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101.
Bohuslav Rittich Alena Španová Petr Šálek Štěpánka Trachtová 《Journal of magnetism and magnetic materials》2009,321(10):1667-1670
Carboxyl group-containing magnetic nonporous poly(2-hydroxyethyl methacrylate-co-glycidyl methacrylate) (P(HEMA-co-GMA)) and magnetic glass microspheres were used for the isolation of bacterial DNA. P(HEMA-co-GMA) microspheres were prepared by the dispersion polymerization in toluene/2-methylpropan-1-ol mixture in the presence of magnetite nanoparticles obtained by coprecipitation of Fe(II) and Fe(III) salts with ammonium hydroxide. Carboxyl groups were then introduced by oxidation of the microspheres with potassium permanganate. The most extensive DNA recovery was achieved at PEG 6000 concentrations of 12% or 16% and 2 M NaCl. The method proposed was used for bacterial DNA isolation from different dairy products containing Bifidobacterium and Lactobacillus cells. The presence of target DNA and the quality of isolated DNA were checked by polymerase chain reaction (PCR) amplification with specific primers. 相似文献
102.
Petr A. Obraztsov Anatoliy. A. Sirotkin Elena D. Obraztsova Yuri P. Svirko Sergey V. Garnov 《Optical Review》2010,17(3):290-293
We demonstrate the passive mode-locking of a diode-pumped Nd+3:YAG (central wavelength: 1.32 μm; pulse duration: 50 ps; output energy: up to 70 μJ) laser using a polymer film containing
single-wall carbon nanotubes. The mode-locking regime is stable at a pump repetition rate of up to 1 kHz. We also investigate
the temporal evolution of the light-induced absorption change of the polymer film containing carbon nanotubes in the spectral
range of 1.3–1.5 μm by femtosecond time-resolved pump-probe measurements. The measurements reveal that light-induced transmission
exhibits fast and slow components that last 280 fs and more than 10 ps, respectively. The third-order susceptibility of the
polymer film containing single wall carbon nanotubes is as high as 10−11 esu. 相似文献
103.
104.
Construction X and its variants are known from the theory of classical error control codes. We present instances of these constructions that produce binary stabilizer quantum error control codes from arbitrary quaternary linear codes. Our construction does not require the classical linear code \(C\) that is used as the ingredient to satisfy the dual containment condition, or, equivalently, \(C^{\perp _h}\) is not required to satisfy the self-orthogonality condition. We prove lower bounds on the minimum distance of quantum codes obtained from our construction. We give examples of record breaking quantum codes produced from our construction. In these examples, the ingredient code \(C\) is nearly dual containing, or, equivalently, \(C^{\perp _h}\) is nearly self-orthogonal, by which we mean that \(\dim (C^{\perp _h})-\dim (C^{\perp _h}\cap C)\) is positive but small. 相似文献
105.
Marcos Petrúcio Cavalcante Heudson Mirandola Feliciano Vitório 《Journal of Geometric Analysis》2014,24(1):205-222
Let $x:M^{m}\to\bar{M}$ , m≥3, be an isometric immersion of a complete noncompact manifold M in a complete simply connected manifold $\bar{M}$ with sectional curvature satisfying $-k^{2}\leq K_{\bar{M}}\leq0$ , for some constant k. Assume that the immersion has finite total curvature in the sense that the traceless second fundamental form has finite L m -norm. If $K_{\bar{M}}\not\equiv0$ , assume further that the first eigenvalue of the Laplacian of M is bounded from below by a suitable constant. We prove that the space of the L 2 harmonic 1-forms on M has finite dimension. Moreover, there exists a constant Λ>0, explicitly computed, such that if the total curvature is bounded from above by Λ then there are no nontrivial L 2-harmonic 1-forms on M. 相似文献
106.
Przemyslaw W. Wachulak Andrzej Bartnik Henryk Fiedorowicz Dalibor Pánek Petr Br??a 《Applied physics. B, Lasers and optics》2012,109(1):105-111
Laser-produced plasma sources of short-wavelength radiation offer an interesting alternative to synchrotron and free-electron laser installations. Recently, we reported on a newly developed desktop EUV microscope based on plasma generated from a gas-puff target and diffractive optics. The half-pitch resolution of the microscope approached 50?nm. Compared to analogous microscopes based on synchrotron sources, our system is compact and cost-effective. In this paper, we present the results of imaging experiments on a thin polycrystalline object that was carried out in order to further examine the applicability of the microscope. We have demonstrated here that EUV microscopy can provide structural information that cannot be accessed by conventional optical microscopy or SEM. 相似文献
107.
