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81.
82.
María Álvarez de Morales Lidia Fernández Teresa E. Pérez Miguel A. Piñar 《Numerical Algorithms》2007,45(1-4):153-166
In this paper, we consider bivariate orthogonal polynomials associated with a quasi-definite moment functional which satisfies
a Pearson-type partial differential equation. For these polynomials differential properties are obtained. In particular, we
deduce some structure and orthogonality relations for the successive partial derivatives of the polynomials.
相似文献
83.
采用免疫化学方法,以胸苷激酶(TK)抗体检测了5种培养的细胞(4种癌细胞和1种正常细胞)及12种人类癌组织切片.结果表明,正常细胞呈阴性结果,4种癌细胞及12种癌组织均呈阳性结果.提示此种方法在癌症的临床诊断方面可能有意义. 相似文献
84.
T.-W. Pi L.-C. TienJ.-F. Wen C.-P. OuyangC.-P. Cheng J. Hwang 《Solid State Communications》2003,125(9):459-462
We have employed synchrotron radiation photoemission to investigate calcium fluoride deposited on Si(001)-2×1 annealed at 700 °C. The valence band spectra reveal that the initial molecules are dissociated to single Ca atoms resting on the surface. Si 2p core-level spectra manifest a negatively shifted Ca-induced line at 0.35 eV. The dissociated Ca atoms occupy only half of the surface, on top of which the CaF2 molecules commence growth. This is in contrast to the Si(111)-7×7 counterpart, which exhibits a CaF layer in the interface. Strong elastic scattering due to the absorbed Ca atoms is evident in the photoemission spectra, thus averaging out the angle-dependent features. 相似文献
85.
Calcium tin silicate, CaSnSiO5, called Malayaite is synthesized with equimolecular quantities of calcium oxide, silica and stannic oxide followed by a thermic
process. In this work, the synthesis of Malayaite and the structure of a Malayaite-based pigment, Sn/Co pink, is investigated
by X-ray diffraction and Mossbauer spectroscopy. The results indicate Malayaite and Cassiterite formation, but the ion cobalt
incorporated in the Malayaite structure, diminishes the Cassiterite proportion and causes larger asymmetry in the environment
of the tin atom. 相似文献
86.
NONLINEAROSCILIATIONANALYSISBYANORTHOGONALFUNCTIONMETHODSunPi,hong(孙丕忠)TangPiangang(唐乾刚)SunShixian(孙世贤)(NationUniversityofDef... 相似文献
87.
Rhodium(III)‐Catalyzed [3+2]/[5+2] Annulation of 4‐Aryl 1,2,3‐Triazoles with Internal Alkynes through Dual C(sp2)H Functionalization
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Yuan Yang Ming‐Bo Zhou Xuan‐Hui Ouyang Rui Pi Dr. Ren‐Jie Song Prof. Dr. Jin‐Heng Li 《Angewandte Chemie (International ed. in English)》2015,54(22):6595-6599
A rhodium(III)‐catalyzed [3+2]/[5+2] annulation of 4‐aryl 1‐tosyl‐1,2,3‐triazoles with internal alkynes is presented. This transformation provides straightforward access to indeno[1,7‐cd]azepine architectures through a sequence involving the formation of a rhodium(III) azavinyl carbene, dual C(sp2)? H functionalization, and [3+2]/[5+2] annulation. 相似文献
88.
Dale McMorrow Michon Irons Wyche Pi Tai Chou Michael Kasha 《Photochemistry and photobiology》2015,91(3):576-585
Trace quantities of hydrogen‐bonding impurities in otherwise highly purified and dried glassy hydrocarbon matrices at 77 K can modify the relative triplet state energy levels, and hence the photophysical properties of two aromatic ketones, xanthone and chromone, to the extent that the intrinsic spectroscopic properties are obscured. The intrinsic spectroscopic properties of each are revealed in multicrystalline n‐alkane Shpol'skii matrices, and also can be observed in rigorously purified and dried hydrocarbon glasses at 77 K. The extreme sensitivity to stoichiometric, and even substoichiometric quantities of hydrogen‐bonding impurities arises from the near‐degeneracy of the two lowest‐lying triplet states, and the sensitive nature of the n→π* blueshift phenomena to specific hydrogen‐bonding interactions. 相似文献
89.
Yuan Yang Ming‐Bo Zhou Xuan‐Hui Ouyang Rui Pi Ren‐Jie Song Jin‐Heng Li 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2015,127(22):6695-6699
A rhodium(III)‐catalyzed [3+2]/[5+2] annulation of 4‐aryl 1‐tosyl‐1,2,3‐triazoles with internal alkynes is presented. This transformation provides straightforward access to indeno[1,7‐cd]azepine architectures through a sequence involving the formation of a rhodium(III) azavinyl carbene, dual C(sp2) H functionalization, and [3+2]/[5+2] annulation. 相似文献
90.
Erenas MM Piñeiro O Pegalajar MC Cuellar MP de Orbe-Payá I Capitán-Vallvey LF 《Analytica chimica acta》2011,694(1-2):128-135
A disposable optical tongue for the alkaline ions Na(I) and K(I) is described. The two-sensor layout prepared on a transparent support consists of non-specific polymeric membranes working by ionophore-chromoionophore chemistry. The non-specific behavior of the membranes was controlled by means of the crown ether-type ionophore present. The imaging of the tongue, after reaction for 3 min with the unknown solution, by means of a conventional flatbed scanner working by transmission mode, makes it possible to calculate the H (hue) value of the hue, saturation, value (HSV) color space used as a robust and precise analytical parameter. The modelling of the response of the two-sensor tongue as a sigmoidal surface is used to characterize the behavior of the tongue and as a basis to infer the concentration values. To compute the concentration of two analytes from the two hue values obtained using the optical tongue, a surface fit approach was used. The tongue works over a wide dynamic range (1.0×10(-4)-0.1 M both in Na(I) and K(I)). The sensing membranes show good intramembrane (1.4% RSD) and intermembrane precision (0.71% RSD) and lifetime (around 45 days in darkness). The procedure was used to analyze Na(I) and K(I) in different types of natural waters (tap and mineral), validating the results against a reference procedure. 相似文献