Luminescence properties of Ba2NaNb5O15 crystals activated with Sm, Eu, Tb or Dy ions

Single crystals of Ba₂NaNb₅O₁₅ (BNN) singly doped with Sm³⁺, Eu³⁺, Tb³⁺ or Dy³⁺ have been grown by means of the flux growth method. Their visible emission and excitation spectra and the decay profiles of the luminescence have been measured at room temperature. All spectral features are significantly inhomogeneously broadened in consequence of the structural disorder of the host and of the doping mechanisms. The analysis of the observed spectra allows formulating an hypothesis about the site occupancy of the active ions in the BNN lattice.     

Blood flow evaluation in high-frequency, 40 MHz imaging: A comparative study of four vector velocity estimation methods

Ultrasonic imaging is often used to estimate blood flow velocity. Currently, estimates are carried out using Doppler-based techniques. However, there are a number of shortcomings such as the limited spatial resolution and the inability to estimate longitudinal flows. Thus, alternative methods have been proposed to overcome them. Difficulties are notably encountered with high-frequency imaging systems that use swept-scan techniques. In this article, we propose to compare four vector velocity estimation methods that are complementary to Doppler, focusing on 40 MHz, high-frequency imaging. The goal of this study is to evaluate which method could circumvent the limitations of Doppler methods for evaluation of microcirculation, in the vessels having diameter on the order of 1 mm. We used two region-based approaches, one decorrelation-based approach and one spatiotemporal approach. Each method has been applied to seven flow sequences with various orientations and mean velocities. Four sequences were simulated with a system approach based on a 3D set of moving scatterers. Three experimental sequences were carried out by injecting blood-mimicking fluid within a gelatin phantom and then acquiring images with Visualsonics, Vevo 660 system. From velocity estimates, several performance criteria such as the normalized mean error or the normalized mean standard deviation were defined to compare the performance of the four estimators. The results show that region-based methods are the most accurate exhibiting mean errors less than 10% and mean standard deviation less than 13%. However, region-based approaches are those that require the highest calculative cost compared to the decorrelation-based method, which is the fastest. Finally, the spatiotemporal approach appeared to be a trade-off in terms of computational complexity and accuracy of estimates. It provides estimates with errors less than 10% for mean velocity and the CPU time is approximately 17 s for a ROI of size 40 * 80 pixels.     

Uniqueness of Mass-Conserving Self-similar Solutions to Smoluchowski’s Coagulation Equation with Inverse Power Law Kernels

Uniqueness of mass-conserving self-similar solutions to Smoluchowski’s coagulation equation is shown when the coagulation kernel K is given by \(K(x,x_*)=2(x x_*)^{-\alpha }\), \((x,x_*)\in (0,\infty )^2\), for some \(\alpha >0\).     

Measuring fluorescence to track a quantum emitter's state: a theory review

We review the continuous monitoring of a qubit through its spontaneous emission, at an introductory level. Contemporary experiments have been able to collect the fluorescence of an artificial atom in a cavity and transmission line, and then make measurements of that emission to obtain diffusive quantum trajectories in the qubit's state. We give a straightforward theoretical overview of such scenarios, using a framework based on Kraus operators derived from a Bayesian update concept; we apply this flexible framework across common types of measurements including photodetection, homodyne, and heterodyne monitoring and illustrate its equivalence to the stochastic master equation formalism throughout. Special emphasis is given to homodyne (phase-sensitive) monitoring of fluorescence. The examples we develop are used to illustrate basic methods in quantum trajectories, but also to introduce some more advanced topics of contemporary interest, including the arrow of time in quantum measurement, and trajectories following optimal measurement records derived from a variational principle. The derivations we perform lead directly from the development of a simple model to an understanding of recent experimental results.     

