Fast choice of separation conditions for analyses by capillary zone electrophoresis using an information system Xemic

An information system Xemic applicable in analytical chemistry is described and its use in capillary electrophoresis for searching suitable separation conditions is demonstrated. This system is capable to provide suitable separation conditions even for analytes for which no electrophoretic experiments have been published so far. The system works with a database of components of anionic character the analyses of which have been performed, published in reviewed scientific journals, and included into a database created by an expert. Moreover, the system learned to search also in abstracts or complete scientific articles to find articles dealing with the determination of a substance in a given sample matrix. When no experiments have been published so far for a defined substance in a specific matrix, Xemic shows the separation conditions for determination of the substance regardless of the matrix. When no response can be found for the analyte of interest at all, the system Xemic works like an expert in the field and searches chemically similar substances and offers a series of substances the physicochemical properties of which are close to the followed analyte with respect to the behavior in the electric field, and shows working conditions for their analysis. Thus, the analyst puts only the order in the form of a given analyte in a given matrix and obtains a recommendation of a separation system that should enable to perform a successful separation. The system is not rigid and enables the operator to change the importance of individual attributes used in similarity search so as to obtain a broader or narrower group of similar components. With a certain probability the analyte of interest can be successfully analyzed under separation conditions that suited for the analysis of the most similar substances in the given matrix.     

Enantiomeric partitioning using fluorous biphase methodology for lipase-mediated (trans)esterifications

Lipase-catalysed (trans)esterification reactions in homogenous perfluorocarbon-hydrocarbon solvents enabled direct enantiomeric partitioning (up to 95% ee) of the products by liquid-liquid separation.     

Analytic solution for the nondegenerate quantum control problem

We present an analytic solution for the nondegenerate quantum control problem, i.e., the transfer of a deliberate amount of population, 0%-100%, between arbitrary initial Psi(t)> and final Psi'(t)> states, which can be expanded in terms of nondegenerate energy eigenstates k>. The solution constitutes a robust two-photon multicomponent adiabatic passage, via an intermediate eigenstate 0>, which relies on three types of "null states."     

Theoretical estimates of radial electric fields and plasma rotation induced in H-1NF by RF waves

The purpose of this study is to estimate, for planned experiments at the H-1NF heliac, nonlinear variations of the stationary radial electric field, and poloidal and toroidal plasma rotation, that result from ponderomotive forces exerted by large amplitude RF waves in the H-1NF. Similarly as in the previous studies of nonlinear transport effects induced by RF waves, the nonlinear ponderomotive force effects on the radial electric field, toroidal and poloidal plasma rotation become important for dissipated powers of the order of 1 MWm^–3 for RF waves with frequency of about 10 MHz. At these high RF powers, the nonlinear ponderomotive force effects might therefore result in important changes in plasma confinement and RF wave coupling in H-1NF.This work has been partially supported by the Australian National University, by the DIST Department of the Australian Government, by the Czech Grant Agency grants No. 202/96/1355 and 1350, and by the Queen Elisabeth II grant administered by G.G. Borg. The author is grateful to G.G. Borg and R.L. Dewar for many stimulating discussions.     

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Nonlinear waves in a waveguide partially filled with a plasma

Nonlinear waves have been studied in a circular waveguide partially filled with a cold magnetized collisionless plasma. The solution obtained is periodical with the frequency increasing as a square root of the amplitude of the solution in the first approximation.The author is indebted to K.Jungwirth, R.Klíma and J.Preinhaelter for valuable discussions.