We study spectral approximations of Schrödinger operators T = ?Δ+Q with complex potentials on Ω = ?d, or exterior domains Ω??d, by domain truncation. Our weak assumptions cover wide classes of potentials Q for which T has discrete spectrum, of approximating domains Ωn, and of boundary conditions on ?Ωn such as mixed Dirichlet/Robin type. In particular, Re Q need not be bounded from below and Q may be singular. We prove generalized norm resolvent convergence and spectral exactness, i.e. approximation of all eigenvalues of T by those of the truncated operators Tn without spectral pollution. Moreover, we estimate the eigenvalue convergence rate and prove convergence of pseudospectra. Numerical computations for several examples, such as complex harmonic and cubic oscillators for d = 1,2,3, illustrate our results. 相似文献
108.
Leo Valenta Petr Kovaí
ek Vclav Vale Zdenk Bastl Karolina A. Drogowska Timotheus A. Verhagen Radek Cibulka Martin Kalb
《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(5):1338-1342
Spatially resolved functionalization of 2D materials is highly demanded but very challenging to achieve. The chemical patterning is typically tackled by preventing contact between the reagent and material, which brings various accompanying challenges. Photochemical transformation on the other hand inherently provides remote high spatiotemporal resolution using the cleanest reagent—a photon. Herein, we combine two competing reactions on a graphene substrate to create functionalization patterns on a micrometer scale via the Mitsunobu reaction. The mild reaction conditions allow introduction of covalently dynamic linkages, which can serve as reversible labels for surface‐ or graphene‐enhanced Raman spectroscopy characterization of the patterns prepared. The proposed methodology thus provides a pathway for local introduction of arbitrary functional groups on graphene. 相似文献
109.
Luk Petera Klaudia Mrazikova Lukas Nejdl Kristyna Zemankova Marketa Vaculovicova Adam Pastorek Svatopluk Civis Petr Kubelik Alan Heays Giuseppe Cassone Jiri Sponer Martin Ferus Judit Sponer 《Molecules (Basel, Switzerland)》2021,26(8)
Synthesis of RNA nucleobases from formamide is one of the recurring topics of prebiotic chemistry research. Earlier reports suggest that thymine, the substitute for uracil in DNA, may also be synthesized from formamide in the presence of catalysts enabling conversion of formamide to formaldehyde. In the current paper, we show that to a lesser extent conversion of uracil to thymine may occur even in the absence of catalysts. This is enabled by the presence of formic acid in the reaction mixture that forms as the hydrolysis product of formamide. Under the reaction conditions of our study, the disproportionation of formic acid may produce formaldehyde that hydroxymethylates uracil in the first step of the conversion process. The experiments are supplemented by quantum chemical modeling of the reaction pathway, supporting the plausibility of the mechanism suggested by Saladino and coworkers. 相似文献
110.
Petr Tůma Martin Jaček Blanka Sommerová Pavel Dlouhý Radka Jarošíková Jitka Husáková Veronika Wosková Vladimíra Fejfarová 《Electrophoresis》2022,43(11):1129-1139
Determination of the broad-spectrum antibiotics amoxicilline (AMX) and ceftazidime (CTZ) in blood serum and microdialysates of the subcutaneous tissue of the lower limbs is performed using CE with contactless conductivity detection (C4D). Baseline separation of AMX is achieved in 0.5 M acetic acid as the background electrolyte and separation of CTZ in 3.2 M acetic acid with addition of 13% v/v methanol. The CE-C4D determination is performed in a 25 µm capillary with suppression of the EOF using INST-coating on an effective length of 18 cm and the attained migration time is 4.2 min for AMX and 4.4 min for CTZ. The analysis was performed using 20 µl of serum and 15 µl of microdialysate, treated by the addition of acetonitrile in a ratio of 1/3 v/v and the sample is injected into the capillary using the large volume sample stacking technique. The LOQ attained in the microdialysate is 148 ng/ml for AMX and 339 ng/ml for CTZ, and in serum 143 ng/ml for AMX and 318 ng/ml for CTZ. The CE-C4D method is employed for monitoring the passage of AMX and CTZ from the blood circulatory system into the subcutaneous tissue at the sites of diabetic ulceration in patients suffering from diabetic foot syndrome and also for measuring the pharmacokinetics following intravenous application of bolus antibiotic doses. 相似文献