An efficient chloride-selective fluorescent chemosensor based on 2,9-bis(4'-hydroxyphenyl)phenanthroline Cu(II) complex

A new complex Cu(II)/L, composed of 2,9-bis(4'-hydroxyphenyl)phenanthroline (L) and Cu(II), was synthesized as an efficient chloride-detection fluorescent chemosensor with high selectivity and sensitivity over other halide anions, F(-), Br(-), I(-). The recognition mechanism was discussed primarily.     

Simultaneous analysis of multiple bioactive constituents in Rheum tanguticum Maxim. ex Balf. by high-performance liquid chromatography coupled to tandem mass spectrometry

A simple, rapid method was developed using on-line high-performance liquid chromatography (HPLC)-diode array detection (DAD)/electrospray ionization mass spectrometry (ESI-MS) to simultaneously analyze multiple bioactive constituents in the extract of Rheum tanguticum Maxim. ex Balf. (Dahuang), a traditional Chinese medicine (TCM). Many bioactive constituents gave prominent [M-H]- ions in the negative ion ESI mass spectra. Among them, 41 different constituents including 16 anthraquinone derivatives, 7 phenylbutanone glucopyranosides, 4 stilbenes and 14 tannins were unambiguously identified or tentatively characterized based on their retention times, UV spectra and mass spectra in comparison with the data from standards or references. Meanwhile, some principles of fragmentation behavior for different types of constituents were proposed, which could contribute to the elucidation of these constituents in Rheum tanguticum.     

Covalent modification of glassy carbon electrode with aspartic acid for simultaneous determination of hydroquinone and catechol

Glassy carbon electrode (GCE) is covalently modified with aspartic acid (Asp). The modified electrode is used for the simultaneous electrochemical determination of hydroquinone (HQ) and catechol (CC) and shows an excellent electrocatalytical effect on the oxidation of HQ and CC by cyclic voltammetry (CV) in 0.1 mol/L acetate buffer solution (pH 4.5). In differential pulse voltammetric (DPV) measurements, the modified electrode could separate the oxidation peak potentials of HQ and CC present in binary mixtures by about 101 mV though the bare electrode gave a single broad response. A successful elimination of the fouling effect by the oxidized product of HQ on the response of CC has been achieved at the modified electrode. The determination limit of HQ in the presence of 0.1 mmol/L CC was 9.0 x 10(-7) mol/L and the determination limit of CC in the presence of 0.1 mmol/L HQ was 5.0 x 10(-7) mol/L. The proposed method has been applied to the simultaneous determination of HQ and CC in a water sample with simplicity and high selectivity.     

一种X射线聚焦光学及其在X射线通信中的应用

基于栅控脉冲发射X射线源与单光子探测技术的X射线通信已经实现了实验室语音通信验证,并对通信系统的误码率性能进行了分析,为探索未来X射线深空应用打下了坚实的基础.针对目前X射线通信面临的信号发散角大、通信距离短、难以实现工程化应用的情况,迫切需要对X射线通信天线系统进行深入研究.为了提高信号增益、增大X射线通信的距离,提出了多层嵌套式X射线聚焦光学作为X射线通信的"收发天线",理论分析了X射线聚焦光学用于X射线通信"收发天线"的可行性,分析了X射线聚焦光学的理论基础与结构设计,对"发射天线"发散角、"接收天线"有效面积与焦斑尺寸、信号增益等性能做了探讨.结果表明:在信号发射端,"天线"的发散角为3 mrad左右,发射增益23 d B;在信号接收端,"接收天线"的有效面积5700 mm2@1.5 keV,焦斑直径为4.5 mm,接收增益为25 d B,通信系统总的增益可达48 d B.     

PAPIDITY DISTRIBUTIONS IN UNEQUAL NUCLEI COLLISION AT HIGH ENERGIES AND HYDRODYNAMICAL MODEL

The mechanism of high-energy A'－A collision (A>A',A'^1/3>>1) and the space-time evolution of the fluid formed in the collision are analysed. The corresponding 1+1 dimensional hydrodynamical equations are established. The average rapidity distributions are estimated and compared with some cosmic ray events. The origin of the nonsymmetry of rapidity distribution is explained.

     

具有本征低晶格热导率的硫化银快离子导体的热电性能

硫化银(Ag_2S)是一种典型的快离子导体材料,前期关于Ag_2S的研究主要集中在光电和生物等领域.最近的研究表明, a-Ag_2S具有和金属一样的良好延展性和变形能力.但是, Ag_2S的热电性能尚无公开报道.本工作合成了单相Ag_2S化合物,系统研究了其在300—600 K范围的物相变化、离子迁移特性和电热输运性质.研究发现, Ag_2S在300—600 K温度区间表现出半导体的电输运性质.由于单斜-体心立方相晶体结构转变, Ag_2S的离子电导率、载流子浓度、迁移率、电导率、泽贝克系数等性质在455 K前后出现急剧变化.在550 K, Ag_2S的功率因子最高可达5μW·cm~(–1)·K~(–2). Ag_2S在300—600 K温度区间均表现出本征的低晶格热导率(低于0.6 W·m~(–1)·K~(–1)). S亚晶格中随机分布的类液态Ag离子是导致b-Ag_2S体心立方相具有低晶格热导率的主要原因.在573 K, Ag_2S的热电优值可达0.55,与Ag_2Se, Ag_2Te, CuAgSe等已报道的Ag基快离子导体热电材料的性能相当.     

Analysis on Patterns of Globally Coupled Phase Oscillators with Attractive and Repulsive Interactions

The Hong-Strogatz (HS) model of globally coupled phase oscillators with attractive and repulsive interactions reflects the fact that each individual (oscillator) has its own attitude (attractive or repulsive) to the same environment (mean field). Previous studies on HS model focused mainly on the stable states on Ott-Antonsen (OA) manifold. In this paper, the eigenvalues of the Jacobi matrix of each fixed point in HS model are explicitly derived, with the aim to understand the local dynamics around each fixed point. Phase transitions are described according to relative population and coupling strength. Besides, the dynamics off OA manifold is studied.     

分子动力学模拟壁面附近流体特性及降温过程

采用三相模型计算结果表明:近壁区内流体密度呈现出"层状化"的特点,切向应力张量呈"振荡"分布;固液界面张力随温度增加而降低;进一步增强壁面浸润性,固液界面张力变化不大;同温壁面对近壁区流体特性的影响较大,近壁区之外的流体特性与两相模型吻合较好.降低壁面温度的模拟表明,当温差减小时,传热量减小,界面接触热阻占主导地位.     

Ultrafast Electron Diffraction with Spatiotemporal Resolution of Atomic Motion

Ultrafast electron diffraction （UED） is a rapidly advancing technique capable of recording the atomic-detail structural dynamics in real time. We report the establishment of the first UED system in China. Employing this UED apparatus, both the coherent and the concurrent thermal lattice motions in an aluminium thin-film, trigged by ultrafast laser heating, have been observed. These results demonstrate its ability to directly measure a sub-milli-angstrom lattice spacing change on a sub-picosecond time scale.     

微小圆通道内流动沸腾换热特性的研究

微小通道内相变换热具有热流密度高、单位体积内换热面积大、结构紧凑等特点,成为高效紧凑式换热器设计的重要途径。本文以氟利昂R113为工质,完成了0.7、1.1和1.4 mm的圆形小通道内的流动沸腾实验,对小通道内流动沸腾换热特性进行了分析,拟合了计算沸腾换热特性的实验关联式,为工程实际应用提供参考。