1,3-bis(2,4,6-trinitrophenylaminooxy)propane and its 4-cyano-2,6-dinitrophenyl congener: Synthesis and properties

Starting from N-hydroxyphthalimide (5) and 1,3-dibromopropane (6) we obtained 1,3-bis(phthalimidooxy)propane (7) which led to 1,3-bis(aminooxy)propane dihydrochloride (8). From its reaction with picryl chloride or 4-cyano-2,6-dinitrochlorobenzene, the two title compounds (4b, 4a) were obtained. ¹H-NMR and ¹³C-NMR spectra are presented. For comparison with the analogous N-methoxy-2,6-dinitro-4-R-anilines 1a, 1b (R=CN or R=NO₂), wer report the hydrophobic characteristics (by RPTLC), electronic spectra for the neutral compounds and their anions, pK _a values, and the behavior towards oxidizers (DPPH, PbO₂, Pb(CH₃COO)₄, KMnO₄ and Ag₂O); DPPH converts compounds 1a, 1b and 4a, 4b into betainic structures 2a, 2b respectively.     

Synthesis and Characterization of Alumina R Chemically Modified with n-Octyl for Use as a Stationary Phase in TLC

JPC – Journal of Planar Chromatography – Modern TLC - A stationary phase for thin-layer chromatography has been prepared by attaching 1-octene to alumina R. This stationary phase has...     

Global existence of solutions for perturbed differential equations

In this paper we consider sufficient conditions for the continuability of solutions for perturbed differential equations. We obtain also some results for the global existence of solutions for differential inclusions and for stochastic differential equations of McShane and Ito type. We give an application to the global inversion of local diffeomorphisms.     

SU(2) andSU(1,1) algebra eigenstates: A unified analytic approach to coherent and intelligent states

We introduce the concept of algebra eigenstates which are defined for an arbitrary Lie group as eigenstates of elements of the corresponding complex Lie algebra. We show that this concept unifies different definitions of coherent states associated with a dynamical symmetry group. On the one hand, algebra eigenstates include different sets of Perelomov's generalized coherent states. On the other hand, intelligent states (which are squeezed states for a system of general symmetry) also form a subset of algebra eigenstates. We develop the general formalism and apply it to theSU(2) andSU(1,1) simple Lie groups. Complete solutions to the general eigenvalue problem are found in both cases by a method that employs analytic representations of the algebra eigenstates. This analytic method also enables us to obtain exact closed expressions for quantum statistical properties of an arbitrary algebra eigenstate. Important special cases such as standard coherent states and intelligent states are examined and relations between them are studied by using their analytic representations.     

The major conjugates of ecdysteroids in young eggs and in embryos of locusta migratoria

Newly-laid eggs of migratory locust contain as the major ecdysteroid conjugate donated by the female to its offspring the 22-adenosinemonophosphoric ester of 2-deoxyecdysone; in 8 days old embryos, the major ecdysteroid is the 3-phosphate of 3-epi 2-deoxyecdysone.     

Spectres de masse de phospholipides et polypeptides non proteges. Une technique simple d'obtention du spectre complet.

Direct introduction of diacyl-lecithins in the ionization chamber on a gold support gives the molecular ion and structurally significant fragments; the same is true with unprotected small polypeptides.     

Thermal behavior of some polyurethanes reticulated by aminated maltose

Polymeric materials by polyaddition reaction between aminated maltose and methylene diisocyanate, in different molar ratio, were synthesized. Aminated maltose was obtained by functionalization at the reductive end with methylene dianiline, under soft reductive conditions. The addition reaction was certified by comparative FTIR and Raman spectra of reactants and obtained materials. The thermooxidative stability of these materials was established under non-isothermal conditions. The thermal stability decreases by increasing the isocyanate/aminated maltose molar ratio.