Oxidative dehydrogenation of crotonaldehyde overK2HPMo12O40catalyst

Summary The oxidative dehydrogenation of crotonaldehyde to furan and maleic anhydride was carried out over K₂HPMo₁₂O₄₀catalyst. A positive effect of water vapor on furan formation is explained by ability of the catalyst to isomerize 2E- to 2Z-crotonaldehyde.</o:p>     

Compatibility and Marginality

We present a way of introducing joint distibution function and its marginal distribution functions for non-compatible observables. Each such marginal distribution function has the property of commutativity. Models based on this approach can be used to better explain some classical phenomena in stochastic processes.     

Low noise optical receiver with multi-octave bandwidth

Optical and Quantum Electronics - A new approach for the design and construction of low noise broadband optical receivers is presented utilizing distributed amplification based on hybrid integrated...     

The surface electronic structure of Ag8Au4 superlattice

We present the calculations of electronic structure and photoemission spectra for a lattice-matched Ag-Au(111) superlattice. The selfconsistent band structure exhibits a superlattice gap at about 1 eV below the Fermi level. A surface state is found in this gap and its dispersion properties are investigated. Its energy location is varied with location of surface terminating plane within the superlattice period. The calculated normal photoemission spectra explain well available experimental data.     

Newtonian limits of warp drive spacetimes

We find a class of warp drive spacetimes possessing Newtonian limits, which we then determine. The same method is used to compute Newtonian limits of the Schwarzschild solution and spatially flat Friedmann-Robertson-Walker cosmological models. This work was partially supported by FCT/POCTI/FEDER.     

Zeroth and second laws of thermodynamics simultaneously questioned in the quantum microworld

A new and rather trivial model is suggested with mechanism that implies simultaneous violation of the zeroth and the second laws of thermodynamics. Mathematically rigorous quantum theory reduces to a trivial application of the Golden rule formula. It yields exciton on-energy-shell diffusion caused by bath-nonassisted excitation hopping between tails of different exciton site levels ε₁ < ε₂ broadened by bath-assisted finite life-time effects. The elastic character of the hopping implies 1 ↔ 2-symmetric transfer rate W. Thus the net diffusion exciton flow W(P ₁ - P ₂) and also, as argued, the net energy flow are possible due to different near-to-equilibrium exciton populations P ₁ > P ₂. As the sites are provided with two different baths, the population imbalance and the flows survive even for slightly different local bath temperatures T ₁ < T ₂ < T ₁ε₂/ε₁. Thus spontaneous exciton and also energy flows against temperature step become possible, in contradiction with the Clausius form of the second law. Violations of both the laws disappear in the high-temperature, i.e. classical limit Received 16 May 2001 and Received in final form 20 September 2001     

The Random Average Process and Random Walk in a Space-Time Random Environment in One Dimension

We study space-time fluctuations around a characteristic line for a one-dimensional interacting system known as the random average process. The state of this system is a real-valued function on the integers. New values of the function are created by averaging previous values with random weights. The fluctuations analyzed occur on the scale n ^1/4, where n is the ratio of macroscopic and microscopic scales in the system. The limits of the fluctuations are described by a family of Gaussian processes. In cases of known product-form invariant distributions, this limit is a two-parameter process whose time marginals are fractional Brownian motions with Hurst parameter 1/4. Along the way we study the limits of quenched mean processes for a random walk in a space-time random environment. These limits also happen at scale n ^1/4 and are described by certain Gaussian processes that we identify. In particular, when we look at a backward quenched mean process, the limit process is the solution of a stochastic heat equation.     

A multivalued version of Sharkovskiĭ’s theorem holds with at most two exceptions

A multivalued version of Sharkovskiĭ’s theorem is formulated for M-maps on linear continua and, more generally, for triangular M-maps on a Cartesian product of linear continua. This improves the main result of [AP1] in the sense that our multivalued analogue holds with at most two exceptions. A further specification requires some additional restrictions. For instance, 3- orbits of m-maps imply the existence of k-orbits for all k ? \mathbbNk \in {\mathbb{N}} , except possibly for k ?k \in {4, 6}. It is also shown that, on every connected linearly ordered topological space, an M-map with orbits of all periods can always be constructed. This demonstrates that Baldwin’s classification of linear continua in terms of admissible periods [Ba] is useless for multivalued maps.     

Problems of an additional experiment

In some situations estimates of unknown parameters must be corrected by additional measurements. It is in principle no problem to calculate the corrected estimates, however, it is of more interest to find formulae for correction itself. The formulae enable us to design an additional experiment and to judge its usefulness. The aim of the paper is to find such formulae for several situations. Supported by the grant of the Council of Czech Government MSM 6 198 959 214.