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991.
Marchenko AV Vedernikov AN Dye DF Pink M Zaleski JM Caulton KG 《Inorganic chemistry》2002,41(16):4087-4089
The reaction of RuHCl(CO)L(2) (L = P(i)Pr(3)) with NO initially forms a 1:1 adduct, shown by DFT calculations and EPR spectroscopy (including the RuD isotopomer) to contain a bent ( 90 degree angle Ru-N-O = 143.9 degrees ) nitrosyl where the majority of the spin density is on the nitrosyl nitrogen. This radical adduct transforms further to give equimolar RuCl(NO)(CO)L(2) and RuHCl(HNO)(CO)L(2), the latter with hydride trans to the nitroxyl ligand HN=O. This is the first observation of the synthesis of coordinated HNO from NO itself. DFT calculations lead to the proposal that this H-atom transfer is effected by free NO, and the lifetime of RuHCl(HNO)(CO)L(2) is indeed qualitatively dependent on the presence of free NO. 相似文献
992.
Andrei Golov Sergei Sekatskii 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1993,27(4):349-355
Bound electron states with a charged helium cluster are considered for the first time. They are characterized by a hydrogen-like spectrum and allow precise investigation of highly excited states. Depending on the cluster radius, the energy levels have been calculated, the stability of this “atom” has been studied. The scope of experimental observation of such objects is under discussion. 相似文献
993.
New sulfonamide-derived hydroxamic acids have been developed as chiral ligands for the V-catalysed asymmetric epoxidation, showing high reactivity at subzero temperatures and moderate to good enantioselectivity. The strong accelerating effect exhibited by the ligands of this type can be attributed to the sulfonamide functionality. A range of cinnamyl type allylic alcohols were epoxidised with up to 74% ee. 相似文献
994.
Jian Chen Dirk Steenackers Andrei Medvedovici Pat Sandra 《Journal of separation science》1993,16(10):605-608
The effect of column temperature on the separation of the sixteen polycyclic aromatic hydrocarbons (PAHs) of mixture SRM 1647a of the US Environmental Protection Agency has been studied on different micropacked ODS columns. Isothermal temperature optimization was successfully used for complete separation of the PAHs on a polymeric ODS stationary phase, whereas temperature programmed conditions were selected for separation on a monomeric ODS stationary phase. 相似文献
995.
Meshkov VV Pazyuk EA Zaitsevskii A Stolyarov AV Brühl R Zimmermann D 《The Journal of chemical physics》2005,123(20):204307
Direct deperturbation analysis of the highly accurate experimental rovibronic term values of the A (2)Pi approximately B (2)Sigma(+) complex of LiAr [R. Bruhl and D. Zimmermann, J. Chem. Phys. 114, 3035 (2001)] has been performed in the framework of inverted close-coupling approach implicitly adjusted to the unified treatment of the overall A approximately B coupling effect without reducing the rovibrational dimensionality. The nonlinear fitting procedure was supported by the ab initio calculations on the spin-orbit and angular coupling matrix elements between the lowest X (2)Sigma(+), A (2)Pi, and B (2)Sigma(+) states. The analytical grid mapping based on the reduced variable representation of the radial coordinate r was used to improve the efficiency of the solution of the close-coupling radial equations near the dissociation limit. The mutual A approximately X perturbation effect on the A (2)Pi term values and spin-rotation splitting of the ground state were evaluated for both (7,6)LiAr isotopomers. The resulting empirical potential-energy curves for the adiabatic A (2)Pi and B (2)Sigma(+) states, along with the refined r-dependent nonadiabatic matrix elements, reproduce the total rovibronic structure of the (7)LiAr complex with the standard deviation of 0.003 cm(-1). The mass invariance of the deperturbed electronic parameters was confirmed by the calculation of the rovibronic term values of the (6)LiAr isotopomer which coincided with their experimental counterparts within 0.004 cm(-1). 相似文献
996.