Temperature Dependence of 1H Paramagnetic Chemical Shifts in Actinide Complexes,Beyond Bleaney's Theory: The AnVIO22+–Dipicolinic Acid Complexes (An=Np,Pu) as an Example

Actinide +VI complexes ( = , and ) with dipicolinic acid derivatives were synthesized and characterized by powder XRD, SQUID magnetometry and NMR spectroscopy. In addition, and complexes were described by first principles CAS based and two-component spin-restricted DFT methods. The analysis of the ¹H paramagnetic NMR chemical shifts for all protons of the ligands according to the X-rays structures shows that the Fermi contact contribution is negligible in agreement with spin density determined by unrestricted DFT. The magnetic susceptibility tensor is determined by combining SQUID, pNMR shifts and Evans’ method. The SO-RASPT2 results fit well the experimental magnetic susceptibility and pNMR chemical shifts. The role of the counterions in the solid phase is pointed out; their presence impacts the magnetic properties of the complex. The temperature dependence of the pNMR chemical shifts has a strong contribution, contrarily to Bleaney's theory for lanthanide complexes. The fitting of the temperature dependence of the pNMR chemical shifts and SQUID magnetic susceptibility by a two-Kramers-doublet model for the complex and a non-Kramers-doublet model for the complex allows for the experimental evaluation of energy gaps and magnetic moments of the paramagnetic center.     

Hippocampal metabolomics using ultrahigh-resolution mass spectrometry reveals neuroinflammation from Alzheimer’s disease in CRND8 mice

In the wake of genomics, metabolomics characterizes the small molecular metabolites revealing the phenotypes induced by gene mutants. To address the metabolic signatures in the hippocampus of the amyloid-beta (Aβ) peptides produced in transgenic (Tg) CRND8 mice, high-field ion cyclotron resonance–Fourier transform mass spectrometry supported by LC-LTQ-Orbitrap was introduced to profile the extracted metabolites. More than 10,000 ions were detected in the mass profile for each sample. Subsequently, peak alignment and the 80 % rule followed by feature selection based on T score computation were performed. The putative identification was also conducted using the highly accurate masses with isotopic distribution by interfacing the MassTRIX database as well as MS/MS fragmentation generated in the LTQ-Orbitrap after chromatographic separation. Consequently, 58 differentiating masses were tentatively identified while up to 44 differentiating elemental compositions could not be biologically annotated in the databases. Nonetheless, of the putatively annotated masses, eicosanoids in arachidonic acid metabolism, fatty acid beta-oxidation disorders as well as disturbed glucose metabolism were highlighted as metabolic traits of Aβ toxicity in Tg CRND8 mice. Furthermore, a web-based bioinformatic tool was used for simulation of the metabolic pathways. As a result of the obtained metabolic signatures, the arachidonic acid metabolism dominates the metabolic perturbation in hippocampal tissues of Tg CRND8 mice compared to non-Tg littermates, indicating that Aβ toxicity functions neuroinflammation in hippocampal tissue and new theranostic opportunities might be offered by characterization of altered arachidonic acid metabolism for Alzheimer’s disease.      

Laterally dibenzyloxy-branched nematogens with large nematic range and rich solid polymorphism

Mesogenic compounds containing four rings in the core usually have very high melting points. However, when two identical lateral benzyloxy groups are introduced on the same side of one of the central rings, the melting point is lowered dramatically and a large nematic range is retained. This range is affected by the bulkiness of the para-substituents in the lateral rings. Methyl groups can be introduced in the ortho- or meta-positions with a consequent decrease in the melting temperature without much affecting the nematic range. These compounds exhibit a rich solid polymorphism which is certainly related to the effect of the conformations of the lateral substituent on the molecular arrangment in the solid phase. Some preliminary NMR experiments on the nematic phase indicate that the molecular long axis coincides with the core axis, whereas the para-axis of the lateral fragment makes an angle close to the magic angle with respect to the molecular long axis.     

Principal hierarchies of infinite-dimensional Frobenius manifolds: The extended 2D Toda lattice

We define a dispersionless tau-symmetric bihamiltonian integrable hierarchy on the space of pairs of functions analytic inside/outside the unit circle with simple poles at 0/∞$0/\infty$ respectively, which extends the dispersionless 2D Toda hierarchy of Takasaki and Takebe. Then we construct the deformed flat connection of the infinite-dimensional Frobenius manifold _M0$M_0$ introduced by Carlet, Dubrovin and Mertens (2011) [3] and, by explicitly solving the deformed flatness equations, we prove that the extended 2D Toda hierarchy coincides with principal hierarchy of _M0$M_0$.