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971.
X-ray diffraction studies have been undertaken on aqueous solutions of hydroxy propylcellulose (HPC) over a wide range of the scattering vector Q. The experiments revealed only modest differences in local structure on a distance scale ca. 5–300 Å despite the fact that they covered concentrations generally interpreted as ranging from the isotropic (35.1 wt %) to the anisotropic liquid crystalline (LC) phase (53.5 wt %). Several models were used to interpret the small-angle scattering data, and each gave similar structural parameters and extrapolated intensities ( Q → 0) for both solutions. Peaks were observed with d-spacings ca. 12–17 Å in both materials. Wide-angle x-ray scattering (WAXS) showed slightly increased local order over a size range ca. 5–20 Å for the anisotropic solution, and this is consistent with a greater intensity of the 13 Å peak in this material. It is difficult to reconcile these findings with an interpretation of the LC state involving major differences with the isotropic phase and a high degree of orientational order extending over long length scales. 相似文献
972.
V. N. Korneev P. M. Sergienko V. A. Shlektarev V. M. Aul’chenko M. A. Bukin V. M. Titov B. P. Tolochko M. R. Sharafutdinov A. V. Zabelin E. I. Litvinov A. M. Matyushin V. G. Stankevich M. A. Sheromov O. V. Naida A. A. Vazina 《Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques》2007,1(1):99-104
To modernize the DICSI station, new hardware and software have been created according to the conditions of the operating storage ring “Sibir’-2” beam channel. The recording system has been successfully tested on the operating channel of the storage ring VEPP-3 (Budker Institute of Nuclear Physics Siberian Branch, Russian Academy of Sciences, Novosibirsk) using the time-resolved “diffraction cinema” technique in studying real biological objects in the static and dynamic modes of data accumulation. At the DICSI station, structural changes in medical and biological objects are permanently investigated. The specific structure dimensions of these objects are in the nanometric range. 相似文献
973.
A rapid single-step method for the electrosynthesis of chloro and bromo complexes of palladium(II and IV), viz. M2[PdX4] and M2[PdX6], by the dissolution of a palladium anode in chloride or bromide containing media is described. Electrolysis of dilute HX solution in the presence of pyridine, 2,2′-bipyridyl or 1,10-phenanthroline gives rise to non-electrolytes, e.g. trans-[PdX2(py)2], [PdX2(bipy)] and [PdX2(phen)]. Anodic oxidation of palladium in HX medium in the presence of acetonitrile and benzonitrile also gives the non-electrolytes trans-[PdX2(CH3CH2NH2)2] and trans-[PdX2(C6H5CH2NH2)2], respectively. 相似文献
974.
975.
B. Abramovitz 《Acta Appl Math》1994,36(3):211-226
In this work, we consider the regularization method for linear ill-posed problems. For operators and approximating subspaces satisfying certain conditions and for a specific form of the regularization parameter, upper and lower bounds are given for the condition number of the corresponding discrete problem. 相似文献
976.
977.
This paper presents a connection between the defining basis presented by Beilinson-Lusztig-MacPherson [1] in their geometric setting for quantum GLn and the isomorphism classes of linear quiver representations. More precisely, the positive part of the basis in [1] identifies with the defining basis for the relevant Ringel-Hall algebra; hence, it is a PBW basis in the sense of quantum groups. This approach extends to q-Schur algebras, yielding a monomial basis property with respect to the Drinfeld-Jimbo type presentation for the positive (or negative) part of the q-Schur algebra. Finally, the paper establishes an explicit connection between the canonical basis for the positive part of quantum GLn and the Kazhdan-Lusztig basis for q-Schur algebras. 相似文献
978.
C.J. Lu H.M. Shen S.B. Ren Y.N. Wang 《Applied Physics A: Materials Science & Processing》1997,65(4-5):395-401
3 thin films is systematically studied by using X-ray diffraction (XRD). The PbTiO3 thin films with different average grain sizes were prepared on various substrates by a sol-gel process. The films on NaCl
and fused glass are randomly grain-oriented, while those on (111)Pt/Ti/SiO2/Si are highly {100} cubic index grain-oriented . It is found from the XRD patterns of the films on NaCl that with decreasing
average grain size from 230 to 80 nm, the intensities of high h index (h>l) peaks (hkl), such as (100), (110), (200), (201),
(210), (211), etc., decrease rapidly and ultimately disappear, whereas another set of peaks (lkh), including (001), (002),
(102), (112), etc., are still intense. This interesting result suggests that at grain size below a certain critical size an
increasing number of grains no longer show 90°-domains, which is confirmed by TEM observations. Meanwhile, X-ray evidence
of such a grain-size-related absence of 90°-domains is also found for PbTiO3 films on Pt(111) and fused-glass substrates. The volume fractions of single-domain grains (without 90°-domains) in the films
are estimated from their XRD patterns. By combining SEM and TEM investigations, the critical grain size for the formation
of 90°-domains is further determined to be near 200 nm.
Received: 19 December 1996/Accepted: 24 March 1997 相似文献
979.
The phenomenon of “475°C embrittlement” of Fe?Cr?Ni alloys with Fe/Cr ratios of 2.7 and 1.05, containing 0.2 and 4 at.% Ni, has been investigated using the Mössbauer effect and hardness measurements. The results show that the addition of nickel to Fe-xCr alloys (x=25 and 45 at.%) increases the transformation rate notoriously in the first hours of aging, the effect of this element being more important for alloys with Fe/Cr=1.05. 相似文献
980.
R. B. Gelfand V. A. Gordeev Yu. V. Gorelkinsky S. A. Kuten A. V. Mudry N. N. Nevinny V. I. Rapoport A. G. Ulyashin 《Hyperfine Interactions》1991,64(1-4):579-584
The electronic structure of muonium (Mu) located at the bond-centered sites of the silicon and diamond crystals is calculated
by the intermediate neglect of differential overlap method. Calculations of the electronicg- and hyperfine interaction tensors of the impurity atom are performed. The results obtained are compared to the experimental
properties of “anomalous” muonium Mu*. It is shown that the properties of Mu located at the bond-centered sites of the Si and C lattices are in qualitative agreement
with the observed properties of Mu*. 相似文献