Jack W. Jordan Kayleigh L. Y. Fung Stephen T. Skowron Christopher S. Allen Johannes Biskupek Graham N. Newton Ute Kaiser Andrei N. Khlobystov 《Chemical science》2021,12(21):7377
We induce and study reactions of polyoxometalate (POM) molecules, [PW12O40]3− (Keggin) and [P2W18O62]6− (Wells–Dawson), at the single-molecule level. Several identical carbon nanotubes aligned side by side within a bundle provided a platform for spatiotemporally resolved imaging of ca. 100 molecules encapsulated within the nanotubes by transmission electron microscopy (TEM). Due to the entrapment of POM molecules their proximity to one another is effectively controlled, limiting molecular motion in two dimensions but leaving the third dimension available for intermolecular reactions between pairs of neighbouring molecules. By coupling the information gained from high resolution structural and kinetics experiments via the variation of key imaging parameters in the TEM, we shed light on the reaction mechanism. The dissociation of W–O bonds, a key initial step of POM reactions, is revealed to be reversible by the kinetic analysis, followed by an irreversible bonding of POM molecules to their nearest neighbours, leading to a continuous tungsten oxide nanowire, which subsequently transforms into amorphous tungsten-rich clusters due to progressive loss of oxygen atoms. The overall intermolecular reaction can therefore be described as a step-wise reductive polycondensation of POM molecules, via an intermediate state of an oxide nanowire. Kinetic analysis enabled by controlled variation of the electron flux in TEM revealed the reaction to be highly flux-dependent, which leads to reaction rates too fast to follow under the standard TEM imaging conditions. Although this presents a challenge for traditional structural characterisation of POM molecules, we harness this effect by controlling the conditions around the molecules and tuning the imaging parameters in TEM, which combined with theoretical modelling and image simulation, can shed light on the atomistic mechanisms of the reactions of POMs. This approach, based on the direct space and real time chemical reaction analysis by TEM, adds a new method to the arsenal of single-molecule kinetics techniques.We induce and study reactions of polyoxometalate (POM) molecules, [PW12O40]3− (Keggin) and [P2W18O62]6− (Wells–Dawson), at the single-molecule level, utilising TEM as an analytical tool, and nanotubes as test tubes. 相似文献
997.
Fábio Andrei Duarte Juliana Severo Fagundes PereiraMárcia Foster Mesko Fabiane GoldschmidtÉrico Marlon de Moraes Flores Valderi Luiz Dressler 《Spectrochimica Acta Part B: Atomic Spectroscopy》2007
This work describes an arsenic speciation analysis in aqueous effluent from a shale industrial plant using liquid chromatography coupled to inductively coupled plasma mass spectrometry (LC–ICP–MS). Arsenic species have been separated through an anion-exchange column and several parameters investigated, such as retention time, pH, flow rate and concentration of the mobile phase (ammonium carbonate), chloride interference and column conditioning time. The best conditions have been found by fixing the pH of the mobile phase at 8.7. Keeping the mobile phase flow rate at 1.5 ml min− 1, arsenic species were separated by varying the concentration of the mobile phase and the time of elution, as follow: 1.5 mmol l− 1 for 10 min, 12 mmol l− 1 for 10 min and 20 mmol l− 1 for 10 min, respectively. Up to 13 As species present in the samples were separated under these conditions and the following species could be identified and quantified: arsenite [As(III)], dimethylarsinic acid (DMA), monomethylarsonic acid (MMA) and arsenate [As(V)]. The limits of detection of the LC–ICP–MS method were 0.02, 0.06, 0.04 and 0.10 μg l− 1 of As(III), DMA, MMA, and As(V), respectively. The concentration of these species in the samples were from 3.7 to 6.4 μg l− 1, 6.9 to 13.2 μg l− 1, 100 to 142 μg l− 1 and 808 to 1363 μg l− 1 for As(III), DMA, MMA and As(V), respectively. The accuracy, evaluated by recovery tests, varied from 94 to 105% and the precision, evaluated by the relative standard deviation was typically lower than 10%. 相似文献
998.
