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941.
François Golanski Véronique Fortuné Eric Lamballais 《Theoretical and Computational Fluid Dynamics》2005,19(6):391-416
The ability of Lighthill's analogy to predict the sound radiated by a transitional mixing layer is evaluated by means of direct
numerical simulation (DNS). The specific case of low Mach number flows with density variations is investigated. In order to
limit the global computational cost, the acoustic source information is based on numerical results where the sound waves have
been removed. It is shown that the low Mach number approximation coupled with the acoustic analogy can lead to very accurate
predictions for the radiated sound if the acoustic sources in Lighthill's equation are taken into account carefully. Results
for the acoustic intensity deduced from a repeated use of the Lighthill's analogy over a wide range of Mach numbers allow
us to discuss the adequacy of scaling laws proposed by previous authors (J. Sound Vib. 28(3), 563–585, 1973; 31(4), 391–397, 1973; 48(1), 95–111, 1976) for the prediction of noise from hot jets. 相似文献
942.
Paulo B. Gonçalves Frederico M. A. Silva Zenón J. G. N. Del Prado 《Nonlinear dynamics》2007,50(1-2):121-145
In the present study, the large-amplitude vibrations and stability of a perfect circular cylindrical shell subjected to axial
harmonic excitation in the neighborhood of the lowest natural frequencies are investigated. Donnell's shallow shell theory
is used and the shell spatial discretization is obtained by the Ritz method. An efficient low-dimensional model presented
in previous publications is used to discretize the continuous system. The main purpose of this work is to discuss the use
of basins of attraction as a measure of the reliability and safety of the structure. First, the nonlinear behavior of the
conservative system is discussed and the basin structure and volume is understood from the topologic structure of the total
energy and its evolution as a function of the system parameters. Then, the behavior of the forced oscillations of the harmonically
excited shell is analyzed. First the stability boundaries in force control space are obtained and the bifurcation events connected
with these boundaries are identified. Based on the bifurcation diagrams, the probability of parametric instability and escape
are analyzed through the evolution and erosion of basin boundaries within a prescribed control volume defined by the manifolds.
Usually, basin boundaries become fractal. This together with the presence of catastrophic subcritical bifurcations makes the
shell very sensitive to initial conditions, uncertainties in system parameters, and initial imperfections. Results show that
the analysis of the evolution of safe basins and the derivation of appropriate measures of their robustness is an essential
step in the derivation of safe design procedures for multiwell systems. 相似文献
943.
In this paper, we show that the maximum principle holds for quasilinear elliptic equations with quadratic growth under general structure conditions.Two typical particular cases of our results are the following. On one hand, we prove that the equation (1) {ie77-01} where {ie77-02} and {ie77-03} satisfies the maximum principle for solutions in H
1()L(), i.e., that two solutions u
1, u
2H1() L() of (1) such that u
1u2 on , satisfy u
1u2 in . This implies in particular the uniqueness of the solution of (1) in H
0
1
()L().On the other hand, we prove that the equation (2) {ie77-04} where fH–1() and g(u)>0, g(0)=0, satisfies the maximum principle for solutions uH1() such that g(u)¦Du|{2L1(). Again this implies the uniqueness of the solution of (2) in the class uH
0
1
() with g(u)¦Du|{2L1().In both cases, the method of proof consists in making a certain change of function u=(v) in equation (1) or (2), and in proving that the transformed equation, which is of the form (3) {ie77-05}satisfies a certain structure condition, which using ((v1
-v
2)+)n for some n>0 as a test function, allows us to prove the maximum principle. 相似文献
944.
José A. Ferreira Gonçalo Pena 《Numerical Methods for Partial Differential Equations》2015,31(5):1589-1602
Diffusion processes are usually simulated using the classical diffusion equation. In certain scenarios, such equation induces anomalous behavior and consequently several improvements were introduced in the literature to overcome them. One of the most popular was the replacement of the diffusion equation by an integro‐differential equation. Such equation can be established considering a modification of Fick's mass flux where a delay in time is introduced. In this article, we consider mathematical models for diffusion processes that take into account a memory effect in time and space. © 2015 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 31: 1589–1602, 2015 相似文献
945.
Thayana da C. Alves Mariele R. S. Gonçalves Francyne C. S. Correia Virgínia C. da Silva Paulo T. de Sousa Jr. Mário G. de Carvalho Raimundo Braz‐Filho Evandro L. Dall'Oglio 《Helvetica chimica acta》2014,97(11):1469-1474
From the hexane and MeOH extracts of Annona coriacea Mart . (Annonaceae) seeds, two novel acetogenins, coriapentocins A and B ( 1 and 2 , resp.) were isolated. The known acetogenin bullacin ( 3 ) was also isolated from the hexane extract. The structures of compounds 1 – 3 were elucidated by NMR and MS analysis, and relative configurations were established by comparison with literature data. 相似文献
946.
