Catalysis of heteropoly acidic salts for synthesis of diethylene glycol ethyl ether with diethylene glycol and ethanol

Ag₃PW₁₂O₄₀ and Ag₄SiW₁₂O₄₀ showed high activity and stability in the synthesis of diethylene glycol ethyl ether with diethylene glycol and ethanol, on which the conversion is 80.2% and 78.4%, respectively, and the selectivity of diethylene glycol ether is 75.4% and 80.6%, respectively. After the third reaction cycle, Ag₃PW₁₂O₄₀ and Ag₄SiW₁₂O₄₀) still showed higher activity and selectivity, on which the conversion is 72. 6% and 77.5% respectively. But the activity of Ag₃PMo₁₂O₄₀ is lower, the conversion is only 21.0%. IR, XRD, TG and n‐butylamine titrimetry showed that the catalysis may be connected with two kinds of acidic centers owned by heteropoly acidic salt.     

Facile synthesis of monodisperse silver nanoparticles by bio-template of squama inner coat of onion

This paper describes a facile sy]nthetic method for preparing monodisperse silver nanoparticles by bio-template of the squama inner coat of onion. The method is able to make silver nanoparticles with average diameters in the range of 4.6–7.9 nm with narrow size distribution. The important factors in the synthesis of monodisperse silver nanoparticles were discussed. The nanoparticles were characterized by transmission electron microscope, Powder X-ray diffraction and UV-Vis spectroscopy. A possible formation mechanism was also proposed. Because of its simple apparatus, high yield, convenient operation and mild conditions, this synthetic method will have potential application in preparing nanoparticles.     

175-W continuous-wave master oscillator power amplifier structure ytterbium-doped all-fiber laser

We report on hundred watts range ytterbium-doped all-fiber laser assembly based on the master oscillator power amplifier structure. It consisted of an oscillator and an amplifier with all-fiber components. And fiber fusion splice made the laser be an integrated fiber system. It generated up to 175.5 W of continuouswave (CW) output power at 1085 nm with more than 75% extraction efficiency in the amplifier when the total coupled pump power into the double clad fiber was 270 W.     

Ultraviolet and visible upconversion luminescence of Tm(0.1)Yb(5):FOV oxyfluoride nanophase vitroceramics

The ultraviolet upconversion luminescence of Tm³⁺ ions sensitized by Yb³⁺ ions in oxyfluoride nanophase vitroceramics when excited by a 975 nm diode laser was studied. An ultraviolet upconversion luminescence line positioned at 363.6 nm was found. It was attributed to the fluorescence transition of ¹D₂→³H₆ of Tm³⁺ ion. Several visible upconversion luminescence lines at 450.7 nm, (477.0 nm, 462.5 nm), 648.5 nm, (680.5 nm, 699.5 nm) and (777.2 nm, 800.7 nm) were also found, which result respectively from the fluorescence transitions of ¹D₂→³F₄, ¹G₄→³H₆, ¹G₄→³F₄, ³F₃→³H₆ and ³H₄→³H₆ of Tm³⁺ ion. The careful measurement and analysis of the variation of upconversion luminescence intensity F as a function of the 975 nm pumping laser power P prove that the upconversion luminescence of ¹D₂ state is partly a five-photon upconversion luminescence, and the upconversion luminescence of ¹G₄ state and ³H₄ state are respectively the three-photon and two-photon upconversion luminescence. The theoretical analysis suggested that the upconversion mechanism of the 363.6 nm ¹D₂→³H₆ upconversion luminescence is partly the cross energy transfer of {³H₄(Tm³⁺), ³F₄(Tm³⁺), ¹G₄(Tm³⁺)→¹D₂(Tm³⁺)} and {¹G₄(Tm³⁺)→³F₄(Tm³⁺), ³H₄(Tm³⁺)→¹D₂(Tm³⁺)} between Tm³⁺ ions. In addition, the upconversion luminescence of ¹G₄ and ³H₄ state results respectively from the sequential energy transfer {²F_5/2(Yb³⁺)→²F_7/2(Yb³⁺), ³H₄(Tm³⁺)→¹G₄(Tm³⁺)} and {²F_5/2(Yb³⁺) →²F_7/2(Yb³⁺), ³F₄(Tm³⁺)→³F₂(Tm³⁺)} from Yb³⁺ ions to Tm³⁺ ions. Supported by the National Natural Science Foundation of China (Grant No. 10674019)     