Bordunov AV Bradshaw JS Zhang XX Dalley NK Kou X Izatt RM 《Inorganic chemistry》1996,35(25):7229-7240
New 5-chloro-8-hydroxyquinoline (CHQ)-substituted aza-18-crown-6 (4), diaza-18-crown-6 (1), diaza-21-crown-7 (2), and diaza-24-crown-8 (3) ligands, where CHQ was attached through the 7-position, and aza-18-crown-6 (11) and diaza-18-crown-6 (10) macrocycles, where CHQ was attached through the 2-position, were prepared. Thermodynamic quantities for complexation of these CHQ-substituted macrocycles with alkali, alkaline earth, and transition metal ions were determined in absolute methanol at 25.0 degrees C by calorimetric titration. Two isomers, 1 and 10, which are different only in the attachment positions of the CHQ to the parent macroring, exhibit remarkable differences in their affinities toward the metal ions. Compound 1 forms very stable complexes with Mg(2+), Ca(2+), Cu(2+), and Ni(2+) (log K = 6.82, 5.31, 10.1, and 11.4, respectively), but not with the alkali metal ions. Ligand 10 displays strong complexation with K(+) and Ba(2+) (log K = 6.61 and 12.2, respectively) but not with Mg(2+) or Cu(2+). The new macrocycles and their complexes have been characterized by means of UV-visible and (1)H NMR spectra and X-ray crystallography. New peaks in the UV spectrum of the Mg(2+)-1 complex could allow an analytical determination of Mg(2+) in very dilute solutions in the presence of other alkali and alkaline earth metal cations. (1)H NMR spectral and X-ray crystallographic studies indicate that ligand 10 forms a cryptate-like structure when coordinated with K(+) and Ba(2+), which induces an efficient overlap of the two hydroxyquinoline rings. Such overlapping forms a pseudo second macroring that results in a significant increase in both complex stability and cation selectivity. 相似文献
999.
A range of new functionalised 9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene (TTFAQ) derivatives have been synthesised from the key di(halomethyl) building blocks, 10-[4,5-bis(bromomethyl)-1,3-dithiol-2-ylidene]-anthracene-9(10H)-one 10, 10-[4,5-bis(chloromethyl)-1,3-dithiol-2-ylidene]anthracene-9(10H)-one 11 and 9-[4,5-bis(chloromethyl)-1,3-dithiol-2-ylidene]-10-[4,5-bis(hexylsulfanyl)- 1,3-dithiol-2-ylidene]-9,10-dihydroanthracene 18. A Diels-Alder strategy comprising trapping of the transient exocyclic diene 19, which is derived from 18, with 1,4-naphthoquinone leads to the aromatised TTFAQ anthraquinone system 21. Horner-Wadsworth-Emmons olefination of 21 with the anion generated from reagent 22 gave the fused bis(TTFAQ) structure 23. Pyrrolo-annelated derivatives 30-34 have been obtained in a sequence of reactions from compound 10. Mono-formylation of the pyrrole ring of 32 and 33 under Vilsmeier conditions gave 35 and 36 which upon reaction with 2,4,5,7-tetranitrofluorene gave the donor-pi-acceptor diads 38 and 39. Cyclic voltammetry (CV) in solution for all the TTFAQ derivatives shows the typical quasi-reversible two-electron oxidation wave of the TTFAQ core at potentials which vary slightly depending on the substituents. For example, the value of Eox is raised by the electron withdrawing anthraquinone and tetranitrofluorene units of 21 and 38, respectively. The CV of the conjugated TTFAQ dimer 23 showed two, two-electron oxidation waves corresponding to the sequential formation of 23(2+) and 23(4+) (delta Eox = 130 mV) providing evidence for a significant intramolecular electronic interaction, i.e. the dication 23(2+) acts as a conjugated donor-pi-acceptor diad, thereby raising the oxidation potential of its partner TTFAQ unit. Spectroelectrochemical studies on 23 support this explanation. A strong intramolecular charge transfer band at lambda max 538 nm is seen in the UV-Vis spectra of the TTFAQ-pi-tetranitrofluorene diads 38 and 39. The X-ray crystal structures are reported for compounds 30, 33 and 34. The pyrrolo-TTFAQ moiety adopts a saddle-shape with the central ring of the dihydroanthracene moiety folded along the C(9) ... C(10) vector in each case. Significant intermolecular interactions are observed in the structures. 相似文献
1000.
Capillary electrophoresis of platinum-group elements. Analytical, speciation and biochemical studies 总被引:1,自引:0,他引:1
A great deal of research has been carried out in recent years on developing high-efficiency capillary electrophoresis (CE) techniques that are able to separate rapidly and selectively ionic platinum metal species in a wide variety of their complexed forms. Using a range of illustrative examples, this review examines the potential and utilization of various CE separation approaches and detection modes in this expanding area. Also covered are CE procedures suitable for solving practical analytical problems and for platinum metal speciation purposes. Presenting a comprehensive treatise on the evolving practices of CE concerning platinum anticancer drugs--in particular, the examination of the stability of intact drugs, the separation and identification of products of their metabolism and interactions with biomolecules (including kinetic studies of the binding behavior)--this paper witnesses a welcome shift of the main research activities to those performed under physiological conditions. 相似文献