全文获取类型
收费全文 | 6034篇 |
免费 | 204篇 |
国内免费 | 32篇 |
专业分类
化学 | 4144篇 |
晶体学 | 19篇 |
力学 | 209篇 |
数学 | 1029篇 |
物理学 | 869篇 |
出版年
2022年 | 33篇 |
2021年 | 59篇 |
2020年 | 65篇 |
2019年 | 80篇 |
2018年 | 85篇 |
2017年 | 79篇 |
2016年 | 153篇 |
2015年 | 141篇 |
2014年 | 169篇 |
2013年 | 264篇 |
2012年 | 326篇 |
2011年 | 369篇 |
2010年 | 233篇 |
2009年 | 231篇 |
2008年 | 331篇 |
2007年 | 324篇 |
2006年 | 333篇 |
2005年 | 302篇 |
2004年 | 262篇 |
2003年 | 241篇 |
2002年 | 287篇 |
2001年 | 106篇 |
2000年 | 102篇 |
1999年 | 58篇 |
1998年 | 58篇 |
1997年 | 65篇 |
1996年 | 76篇 |
1995年 | 53篇 |
1994年 | 65篇 |
1993年 | 56篇 |
1992年 | 50篇 |
1991年 | 58篇 |
1990年 | 47篇 |
1989年 | 44篇 |
1988年 | 39篇 |
1987年 | 45篇 |
1986年 | 39篇 |
1985年 | 84篇 |
1984年 | 83篇 |
1983年 | 51篇 |
1982年 | 86篇 |
1981年 | 56篇 |
1980年 | 77篇 |
1979年 | 56篇 |
1978年 | 74篇 |
1977年 | 56篇 |
1976年 | 56篇 |
1975年 | 42篇 |
1974年 | 44篇 |
1973年 | 33篇 |
排序方式: 共有6270条查询结果,搜索用时 15 毫秒
21.
22.
Tran Quang Minh Léon Christiaens Pierre Grandclaudon Alain Lablache-Combier 《Tetrahedron》1977,33(17):2225-2229
Photoirradiated in presence of acetophenone, benzo[b]selenophene and its 3-methyl derivative add to dimethyl acetylenedicarboxylate. In each ease, the primary reaction product is unstable and has not been isolated. Photoexeited in its triplet state (the energy of which is in the neighbourhood of 69 ) benzo[b]selenophene and its 2- and 3-methyl, 2,3 dimethyl, 3 acetoxy and 2-methyl-3-acetoxy derivatives add to 1,2 dichloroethylene leading to cyclobutanes. Neither cyclo-addition occurs in absence of photosensitiser. Single-crystal X-ray analysis gave the structures of the two adducts of 3-acetoxybenzo[b]selenophene with trans-1,2-dichloroethylene. In both compounds the chlorine atoms are trans. 相似文献
23.
24.
25.
Hydroboration of the syn, anti-[Fe(CO)3]2 double complex 24 of the readily available 5,6,7,8-tetramethylidene-2-bicyclo[2.2.2]octene ( 22 ) gave the corresponding doubly complexed 2-bicyclo[2.2.2]octanol 25. CrO3-oxidation furnished ketone 27 . The syn-Fe(CO)3-groups in 25 and 27 were oxidized selectively with trimethyl-amine oxide and yielded the corresponding anti-Fe(CO3)-monocomplexed tetraenes 26 and 28. The anti-Fe(CO)3-group in 28 could be removed, and 5,6,7,8-tetramethylidene-2-bicyclo[2.2.2]octanone ( 11 ) was obtained. NaBH4-reduction of 11 afforded tetraenol 10. TCE-cycloadditions to 10 and 11 (k1) were at least 10 times as fast as those (k2) to the corresponding monoadducts 35/36 and 34 , respectively. This Diels-Alder reactivity difference vanishes (k1 ≈ k2) with methyl propynoate. The latter dienophile added to the anti-Fe(CO)3-monocomplexed tetraenone 28 with ‘para’-regioselectivity. 相似文献
26.
To obtain the intrinsic acidity constant of a carboxylic ion-exchanger, we propose a method of graphical double extrapolation. The results for an ion-exchanger made of polyvinyl alcohol grafted with acrylic acid are close to those published for the corresponding linear polyacid. 相似文献
27.
H. Frunder D. Illig H. Finsterhölzl H.W. Schrōtter B. Lavorel G. Roussel J.C. Hilico J.P. Champion G. Pierre G. Poussigue E. Pascaud 《Chemical physics letters》1983,100(1):110-114
The CARS spectrum of the v1 band of 12CH4 at a pressure of 14 mbar was recorded using cw excitation in the cavity of a ring argon ion laser. The analysis of the intensity profile of the obarred spectrum led to the detection of inconsistencies with the hitherto proposed calculated positions of transitions with J = 7 to J = 10 and to a relocation of the corresponding lines. 相似文献
28.
Manijeh Mohraz Wang Jian-qi Edgar Heilbronner Pierre Vogel Olivier Pilet 《Helvetica chimica acta》1980,63(3):568-570
The photoelectron spectrum of the title compound is reported and assigned by correlation with the photoelectron spectra of related molecules. 相似文献
29.
Pierre Laszlo 《Angewandte Chemie (International ed. in English)》1978,17(4):254-266
With the availability of Fourier transform spectrometers, 23Na-NMR spectroscopy has become an important tool. It affords direct insight into solvation and ion pairing phenomena, both in organic and in bio-inorganic systems. Monitoring the chemical shifts and linewidths of 23Na signals gives access to binding constants, reorientational correlation times and the microdynamics of the sodium coordination shell. The binding of other cations can also be studied by 23Na-NMR spectroscopy, in competition experiments. 相似文献
30.
Claude Balny Jennifer Canva Pierre Douzou Jean Bourdon 《Photochemistry and photobiology》1969,10(6):375-382
Abstract— Chemiluminescence and photochemiluminescence of systems generating excited (singlet) molecular oxygen has been studied at low temperature in fluid media. A possible interpretation is proposed: that dimers of singlet oxygen are directly or indirectly responsible for the observed emission, the species [1 δg +1 σg+ ] predominating. Energy transfer to a fluorescent molecule is possible only when conditions of spectral overlap, required for transfer by inductive resonance, are fulfilled. Evidence is also presented for the formation of a transient complex between oxygen and a sensitiser or acceptor molecule [S…O2 ], which is the precursor of singlet oxygen in these systems. However, other possible mechanisms cannot be excluded. 相似文献