_f-A_aD_d氢键体系的统计特征

基于氢键的形成和缩聚反应机理在统计意义下的相似性,利用高分子反应统计理论和反应动力学理论对氢键溶液的一个模型体系进行了相关讨论.给出了体系的溶胶分数和发生溶胶-凝胶相变的条件,指出质子受体基团间的竞争作用对溶胶凝胶相变点的影响,进而讨论了体系的数量分布函数和相关问题.     

AB_3型超支化聚(酰胺-酯)的合成及缩聚动力学研究

采用丁二酸酐、三羟甲基氨基甲烷为主要原料 ,在冰水浴条件下 ,合成AB3型单体 ,然后进行熔融缩聚制得超支化聚 (酰胺 酯 ) ,没有出现凝胶现象 .采用Fourier变换红外谱仪 (FTIR)、粘度测试、端基分析等方法对其结构、特性粘数进行了表征 .同时对AB3型超支化聚 (酰胺 酯 )的缩聚反应动力学进行了研究 ,得出了130℃、14 0℃和 15 0℃时的缩聚反应速率常数 ,并进一步得出了缩聚反应活化能 .实验结果证明缩聚过程为自催化过程 ,且为三级反应     

Vibrational spectroscopies for the analysis of cutaneous permeation: experimental limiting factors identified in the case of caffeine penetration

Caffeine is utilised as a reference for permeation studies in dermatology and cosmetology. The present work aimed to monitor the permeation of a caffeine solution through the skin. For this purpose, Raman and infrared studies were performed. Raman microspectroscopy permitted a dynamic follow-up of the caffeine diffusion. In complementary, infrared microimaging provided information of the caffeine localization in the skin by applying multivariate statistical processing on skin tissue sections. Herein, we prove the possibility of tracking low concentrations of caffeine through the skin and we highlight some experimental limitations of vibrational spectroscopies.     

阴离子型微乳液对火焰原子吸收法测铅增敏作用的研究与应用

研究了在空气－乙炔火焰中，阴离子型表面活性剂十二烷基硫酸钠（ＳＤＳ）组成的微乳液对铅原子化行为的影响。结果表明：在ＳＤＳ组成的微乳液存在下，铅的灵敏度提高了近６０％，比ＳＤＳ胶束存在下灵敏度也提高了２０％。方法用于黄铅和工业废水中铅的测定，结果令人满意。     

异质Stackelberg寡头竞争下创新产品技术许可策略研究

基于异质产品Stackelberg寡头竞争模型,建立了拥有新产品创新技术在位厂商与潜在竞争对手间的技术许可博弈模型.模型中假设潜在竞争对手可以接受许可,也可通过自我研发创新技术进入市场参与竞争.根据潜在竞争对手研发成本的高低,研究了创新厂商的最优两部制收费策略.研究结果表明:潜在竞争者总会接受创新技术许可,最优许可策略依赖于研发成本、市场参数以及产品的替代系数.     

养护条件对UHPC强度和毛细吸水性的影响

为优化超高性能混凝土(UHPC)预制构件养护工艺,研究了不同养护条件对UHPC强度和毛细吸水性的影响,并采用孔结构测试、热重分析和扫描电镜观察,对其机理进行了分析.结果表明:热养护显著提高了UHPC的7 d强度,这与加速火山灰反应有关,但高温和干热养护对其后期强度增大不利,甚至出现约3％的强度倒缩;不论何种养护,UHP...     

Statistical theory for hydrogen bonding fluid system of AaDd type (Ⅲ): Equation of state and fluctuations

The equation of the state of the hydrogen bonding fluid system of AaDd type is studied by the principle of statistical mechanics. The influences of hydrogen bonds on the equation of state of the system are obtained based on the change in volume due to hydrogen bonds. Moreover, the number density fluctuations of both molecules and hydrogen bonds as well as their spatial correlation property are investigated. Furthermore, an equation describing relation between the number density correlation function of "molecules-hydrogen bonds" and that of molecules and hydrogen bonds is derived. As application,taking the van der Waals hydrogen bonding fluid as an example, we considered the effect of hydrogen bonds on its relevant statistical properties.     

Semi-preparative purification and characterization of peptides from complex haemoglobin hydrolysate by HPLC-mass spectrometry

Summary An important goal of previous high-performance liquid chromatography (HPLC) studies was the development of a simple procedure for the purification of peptides from very complex haemoglobin enzymatic hydrolysates. This report demonstrates that the separation system described can be used for large sample loadings at laboratory preparative scale (more than 50 mg) without loss of resolution. The efficiency of peptide purification was shown by fast atom bombardment-mass spectrometry (FAB-MS) and tandem mass spectrometry (tandem M S). The procedure described will be of interest in the biotechnology area for the extensive preparation of peptides for fine applications from complex enzymatic hydrolysates.     

茂钇-铝双金属配合物催化甲基丙烯酸甲酯立规聚合

立规聚合;茂稀土催化剂;稀土;茂钇-铝双金属配合物催化甲基丙烯酸甲酯立规聚合