Dirk T.S. Rijkers Fernando de Prada LópezRob M.J. Liskamp François Diederich 《Tetrahedron letters》2011,52(51):6963-6967
We report on the chemoselective coupling between colorless peptide fragments functionalized with a mutually reactive electron-rich Nα-(4-ethynylphenyl)-Nα-(methyl)-glycyl- and an electron-deficient [4-(2,2-dicyanovinyl)]benzoyl moiety. The resulting donor-substituted 1,1-dicyanobuta-1,3-dienes represent a new class of orange-red colored (λmax = 450-500 nm, with molar extinction coefficients (ε) above 5,000 mol−1 dm3 cm−1) peptide-based imaging chromophores. 相似文献
947.
The combination of electrophoretic and magnetic manipulations with electrochemical detection for a versatile microfluidic and bead-based biosensing application is demonstrated. Amperometric detection is performed in an off-channel setup by means of a voltammetric cell built at the microchannel outlet and using a gold working electrode. Superparamagnetic particles are introduced and handled inside the channel by means of an external permanent magnet in combination with the electrogenerated flow which allows reproducible loading. The specific detection of phenol as electroactive alkaline phosphatase product is used in this study as proof of concept for a sensitive protein quantification. Characterizations and optimization of different parameters have been carried out in order to achieve the best detection signal. The applicability of the device has been finally demonstrated by the detection of rabbit IgG as model protein after an immunoassay performed on magnetic particles as immobilization platform. A comparison between the electrochemical detection using the developed device and the optical standard detection revealed similar performances with, however, extremely lower amount of reagent used and shorter analysis time. The developed electrophoretic- and magnetic-based chip may open the way to several other biosensing applications with interest not only for other proteins but also for DNA analysis, cell counting, and environmental control. 相似文献
948.
Cemal Özeroğlu Emine Doğan Gönül Keçeli 《Journal of Radioanalytical and Nuclear Chemistry》2011,289(2):577-586
In this study, a crosslinked copolymer bearing sodium methacrylate functional groups has been proposed to remove Cs(I) ions
from aqueous solutions. For this purpose, the crosslinked copolymer of ethylene glycol dimethacrylate (EGDM) and methacrylic
acid (MA) containing 25% MA as weight percentage was synthesized by using benzoyl peroxide (BPO)-N,N-dimethyl aniline initiator system. The available carboxyl groups in copolymer were converted to the groups of sodium methacrylate
using 2 N NaOH. The adsorption behavior of cesium ions on the densely crosslinked poly(sodium methacrylate) from aqueous solutions
were investigated by the technique of ICP-MS measurements of cesium ions in solutions. Batch adsorption method was used to
analyze the Cs(I) adsorption as a function of parameters such as the amount of adsorbent, contact time, pH of solution, initial
Cs(I) concentration and temperature. The adsorption data were evaluated by the Freundlich, Langmuir and Dubinin–Radushkevich
(D–R) isotherms. The adsorption capacity and free energy change were calculated by using D–R isotherm. The adsorption data
obtained from experimental results have been tested by the fractional power, the Elovich, the pseudo-first order and the pseudo-second
order kinetic models. 相似文献
949.
Abdelmounaim Safer Mustapha Rahmouni François Carreaux Ludovic Paquin Olivier Lozach Laurent Meijer Jean Pierre Bazureau 《Chemical Papers》2011,65(3):332-337
A series of nine 5-arylidenerhodanine derivatives was prepared in good yields and purity without the use of a solvent or catalyst
under microwave-assisted condensation with some substituted isatins. All 5-arylidenerhodanines were evaluated as possible
inhibitors of the CK1α/β, CDK5/p25, and GSK-3α/β kinases. None of them showed substantive inhibitory activity against these kinases when evaluated at the concentration of
10 μM. 相似文献
950.
Genç R Clergeaud G Ortiz M O'Sullivan CK 《Langmuir : the ACS journal of surfaces and colloids》2011,27(17):10894-10900
There has been enormous interest in the last decade in development methods for the inorganic synthesis of metallic nanoparticles of desired sizes and shapes because of their unique properties and extensive applications in catalysis, electronics, plasmonics, and sensing. Here we report on an environmentally friendly, one-pot synthesis of metallic nanoparticles, which avoids the use of organic solvents and requires mild experimental conditions. The developed method uses liposomes as nanoreactors, where the liposomes were prepared by encapsulating chloroauric acid and exploited the use of glycerol, incorporated within the lipid bilayer as well as in its hydrophilic core, as a reducing agent for the controlled preparation of highly homogeneous populations of gold nanoparticles. The effects of temperature, the presence of a capping agent, and the concentration of glycerol on the size and homogeneity of the nanoparticles formed were investigated and compared with solution-based glycerol-mediated nanoparticle synthesis. Well-distributed gold nanoparticle populations in the range of 2-8 nm were prepared in the designed liposomal nanoreactor with a clear dependence of the size on the concentration of glycerol, the temperature, and the presence of a capping agent whereas large, heterogeneous populations of nanoparticles with amorphous shapes were obtained in the absence of liposomes. The particle morphology and sizes were analyzed using transmission electron microscopy imaging, and the liposome size was measured using photon correlation spectroscopy. 相似文献