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31.
A reaction presented as a photosensitized reduction of carbon dioxide is in fact a photooxidation of the aromatic sensitizers. 相似文献
32.
Note on some complexes between nikethamide and/or pemoline with various salts, especially calcium aminoalkylphosphates A number of binary and ternary complexes of nikethamide and/or pemoline with various calcium salts, particularly calcium aminoalkylphosphates, have been prepared in order to assess their pharmacological properties. The formation of such complexes has been established by IR. spectroscopy. 相似文献
33.
Summary The coupling of carbon dioxide supercritical fluid chromatography with Fourier transform infrared spectrometry (SFC-FTIR)
is a powerful tool for the separation and on-line identification of non-volatile compounds. The IR transparency of carbon
dioxide in the Fermi resonance bands region versus its density has been studied. Functional groups with stretching vibrations
outside the transparent window of carbon dioxide are examined. SFC-FTIR separations allow Gram-Schmidt reconstruction chromatograms
or IR window chemigrams with high quality spectra to be obtained. This SFC-FTIR lightpipe (flow cell, beam condensing optics,
narrow band detector) has allowed detection limits of 250ng for benzonitrile and 70ng for methyl benzoate to be reached. The
feasibility of very rapid SFC-FTIR separations is shown along with the subsequent peak spectra. 相似文献
34.
H. Weisen F. Hofmann M. J. Dutch J. -M. Moret J. B. Lister A. Pochelon R. A. Pitts M. Anton R. Behn S. Bernel F. Bühlmann R. Chavan B. P. Duval D. Fasel A. Favre S. Franke A. Heym Ch. Hollenstein P. Isoz B. Joye X. Llobet B. Marletaz Ph. Marmillod Y. Martin Ch. Nieswand P. J. Paris A. Perez Z. A. Pietrzyk O. Sauter W. Van Toledo G. Tonetti M. Q. Tran F. Troyon D. J. Ward 《Czechoslovak Journal of Physics》1995,45(12):1095-1110
During the first two years of operation, the TCV tokamak has produced a large variety of plasma shapes and magnetic configurations, with 1.0B
tor1.46T,I
p800kA,k2.05, –0.71. A new shape control algorithm, based on a finite element reconstruction of the plasma current in real time, has been implemented. Vertical growth rates up to 1000s–1 have been stabilized using the external coil system. Ohmic H-modes with Troyon factors (
tor
aB/I
p) up to two and densities up to 2.25×1020m–3, corresponding to the Greenwald limit, have been obtained in diverted discharges. Limiter H-modes with line averaged electron densities up to 1.7×1020m–3 have been obtained in elongated D-shaped plasmas with 360 kAI
P600 kA.Presented at 17th Symposium Plasma Physics and Technology, Prague, June 13–16, 1995.This work was partly supported by the Fonds National Suisse de la Recherche Scientifique. 相似文献
35.
S. Czajkowski M. Bernas P. Armbruster H. Geissel C. Kozhuharov G. Münzenberg D. Vieira Ph. Dessagne Ch. Miehe E. Hanelt G. Audi J. K. P. Lee 《Zeitschrift für Physik A Hadrons and Nuclei》1994,348(4):267-272
Neutron-rich Co and Fe isotopes produced by86Kr projectile fragmentation at 500 MeV/u were separated and identified using the fragment separator (FrS) in a bunched energy mode.66Co and65Fe ions were selectively implanted in a double PIN-diode array where the-decay signals were measured. The half-lives were deduced from time correlations between implantation and-decay signals. The remeasurement of the66Co half-life confirms the isotope identification. The value of the65Fe half-life was found to be 0.45±0.15 s. 相似文献
36.
B. Vezin Ph. Dugourd D. Rayane P. Labastie J. Chevaleyre M. Broyer 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1993,26(Z1):128-130
Ionization Potentials of LinHm clusters have been measured by photoionization. As in Lin, odd-even alternations and shell closing effects are observed. In a first approximation, we find that LinH clusters behave like Lin–1 and LinH2 like Lin–2. The results may be interpreted by assuming that the bonding of one hydrogen localizes one electron and that the other electrons remain delocalized. 相似文献
37.
We present a cellular automata model as a new approach to Bernoulli site percolation on the square lattice. A new macroscopic quantity is defined and numerically computed at each level step of the automata dynamics. Its limit manifests a critical behavior at a value of the site occupancy probability quite close to those obtained for site percolation on 2 with the best-known numerical methods. 相似文献
38.
Cataldi TR Bianco G Frommberger M Schmitt-Kopplin P 《Rapid communications in mass spectrometry : RCM》2004,18(12):1341-1344
A rapid, simple and selective method involving direct separation by gas chromatography (GC) with electron ionization mass spectrometry (EI-MS) was employed to determine some N-acylhomoserine lactones (AHLs). Using GC/EI-MS, simultaneous separation and characterization of AHLs were possible without prior derivatization. Informative fragmentation patterns were obtained to identify the structures of N-acyl chains of AHLs. Electron ionization resulted in a common fragmentation pattern with the most abundant ion at m/z 143 and other minor peaks at m/z 71, 57, and 43. The presence of AHLs in extracts of Burkholderia cepacia strains was achieved in selected ion monitoring mode by using the prominent fragment at m/z 143. 相似文献
39.
S. Stassen S. Archambeau Ph. Dubois R. Jerome Ph. Teyssie 《Journal of polymer science. Part A, Polymer chemistry》1994,32(13):2443-2455
Since bromides are well-known precursors of primary amines, diethylaluminum 12 bromo-1-dodecyl oxide has been prepared and used as an initiator for the ring-opening polymerization of ?-caprolactone and L-lactide. Uner strictly controlled conditions, the end-functionalization of the polyesters in quantitative and the bromo end-group is easily converted into an azide group whatever the polymeric backbone. The subsequent reduction of the azide into the expected primary amine has been investigated by catalytic transfer hydrogenation (CTH) in DMF and by hydrolysis in the presence of triphenylphosphine in THF, respectively.The hydrolysis reaction (PΦ3/H2O) is perturbed by a coupling reaction, which involves a protonate secondary amine and leads to a twofold increase in the polyester molecular weight. The CTH method gives rise to the expected ω-NH2 poly (?-caprolactone), in contrast to polylactide which seems to be unstable toward the nascent amine end group. Whatever the polarity of the medium (DMF or THF), aminolysis of polylactides is observed to occur and leads to the formation of an internal amide. © 1994 John Wiley & Sons, Inc. 相似文献
40.
Summary
We say that a curve C in
P
3
has maximal rank if for every integer k the restriction map rc(k):H
0(P
3, OP3(k)) H0 (C, OC(k))has maximal rank. Here we prove the following results. Theorem 1Fix integers g, d with 0g3,dg+3.Fix a curve X of genus g and L Picd (X).If g=3and X is hyperelliptic, assume d8. Let L(X)be the image of X by the complete linear system H
0(X, L). Then a general projection of L(X)into
P
3
has maximal rank. Theorem 2For every integer g0,there exists an integer d(g, 3)such that for every dd(g, 3),for every smooth curve X of genus g and every LPicd (X) the general projection of L(X)into
P
3
has maximal rank. 相似文献