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71.
Fadila Balegroune Pierre Braunstein Laurent Douce Yves Dusausoy Daniel Grandjean Michael Knorr Martin Strampfer 《Journal of Cluster Science》1992,3(3):275-296
The reactions of K[Fe{Si(OMe)3}(CO)3(PY)][PY=Ph2PCH2C(O)Ph, Ph2PCH2C(O)[(-C5H4)FeCp] (Cp=5-C5H5), Ph2P(CH2)2CN] with CdCl2·2.5H2O, ZnX
2 (X=Cl, I) or InCl3 afforded Fe-Cd-Fe or Fe-M(-X)2
M-Fe (M=Cd, Zn, In;X=Cl, I) and Fe-InCl2 complexes. Some of them contain an unusual and labile -2-SiO alkoxysilyl bridge which may be associated with a bridging mode for the ketophosphine ligand (first such example structurally established), thus providing original results in bimetallic chemistry on the intramolecular coordination of oxygendonor functions ofchemically different hemilabile ligands firmly attached to a neighboring metal center. The structures of the trinuclear complex (3), of the chlorobenzene solvate of the tetranuclear complex (4a·C6H5Cl) and of [mer-(OC)3{(EtO)3Si} (4e) have been determined by X-ray diffraction. Crystals of 3 are orthorhombic, space groupPbcn, witha=19.010(4),b=11.766(5),c=26.998(7)Å, andZ=4. Crystals of4a·C6H5Cl are monoclinic, space groupC2/c witha=22.455(3),b=17.680(2),c=16.627(4)Å, =90.80(4)°, andZ=4. Crystals of4e are monoclinic, space groupC2/c witha=25.392(5),b=18.554(6),c=16.28(1)Å, =120.73(3)°, andZ=4. The structures were solved using direct methods and Fourier difference techniques and refined by blocked full-matrix least squares toR=0.035 (R
w
=0.049) for 2719 observed reflections, toR=0.042 (R
w
=0.056) for 3082 observed reflections, and toR=0.057 (R
w
=0.075) for 1850 observed reflections for3, 4a·C6H5Cl and4e, respectively. The Fe-Zn complexes (9a), (9b) and (9c) were prepared and characterized by spectroscopic methods.Part 21 in the Series: Complexes with Functional Phosphines. Part 20: P. Braunstein, S. Coco Cea, A. DeCian, and J. Fischer (1992).Inorg. Chem.
31, 4203. 相似文献
72.
P. Marage M. Aderholz P. Allport N. Armenise J. P. Baton M. Berggren D. Bertrand V. Brisson F. W. Bullock W. Burkot M. Calicchio E. F. Clayton T. Coghen A. M. Cooper-Sarkar O. Erriquez P. J. Fitch G. Gerbier J. Guy F. Hamisi P. O. Hulth G. T. Jones P. Kasper H. Klein R. P. Middleton D. B. Miller M. M. Mobayyen D. R. O. Morrison S. Natali M. Neveu S. W. O'Neale M. A. Parker P. Petiau J. Sacton R. A. Sansum E. Simopoulou C. Vallée K. Varvell A. Vayaki W. Venus H. Wachsmuth J. Wells W. Wittek BEBC WA Collaboration 《Zeitschrift fur Physik C Particles and Fields》1986,31(2):191-197
The cross section for coherent production of a single π? meson in charged current antineutrino interactions on neon nuclei has been measured in BEBC to be (175±25) 10?40 cm2/neon nucleus, averaged over the energy spectrum of the antineutrino wide band beam at the CERN SPS; this corresponds to (0.9±0.1) % of the total charged current \(\bar v_\mu \) cross section. The distributions of kinematical variables are in agreement with theoretical predictions based on the PCAC hypothesis and the meson dominance model; in particular, theQ 2 dependence is well described by a propagator containing a massm=(1.35±0.18) GeV. The absolute value of the cross section is also in agreement with the model. This analysis thus provides a test of the PCAC hypothesis in the antineutrino energy range 5–150 GeV. 相似文献
73.
Pradier CM Rubio C Poleunis C Bertrand P Marcus P Compère C 《The journal of physical chemistry. B》2005,109(19):9540-9549
Adhesion of bacterial strains on solid substrates is likely related to the properties of the outer shell of the micro-organisms. Aiming at a better understanding and control of the biofilm formation in seawater, the surface chemical composition of three marine bacterial strains was investigated by combining Fourier transform IR spectroscopy, X-ray photoelectron spectroscopy (XPS), and time-of-flight secondary-ion mass spectrometry (ToF-SIMS). The D41 strain surface showed evidence of proteins, as deduced from the NH2 and NCO XPS and ToF-SIMS fingerprints; this strain was found to adhere to stainless steel, glass, or Teflon surfaces in a much higher quantity (2 orders of magnitude) than the two other ones, DA and D01. The latter are either enriched in COOH or sulfates, and this makes them more hydrophilic and less adherent to all substrates. Correlations with physicochemical properties and adhesion seem to demonstrate the role of the external layer composition, in particular the role of proteins more than that of hydrophobicity, on their adhesion abilities. 相似文献
74.
Christian Bellec Marie-Claude Bellassoued-Fargeau Bernadette Graffe Marie-Claude Sacquet Pierre Maitte 《Journal of heterocyclic chemistry》1990,27(3):551-555
The chemical reduction of 5H-[1]benzopyranno[4,3-d]pyrimidines with lithium aluminum hydrrde leads to 3,4-dihydro derivations. The electro-chemical reducation in acidic medium shows two monoelectronic cathodic waves. In netural or basic medium, substituted compounds in 2 position show a single bielectronic wave while two bielectronic waves are observed for unsubstituted compounds In all cases, preparative electrolysis lead to a hydrodimer in the 4,4′-positiom. 相似文献
75.
