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131.
Chemical models of genetic toggle switches 总被引:2,自引:0,他引:2
132.
Gerrit L'abb Maria Bruynseels Pieter Delbeke Suzanne Toppet 《Journal of heterocyclic chemistry》1990,27(7):2021-2027
The two structural isomers, 4 and 5 , of 1-substituted-4-iminomethyl-1,2,3-triazoles are interconvertible when heated in dimethyl sulfoxide at 80°. The equilibrium position depends on the electronic properties of the R-substituent, favoring 5 for R = alkyl, benzyl and anisyl, and 4 for p-chlorophenyl and p-nitrophenyl. An interesting application is the synthesis of 1-alkyl-1,2,3-triazole-4-carbaldehydes from 1-phenyl-1,2,3-triazole-4-carbaldehyde by Scheme I. The hydrazones 4ij and the oxime 4k do not rearrange due to an unfavorable Z-configuration around the C ? N bond, whereas the acyloximino derivative 4m is converted into the nitrile 11 . The structures of the products have been fully characterized by 13C nmr spectroscopy and the mechanistic details of the rearrangement are discussed. 相似文献
133.
Magusin PC Zorin VE Aerts A Houssin CJ Yakovlev AL Kirschhock CE Martens JA van Santen RA 《The journal of physical chemistry. B》2005,109(48):22767-22774
Species at three stages in the self-assembly of zeolite ZSM-5 have been studied with one- and two-dimensional magic-angle-spinning 13C, 27Al, 29Si, and 1H NMR spectroscopy and compared with the earlier proposed structures: (1) precursor species containing 33-36 T sites around a tetrapropylammonium (TPA) cation, (2) nanoslabs consisting of a flat 4 x 3 array of such precursors, and (3) the final TPA-ZSM-5 zeolite. Synthesis was carried out in D2O to suppress the water and silanol protons. Under such conditions, the effective Si-H and Al-H distances measured with 29Si-{1H} and 27Al-{1H} rotational echo double resonance (REDOR) reflect the interactions between TPA cations and the surrounding aluminosilica. The 29Si-{1H} REDOR curves for Q4-type silicon atoms at the three mentioned stages are closely similar, as well as the observed 27Al-1H REDOR curve for the precursor species compared to that for the TPA-ZSM-5. This indicates that in addition to externally attached TPA, there is also internal TPA already incorporated at an early stage into the aluminosilicate in a similar way as in the final zeolite, in accordance with the earlier proposed MFI self-assembly pathway (Kirschhock et al. Angew. Chem. Int. Ed. 2001, 40, 2637). However, the effective distances extracted from the initial REDOR curvatures are significantly (10-15%) larger than those computed for the model. Since there is no temperature effect, we tentatively assign this difference to a reduction of the 29Si-1H and 27Al-1H interactions by multispin decoherence effects or self-decoupling caused by proton spin diffusion. By assuming the computed model distances and fitting Anderson-Weiss curves to the observed REDOR data, we obtain similar "decoherence times" in the order of 0.1 ms. The observed 29Si-{1H} REDOR dephasing for the Q3 sites in the precursors is significantly faster than that for the Q4 sites. This is tentatively ascribed to a partial deuteron-proton back exchange at the silanol positions. 相似文献
134.
We analyze the efficiency of several simulation methods which we have recently proposed for calculating rate constants for rare events in stochastic dynamical systems in or out of equilibrium. We derive analytical expressions for the computational cost of using these methods and for the statistical error in the final estimate of the rate constant for a given computational cost. These expressions can be used to determine which method to use for a given problem, to optimize the choice of parameters, and to evaluate the significance of the results obtained. We apply the expressions to the two-dimensional nonequilibrium rare event problem proposed by Maier and Stein [Phys. Rev. E 48, 931 (1993)]. For this problem, our analysis gives accurate quantitative predictions for the computational efficiency of the three methods. 相似文献
135.
136.
137.
Cornelis J. Elsever Pieter Imhoff 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4):405-408
Abstract The synthesis and structure of new metallacyclic compounds of Rh(I) and Ir(I) containing bidentate mono- and bis(iminophosphoranyl)methane or -methanide ligands and their reactions with CO, phosphine and HCl are described. 相似文献
138.
Pieter L. H. Verlooy Koen Robeyns Luc Van Meervelt Christine E. A. Kirschhock Johan A. Martens 《Acta Crystallographica. Section C, Structural Chemistry》2010,66(12):o619-o622
The title compound, 6C13H24N+·H2Si8O206−·44H2O, belongs to the class of cyclosilicate hydrates, which structurally can be positioned between the zeosils and the clathrate hydrates. [Si8O18(OH)2] cubes carrying six negative charges are located on crystallographic inversion centres and are surrounded by six adamantyltrimethylammonium cations. 相似文献
139.
Pieter J. Gilissen Annemiek D. Slootbeek Jiangkun Ouyang Nicolas Vanthuyne Rob Bakker Johannes A. A. W. Elemans Roeland J. M. Nolte 《Chemical science》2021,12(5):1661
The construction of macromolecular hosts that are able to thread chiral guests in a stereoselective fashion is a big challenge. We herein describe the asymmetric synthesis of two enantiomeric C2-symmetric porphyrin macrocyclic hosts that thread and bind different viologen guests. Time-resolved fluorescence studies show that these hosts display a factor 3 kinetic preference (ΔΔG‡on = 3 kJ mol−1) for threading onto the different enantiomers of a viologen guest appended with bulky chiral 1-phenylethoxy termini. A smaller kinetic selectivity (ΔΔG‡on = 1 kJ mol−1) is observed for viologens equipped with small chiral sec-butoxy termini. Kinetic selectivity is absent when the C2-symmetric hosts are threaded onto chiral viologens appended with chiral tails in which the chiral moieties are located in the centers of the chains, rather than at the chain termini. The reason is that the termini of the latter guests, which engage in the initial stages of the threading process (entron effect), cannot discriminate because they are achiral, in contrast to the chiral termini of the former guests. Finally, our experiments show that the threading and de-threading rates are balanced in such a way that the observed binding constants are highly similar for all the investigated host–guest complexes, i.e. there is no thermodynamic selectivity.Chiral guests display kinetic stereoselective threading through chiral porphyrin cages if their chirality is located at the chain ends and not in the centers, supporting the previously reported entron effect of threading. 相似文献
140.
We prove that there is a compact separable continuum that (consistently) is not a remainder of the real line.