Ethanol/water solutions as certified reference materials for breath alcohol analyzer calibration

The Federal Institute for Materials Research and Testing (BAM), Germany, has issued a series of large volume ethanol in water certified reference materials (CRMs), primarily developed for the calibration of evidential breath alcohol analyzers in Germany. The certified parameter is the ethanol mass concentration at 20 °C. When used in a wet bath simulator, the solutions deliver gas samples that meet the requirements set by the Organization of Legal Metrology for calibration of breathalyzers. The materials were prepared gravimetrically by spiking of ethanol into water in single 5 L units. A complete uncertainty budget for the preparation process has been established. The purity of the commercial ethanol stock solution was identified to be the main source of uncertainty. For stability and homogeneity measurements and for the verification of the gravimetric mass concentration of the CRMs, a robust high-precision gas chromatography, with flame-ionization detection method for ethanol determination in aqueous samples was developed and validated. The good performance of this method has been demonstrated in several international comparisons organized by the Consultative Committee for Amount of Substance—Metrology in Chemistry at the International Bureau of Weights and Measures.     

Determination of phase transition points of ionic liquids by combination of thermal analysis and conductivity measurements at very low heating and cooling rates

The determination of phase transition points of nine different ionic liquids (ILs) was performed by thermal analysis with simultaneous recording of conductivity. Conductivity of electrolyte solutions and ILs drastically changes during phase transitions and thus is an additional and very sensitive indicator for measuring phase transition points. Evaluation of temperature–time functions and conductivity–time functions with our computer-coupled automated equipment enabled the determination of melting temperatures with high accuracy and reliability. This claim is based on large samples, low temperature change rates and by regularly repeated measurements, i.e. at least seven measurements per IL. The melting temperatures of 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate, 1-butyl-1-methylpyrrolidinium tris(penta-fluoroethyl)trifluorophosphate, and 1-methyl-3-propylimidazolium iodide were, to our knowledge, determined for the first time. The melting temperatures of the other 1-butyl-1-methylpyrrolidinium-, 1-ethyl-3-methylimidazolium-, 1-hexyl-3-methylimidazolium-, and trimethylsulfonium-based ILs showed either a very good accordance with values published in literature or were distinctly higher.     

Charmonium spectra at finite temperature from QCD sum rules with the maximum entropy method

Charmonia spectral functions at finite temperature are studied using QCD sum rules in combination with the maximum entropy method. This approach enables us to directly obtain the spectral function from the sum rules, without having to introduce any specific assumption about its functional form. As a result, it is found that while J/ψ and η(c) manifest themselves as significant peaks in the spectral function below the deconfinement temperature T(c), they quickly dissolve into the continuum and almost completely disappear at temperatures between 1.0T(c) and 1.1T(c).     

Low-energy termination of graphene edges via the formation of narrow nanotubes

We demonstrate that free graphene sheet edges can curl back on themselves, reconstructing as nanotubes. This results in lower formation energies than any other nonfunctionalized edge structure reported to date in the literature. We determine the critical tube size and formation barrier and compare with density functional simulations of other edge terminations including a new reconstructed Klein edge. Simulated high resolution electron microscopy images show why such rolled edges may be difficult to detect. Rolled zigzag edges serve as metallic conduction channels, separated from the neighboring bulk graphene by a chain of insulating sp(3)-carbon atoms, and introduce van Hove singularities into the graphene density of states.     

Spin squeezing inequalities for arbitrary spin

We determine the complete set of generalized spin squeezing inequalities, given in terms of the collective angular momentum components, for particles with an arbitrary spin. They can be used for the experimental detection of entanglement in an ensemble in which the particles cannot be individually addressed. We also present a large set of criteria involving collective observables different from the angular momentum coordinates. We show that some of the inequalities can be used to detect k-particle entanglement and bound entanglement.     

Fermi gamma-ray "bubbles" from stochastic acceleration of electrons

Gamma-ray data from Fermi Large Area Telescope reveal a bilobular structure extending up to ～50° above and below the Galactic Center. It has been argued that the gamma rays arise from hadronic interactions of high-energy cosmic rays which are advected out by a strong wind, or from inverse-Compton scattering of relativistic electrons accelerated at plasma shocks present in the bubbles. We explore the alternative possibility that the relativistic electrons are undergoing stochastic 2nd-order Fermi acceleration by plasma wave turbulence through the entire volume of the bubbles. The observed gamma-ray spectral shape is then explained naturally by the resulting hard electron spectrum modulated by inverse-Compton energy losses. Rather than a constant volume emissivity as in other models, we predict a nearly constant surface brightness, and reproduce the observed sharp edges of the bubbles.     

Neutron depolarisation imaging: Stress measurements by magnetostriction effects in Ni foils

In this article we present first proof-of-principle neutron depolarization imaging measurements on Ni foils under mechanical stress. The magnetostrictive effect in Ni leads to a reorientation of the magnetic domains in the material depending on the applied force. This in turn leads to a change of the depolarization a neutron beam suffers from transmission of the sample. We propose to use this method as a new technique for the spatially resolved measurement of mechanical stress.     

Influence of processing time on nanoparticle generation during picosecond-pulsed fundamental and second harmonic laser ablation of metals in tetrahydrofuran

The influence of fundamental and second harmonic wavelength on ablation efficiency and nanoparticle properties is studied during picosecond laser ablation of silver, zinc, and magnesium in polymer-doped tetrahydrofuran. Laser ablation in stationary liquid involves simultaneously the fabrication of nanoparticles by ablation of the target material and fragmentation of dispersed nanoparticles by post irradiation. The ratio in which the laser pulse energy contributes to these processes depends on laser wavelength and colloidal properties. For plasmon absorbers (silver), using the second harmonic wavelength leads to a decrease of the nanoparticle productivity over process time along with exponential decrease in particle diameter, while using the fundamental wavelength results in a constant ablation rate and linear decrease in particle diameter. For colloids made of materials without plasmon absorption (zinc, magnesium), laser scattering is the colloidal property that limits nanoparticle productivity by Mie-scattering of dispersed nanoparticle clusters.     

Optimal cost sharing for capacitated facility location games

We consider cost sharing for a class of facility location games, where the strategy space of each player consists of the bases of a player-specific matroid defined on the set of resources. We assume that resources have nondecreasing load-dependent costs and player-specific delays. Our model includes the important special case of capacitated facility location problems, where players have to jointly pay for opened facilities. The goal is to design cost sharing protocols so as to minimize the resulting price of anarchy and price of stability. We investigate two classes of protocols: basic protocols guarantee the existence of at least one pure Nash equilibrium and separable protocols additionally require that the resulting cost shares only depend on the set of players on a resource. We find optimal basic and separable protocols that guarantee the price of stability/price of anarchy to grow logarithmically/linearly in the number of players. These results extend our previous results (cf. von Falkenhausen & Harks, 2013), where optimal basic and separable protocols were given for the case of symmetric matroid games without delays.