Groothaert MH Smeets PJ Sels BF Jacobs PA Schoonheydt RA 《Journal of the American Chemical Society》2005,127(5):1394-1395
This work reports on the capability of the O2-activated Cu-ZSM-5 and Cu-MOR zeolites to selectively convert methane into methanol at a temperature of 398 K. A strong correlation between (i) the activity and (ii) the intensity of the 22 700 cm-1 UV-vis band, assigned to the bis(mu-oxo)dicopper core, is found (i) as a function of the reaction temperature, (ii) as a function of the Cu loading of the zeolite, and (iii) in comparison to other Cu materials. These three lines of evidence firmly support the key role of the bis(mu-oxo)dicopper core in this selective, low-temperature hydroxylation of methane. 相似文献
76.
Hydroboration of the syn, anti-[Fe(CO)3]2 double complex 24 of the readily available 5,6,7,8-tetramethylidene-2-bicyclo[2.2.2]octene ( 22 ) gave the corresponding doubly complexed 2-bicyclo[2.2.2]octanol 25. CrO3-oxidation furnished ketone 27 . The syn-Fe(CO)3-groups in 25 and 27 were oxidized selectively with trimethyl-amine oxide and yielded the corresponding anti-Fe(CO3)-monocomplexed tetraenes 26 and 28. The anti-Fe(CO)3-group in 28 could be removed, and 5,6,7,8-tetramethylidene-2-bicyclo[2.2.2]octanone ( 11 ) was obtained. NaBH4-reduction of 11 afforded tetraenol 10. TCE-cycloadditions to 10 and 11 (k1) were at least 10 times as fast as those (k2) to the corresponding monoadducts 35/36 and 34 , respectively. This Diels-Alder reactivity difference vanishes (k1 ≈ k2) with methyl propynoate. The latter dienophile added to the anti-Fe(CO)3-monocomplexed tetraenone 28 with ‘para’-regioselectivity. 相似文献
77.
The reaction of a stable aminoarylcarbene with 2-chloroacrylonitrile is reported. The resulting 1/1 adduct has been spectroscopically and structurally characterized. The initial Michael addition is not followed by cyclopropane formation but by a dearomatizing cyclization affording an original bicyclic structure. 相似文献
78.
Simultaneous separation of flavanone glycosides and polymethoxylated flavones in citrus juices using liquid chromatography 总被引:5,自引:0,他引:5
We present a simultaneous liquid chromatographic method for the separation of two flavonoid compound families, flavanone glycosides (FGs) and polymethoxylated flavones (PMFs), which are usually found in citrus fruit species and varieties. This technique permits the quantitation of six FGs (narirutin, naringin, hesperidin, neohesperidin, didymin, poncirin) and six PMFs (sinensetin, hexamethoxyflavone, nobiletin, scutellarein, heptamethoxyflavone and tangeretin). This technique, to be used to characterize a citrus juice by its polyphenolic profile, has been applied to the determination of flavonoid compounds in grapefruit- and orange juice. Differentiation of orange juice varieties and mixtures containing tangor juice using polyphenolic profiles and flavonoid content has been achieved. 相似文献
79.
A straightforward preparation of various sulfoforms of the trisaccharide 4-methoxyphenyl O-(sodium beta-d-glucopyranosyluronate)-(1-->3)-( beta-d-galactopyranosyl)-(1-->3)-beta-d-galactopyranoside (1), namely its 6a- and 4a-monosulfate, 6b- and 4b-monosulfate and 6a,6b-disulfate derivatives, is reported for the first time. These compounds, which are partial structures of the linkage region of proteoglycans, will serve as probes for the study of the biosynthesis and sorting of these macromolecules. A key trisaccharide derivative, in which the two similar d-Gal units were differentiated at C-4,6 with 4,6-benzylidene and 4,6-di-tert-butylsilylene acetals, respectively, was used as a common intermediate. Both acetal groups showed excellent orthogonality, and allowed the preparation of all target compounds in high yield. Noteworthy is the possibility to prepare the 6a- and 6b-monosulfated and the 6a,6b-disulfated species through a one-pot regioselective procedure starting from a tetrol precursor. 相似文献
80.
Sofiane Ben Hamouda Quang Trong Nguyen Pierre Schaetzel 《European Polymer Journal》2006,42(11):2994-3005
Ethylene/ethane sorption characteristics were determined for dry Pebax™ (poly(amide 12-block-tetramethylenoxide) copolymer)/AgBF4 membranes by using an electronic microbalance. The membranes containing 0.7 and 22 wt.% AgBF4 showed a dual-mode sorption isotherm. The ethane isotherms for all the membranes were of the Henry-type, which is the normal sorption for gases in rubbery polymers. The abnormal presence of Langmuir sorption sites only for ethylene in the rubbery copolymer, never reported sofar, is attributed to the silver-based specific complexation sites. The silver salt which dissolved in limited amounts in the rubbery copolymer had a much smaller Langmuir sorption capacity than the salt that crystallized in the copolymer. The sorption kinetics indicate that the crystallized salt did adsorb slowly ethylene according to a zeroth-order kinetics, but not ethane. The gas uptake kinetics resulting from a step of the pressure surrounding the copolymer exhibited one stage for ethane but two stages for ethylene. For the latter, there was first a fast Fickian sorption stage, then a drift of the zeroth-order sorption of ethylene on salt crystals, which contributes for a large part to the total uptake. The zeroth-order sorption suggests that the sorbed ethylene amount in the second-stage is independent of the crystal-surface coverage. The value of the Fickian diffusion coefficient calculated by fitting the kinetics with a solution of the second Fick’s law was 5 × 10−12 m2/s for both ethylene (the first stage) and ethane, and is typical for small organic compounds in a rubbery material. 相似文献