全文获取类型
收费全文 | 196篇 |
免费 | 3篇 |
专业分类
化学 | 78篇 |
晶体学 | 2篇 |
力学 | 3篇 |
数学 | 35篇 |
物理学 | 81篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2020年 | 6篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2017年 | 2篇 |
2016年 | 1篇 |
2015年 | 2篇 |
2014年 | 3篇 |
2013年 | 13篇 |
2012年 | 4篇 |
2011年 | 6篇 |
2010年 | 3篇 |
2009年 | 8篇 |
2008年 | 8篇 |
2007年 | 5篇 |
2006年 | 7篇 |
2005年 | 9篇 |
2004年 | 8篇 |
2003年 | 6篇 |
2002年 | 5篇 |
2001年 | 7篇 |
2000年 | 7篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1995年 | 4篇 |
1994年 | 1篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 6篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 5篇 |
1985年 | 4篇 |
1984年 | 4篇 |
1982年 | 4篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 4篇 |
1977年 | 6篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1972年 | 2篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1927年 | 1篇 |
排序方式: 共有199条查询结果,搜索用时 15 毫秒
111.
Hannon MJ Painting CL Plummer EA Childs LJ Alcock NW 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(10):2225-2238
Multiple competing molecular interactions (metal-ligand, pi-stacking and hydrogen-bonding) in the silver(I) complexes of 4'-thiomethyl-2,2':6',2"-terpyridine give rise to a range of different molecular architectures, in which the metal-ligand coordination requirements are satisfied in quite different ways. Polynuclear supramolecular spirals, aggregated mononuclear and aggregated dinuclear units are all structurally characterised. The metallo-supramolecular architecture obtained displays a remarkable dependence both on the choice of non-coordinated anion and the type of solvent used (coordinating or non-coordinating). The anion dependence is particularly surprising, since the anions are not integrated into the centre of the supramolecular structure. The solution behaviour is also solvent and anion dependent, with aggregation of planar mononuclear cations observed in acetonitrile, but oligonuclear spiral species implicated in nitromethane. The extraordinarily variable geometries of these systems suggest that they provide a novel example of the "frustration" principle, in which opposing tendencies cannot simultaneously be satisfied and identify an alternative approach to the design of metallo-supramolecular systems whose structure is responsive to external agents. 相似文献
112.
Shape of the quantum diffusion front 总被引:1,自引:0,他引:1
Zhong J Diener RB Steck DA Oskay WH Raizen MG Plummer EW Zhang Z Niu Q 《Physical review letters》2001,86(12):2485-2489
We show that quantum diffusion has well-defined front shape. After an initial transient, the wave packet front (tails) is described by a stretched exponential P(x,t) = A(t)exp(-absolute value of [x/w](gamma)), with 1 < gamma < infinity, where w(t) is the spreading width which scales as w(t) approximately t(beta), with 0 < beta < or = 1. The two exponents satisfy the universal relation gamma = 1/(1-beta). We demonstrate these results through numerical work on one-dimensional quasiperiodic systems and the three-dimensional Anderson model of disorder. We provide an analytical derivation of these relations by using the memory function formalism of quantum dynamics. Furthermore, we present an application to experimental results for the quantum kicked rotor. 相似文献
113.
A new typical orientation pattern of polyethylene has been observed in extruded, melt-drawn composites containing 10% polyethylene and 90% polystyrene. In these composites, the polyethylene phase is dispersed in the polystyrene matrix as thin, long ribbons (width 1000 Å, thickness 500 Å). The b axis of the crystallites is found oriented preferentially along the long dimension of the ribbons, i.e., in the extrusion direction. The a and c axes of the crystallites show no preferred orientation. This texture pattern is attributed to the fact that, in view of the small cross section of the polyethylene phase, crystallization can proceed only along the long axis of the ribbons. Since the b axis is the direction of fastest growth in polyethylene (and the radial direction in a spherulite), most polyethylene unit cells are oriented with their b axes in the long dimension of the ribbons. 相似文献
114.
A convergent, second generation formal synthesis of (+)-Leucascandrolide A (1) has been efficiently achieved by providing a flexible, enantiocontrolled strategy toward the bioactive macrolactone component. Advancements for stereocontrol in asymmetric allylation methodology are discussed. Efforts feature novel results for reductions using the Terashima hydride reagent. [structure: see text] 相似文献
115.
116.
We propose that the indirect adatom-adatom interaction mediated by the conduction electrons of a metallic surface is responsible for the sqrt[3]xsqrt[3]<==>3x3 structural phase transitions observed in Sn/Ge (111) and Pb/Ge (111). When the indirect interaction overwhelms the local stress field imposed by the substrate registry, the system suffers a phonon instability, resulting in a structural phase transition in the adlayer. Our theory is capable of explaining all the salient features of the sqrt[3]xsqrt[3]<==>3x3 transitions observed in Sn/Ge (111) and Pb/Ge (111), and is in principle applicable to a wide class of systems whose surfaces are metallic before the transition. 相似文献
117.
The solution-phase photodimerization of acephenanthrylene (1) in cyclohexane, chloroform, dibromomethane, and ethyl iodide with visible light (lambda = 419 nm) occurs to form cis (2) and trans (3) photodimers in ratios that vary with the solvent and with the presence or absence of oxygen. The photodimerization exhibits a significant heavy atom effect and also is sensitive to selective quenching by dissolved oxygen, in which only cis stereoisomers are produced. Irradiation of the dimers (lambda = 254 nm) shows that the trans dimers cleave more rapidly than the cis dimers. This is attributed to stabilization of the excited state in the cis dimers. 相似文献
118.
119.
Dai P Fernandez-Baca JA Wakabayashi N Plummer EW Tomioka Y Tokura Y 《Physical review letters》2000,85(12):2553-2556
We use neutron scattering to demonstrate the presence of lattice polarons and their short-range correlations for several samples of La1-xCaxMnO3 in the Ca doping range 0.15=x=0.3. We establish the doping dependence of the orientation, commensuration, and coherence length of the polaron correlations and show that the populations of correlated and uncorrelated polarons are intimately related to the transport properties of the materials. 相似文献
120.
Qian Dong Ariadna J.Torres-Arenas Guo-Hua Sun Shi-Hai Dong 《Frontiers of Physics》2020,15(1):13401-64
Complex oxide interfaces have been one of the central focuses in condensed matter physics and ma-terial science.Over the past decade,aberration corrected scanning transmission electron microscopy and spectroscopy has proven to be invaluable to visualize and understand the emerging quantum phenomena at an interface.In this paper,we briefly review some recent progress in the utilization of electron microscopy to probe interfaces.Specifically,we discuss several important challenges for electron microscopy to advance our understanding on interface phenomena,from the perspective of variable temperature,magnetism,electron energy loss spectroscopy analysis,electronic symmetry,and defects probing. 相似文献