连续时间马尔可夫决策过程的折扣模型

本文考虑的是转移速率族任意且费用率函数可能无界的连续时间马尔可夫决策过程的折扣模型．放弃了传统的要求相应于每个策略的　Ｑ　－过程唯一等条件,而首次考虑相应每个策略的　Ｑ　－过程不一定唯一,　转移速率族也不一定保守,　费用率函数可能无界,　且允许行动空间非空任意的情形．　本文首次用"α－折扣费用最优不等式"更新了传统的α－折扣费用最优方程,并用"最优不等式"和新的方法,不仅证明了传统的主要结果即最优平稳策略的存在性,　而且还进一步探讨了（　∈＞０　　）－最优平稳策略,具有单调性质的最优平稳策略,　以及（∈≥０）　－最优决策过程的存在性,　得到了一些有意义的新结果．　最后,　提供了一个迁移率受控的生灭系统例子,　它满足本文的所有条件,　而传统的假设（见文献［１－１４］）均不成立．     

关于循环子半群的结构与数量问题及拟环的特征与结构

彻底解决了所有循环半群及其子群的结构和数量问题,并讨论了拟群分解问题,同时,对群论基本定理作了部分推广,并给出了定理的另一部分不可推广的反例,最后,建立了一类特殊环－拟环。     

Improved synthesis of (+/-)-4,12-dihydroxy[2.2]paracyclophane and its enantiomeric resolution by enzymatic methods: planar chiral (R)- and (S)-phanol

(+/-)-4,12-Dihydroxy[2.2]paracyclophane [(+/-)-PHANOL] is readily prepared from [2.2]paracyclophane by an improved synthetic protocol. Enzymatic kinetic resolution of its bis-acetate proceeds with good enantioselection. Separation, hydrolysis, and recrystallization provides both enantiomers of PHANOL in high enantiopurity.     

OPCPA系统中光栅对不平行度对脉冲时间波形的影响

 利用光线追迹法和四阶龙格-库塔法分析了光参量啁啾脉冲放大系统中实际展宽器和压缩器所带来的各阶色散，并将其代入放大过程数值模拟了脉冲变化的情况，讨论了压缩器光栅对表面不平行、刻线不平行、信号光强度、泵浦光强度等因素对输出脉冲宽度和时间波形的影响。结果表明，光栅对表面不平行将引起脉冲宽度变大，且光栅顺时针旋转对脉冲宽度和波形影响更大。而光栅刻线不平行时，当仅考虑二阶色散时，夹角为0.8°时脉宽最小，考虑到三阶色散时，夹角为1°脉宽最小，且光栅顺时针和逆时针旋转对脉冲的作用相同。对实际OPCPA系统，当放大晶体材料及长度一定时，尽量调整压缩器光栅平行，信号光强度和泵浦光强度有一最佳值能使输出脉冲宽度达到最小。     

一种掺钕光纤激光器与倍频技术实现的数值模拟

从双包层光纤激光器的速率方程和光传输方程出发，建立数学模型，进行数值计算并对掺钕光纤激光器输出功率沿光纤的分布以及不同光纤长度下抽运功率和输出功率沿光纤的分布进行了数值模拟。以808nm半导体激光器为抽运源，掺钕双包层光纤为增益介质，并以KTP作为倍频晶体，计算并模拟其倍频效率和相位匹配角。最后，对光纤激光器及其倍频的实现进行了模拟研究。结果表明，该光纤激光器能够高效率地实现可见光输出。     

具有真细菌基因启动子活性的古生菌DNA片段

以大肠杆菌启动子探测质粒pKK232-8 为载体,用4 组限制性内切酶分别消化古生菌盐生盐杆菌R1(Halobacterium halobium )的染色体DNA,在体外进行重组,转化E.coliDH-5α感受态细胞,得到12 个转化子(T1～T12),其抗性水平分布在10～500 m g/L的区间内. 将这些转化子所含质粒分别命名为pSX1～pSX12,限制性酶切分析表明,这些质粒各插入了一段不同的外源DNA 片段,杂交分析表明,抗性最强的转化子T11 所含质粒pSX11 上插入了一段来源于盐生盐杆菌R1 染色体的DNA 片段. 该DNA 片段在大肠杆菌中具有启动子功能.