONO2]4. Si-PETN is extremely sensitive to impact, much more so than PETN. This was attributed by Liu et al. to Si-PETN having a
much lower activation barrier to decomposition, via a facile rearrangement that is not as readily available to PETN, and which
releases considerable energy that can promote further steps. We have investigated computationally why the barrier to the rearrangement
is so much lower for Si-PETN than for PETN, using 5, (H3C)3C–CH2ONO2, and 6, (H3C)3Si–CH2ONO2, as models for PETN and Si-PETN. Reaction force analysis shows that most of the difference between the rearrangement barriers
for 5 and 6 comes about in the initial (reactant) stages of the processes, in which 6 benefits from a 1,3 electrostatic interaction involving a positive σ–hole on the silicon and the negative linking oxygen.
The analogous interaction is weaker in 5, since the central carbon does not have positive σ–holes; furthermore, this carbon is less able than silicon to temporarily
expand its coordination sphere. A similar explanation involving a positive silicon σ–hole and a linking oxygen is proposed
for Si-PETN. The greater exothermicity of the rearrangement of 6 (and also Si-PETN) can be rationalized, following Liu et al., in terms of the formation of the strong Si–O bond. 相似文献
17.
James M. Cline H. David Politzer Soo-Jong Rey Mark B. Wise 《Communications in Mathematical Physics》1987,112(2):217-235
The high peaks of a Gaussian random field are studied. Asymptotic expansions, appropriate for high peak thresholds and large spatial separations, are developed for theN-point correlation functions of the number density of high peaks, in terms of the two-point correlation of the underlying Gaussian field. Similar expressions are derived for the correlations of points, not necessarily the positions of peaks, where the field exceeds a high threshold.Work supported in part by U.S. Department of Energy under contract DEAC03-81-ER40050.KFAS Graduate FellowAlfred P. Sloan Foundation Fellow and supported in part by U.S. Department of Energy Outstanding Junior Investigator Program under contract No. DE-FG03-84 ER40172 相似文献
18.
Laura Macaveiu Michael Göbel Thomas M. Klapötke Jane S. Murray Peter Politzer 《Structural chemistry》2010,21(1):139-146
We have extended an earlier crystallographic/computational study which revealed an exceptionally short C–Cl bond in chlorotrinitromethane,
Cl–C(NO2)3. We show that the C–Cl bond length progressively decreases when NO2 groups are introduced into chloromethane. This is attributed to intramolecular attractive interactions between the chlorine
and the closest NO2 oxygens. Computed electrostatic potentials on molecular surfaces support this interpretation, as well as the N–O interactions
between neighboring NO2 groups that help to determine the molecular conformations. The calculated C–Cl bond energies decrease as the NO2 groups are added, which is expected, but means that the usual inverse relationship between bond energy and bond length is
not being obeyed. For purposes of comparison, the computational analyses, which were primarily at the B3PW91/6-311G(3d,2p)
level, were also carried out for the corresponding chlorocyanomethanes and chlorofluoromethanes. These do not show anomalously
short C–Cl bond distances. 相似文献
19.
A. Politzer 《Fresenius' Journal of Analytical Chemistry》1908,47(2-3):158
Ohne Zusammenfassung 相似文献
20.
H David Politzer 《Physics Reports》1974,14(4):129-180
The discovery of asymptotic freedom has opened up the possibility of extracting new sorts of detailed, dynamical consequences from a strongly interacting quantum field theory. The necessary tools - perturbation theory, the renormalization group, gauge theories, and the operator product expansion - are not new. To anyone familiar with these field theoretic approaches to strong interactions, the novel feature is a simple fact: there is a unique class of theories in which “the origin is an ultraviolet fixed point”. But the consequences are so exciting that it seemed appropriate to review these ideas as they reflect on each other. Many important applications of the renormalization group and the operator product expansion to hadronic physics are omitted; the emphasis here is on recent work based on asymptotically free field theories. No doubt, there are some developments so recent that they are not treated in this article.The discussion of the basic results concerning short distance behavior is informal, but, hopefully, accurate and complete. The specific applications are treated in varying detail. 相似文献