Diffusion and correlation effects in iron-doped CoO

The diffusion of ⁵⁹Fe and ⁶⁰Co has been measured in pure CoO and dilute iron-doped CoO, (Co_1?cFe_cO, as a function of temperature (1000–1400°C) and oxygen partial pressure P_{o2), (10^?7 ≦ Po2 ≦ 0 21 atm) The enhancement factors for the diffusivities of iron and cobalt are nearly identical, which suggests that the primary cause of the enhancement is the increased concentration of charge-compensating cation vacancies with the addition of iron. The Fe ions dissolved in CoO appear to exist as a mixture of Fe²⁺ and Fe³⁺ ions, the fraction of iron ions in the three-plus state decreases with decreasing Po2 The simultaneous diffusion of ⁵²Fe and ⁵⁹Fe has been measured as a function of (itpo; at 1200°C The correlation factor for Fe impurity diffusion determined from the isotope-effect measurements is about the same as that for self-diffusion in CoO at high (itPo2} (2 × 10^?3 ≦ p_o2 ≦ 0 21 atm), but increases slightly with decreasing p_O2 Both the enhancement-effect and isotope-effect experiments suggest that the nearestneighbor interactions between Fe ions and vacancies is small, and that the dissolved Fe ions do not have strongly bound electron holes.     

Beziehung zwischen den freien Sulfhydrylgruppen und ehromatographischer Heterogenität und Polymerisation des Rinderserumalbumins

Ohne Zusammenfassung     

A new upper limit for the branching ratio for the decay η → π0e+e−

We have looked for the decay η → π⁰e⁺e^? in an optical spark chamber experiment at the Rutherford Laboratory. Our observations are consistent with no events being seen and give an upper limit rate (η → π⁰e⁺e^?)/ rate (η → all) < 4.5 × 10^?5 (90% C.L.).     

A measurement of the electromagnetic form factor of the eta meson and of the branching ratio for the eta Dalitz decay

In an optical spark chamber experiment we have obtained a sample of 80 eta Dalitz decays (η → e⁺e^?γ) and have measured the eta electromagnetic form factor to be F(X) = 1.0?(0.22 ±0.45)X, where X=M_ee²/M_η², and the branching ratio (η→e⁺e^?γ/(η→π⁺π^?π⁰)= (0.0082 ± 0.0020).     

Isoscalar excitations of7Li

Inelastic scattering of 35 MeV alpha particles from⁷Li was used to induce the five known inelastic excitations. A collective coupled channel analysis yielded deformations for each transition and isoscalar quadrupole reduced transition rates were determined for each. The strong-coupling rotational model was found to agree closely with the results for the states associated with the ground state band, but the higher states are excited mainly by a two-step mechanism.     

Cation self-diffusion and the isotope effect in Mn1−δO

Diffusion of ⁵⁴Mn in Mn_1?δO single crystals has been measured by a serial sectioning technique as a function of temperature (1000–1500°C) and deviation from stoichiometry (0.00003 < δ < 0.12). The value of m in the expression varies from about 6 at low Po₂ at all temperatures to a value approacing 2 at high Po₂ and high temperatures, thus suggesting that diffusion occurs by doubly charged vacancies at low Po₂ with increasing contributions from singly charged and neutral vacancies as Po₂ (and vacancy concentration) increases. For δ near 0.1, the values of D fall below the values extrapolated from smaller defect concentrations. The isotope effect for cation self-diffusion was measured by simultaneous diffusion of ⁵²Mn and ⁵⁴Mn in Mn_1?δO (0.0004 < δ < 0.116) at 1300 and 1500°C. The measured values of fΔK are independent of temperature within experimental error, and decrease from a value of 0.70 at low defect concentrations to 0.37 for large values of δ. The isotope-effect results suggest that diffusion occurs by single non-interacting vacancies at low defect concentrations; defect-defect interactions become important for δ ? 0.01. The defect-defect interactions may involve essentially individual defects or may result in defect clusters; the similarity between the present isotope-effect results and those for Fe_1?δ0 suggests that defect clustering plays a significant role in mass transport in Mn_1?δO at large values of δ.     

A study of the 12N 2.43 MeV level

We have measured the differential cross sections for the reactions ¹²C(τ, τ′)¹²C(17.77 MeV 0⁺T=1) and ¹²C(τ, t)¹²N(2.43 MeV) at E_τ=44 MeV. The similar shapes of the angular distributions and the relative magnitudes of the cross sections suggest that the ¹²N 2.43 MeV level is the 0⁺T=1 analog to the ^q12C 17.77 MeV level. We have also studied the reaction ¹⁴N(p,t) ¹²N(2.43 MeV) at E_p=52 MeV. The strength with which this level is excited in this reaction is consistent with reasonable two-step calculations assuming the 2.43 MeV level to have J^π=0⁺.