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971.
Ma Y Xu GF Yang X Li LC Tang J Yan SP Cheng P Liao DZ 《Chemical communications (Cambridge, England)》2010,46(43):8264-8266
Utilization of the strong electron-withdrawing ligand, hfac, leads to a novel dinuclear dysprosium single-molecule magnet featuring a pyrazine bridge with a large anisotropic barrier. 相似文献
972.
提出了一种MVDR(最小方差无失真响应)的改进算法,用以解决常规MVDR算法由于阵形时变而出现的性能下降问题。在获得时变阵形估计数据的基础上,该算法以统计时段内的平均阵形为基准阵形,在每个扫描方向上根据实际阵形和基准阵形的差异对阵列互谱矩阵多样本进行相位补偿,从而实现统计时段内的互谱矩阵多样本相干累加和目标检测。数值仿真与海上实验数据处理结果表明:与传统MVDR算法相比,改进算法有效缓解了时变阵形下的目标测向角度模糊问题,可提高拖线阵目标左右舷分辨性能、增强弱目标检测能力。 相似文献
973.
太阳光泵浦激光器直接利用太阳光作为泵浦源,实现了太阳光能量到激光能量的直接转化。设计了分腔水冷型金属锥形泵浦腔,以直径8 mm,长115 mm的Nd:YAG晶体棒作为激光工作物质,用有效面积1.03 m2菲涅尔透镜会聚太阳光,实验获得了23.7 W的稳定激光输出,斜效率为7.87%。通过对比实验,改进后的分腔水冷型太阳光泵浦激光器较原有锥形腔激光器有55.92%的激光输出功率提升。分别从侧面泵浦光在冷却水中的吸收损耗以及其耦合效率等方面对新型腔体结构进行了分析,证实了分腔水冷型腔体结构对侧面泵浦效率的提高,并提出了陶瓷漫反射材质的分腔水冷型激光腔的设计。 相似文献
974.
975.
针对水下三维成像的空间分辨率难以提高,且具有较高旁瓣级的问题,提出了一种二维解卷积波束形成高分辨三维声成像算法,该算法首先完成任意距离切片的平面阵波束形成,近场情况下采用菲涅尔近似实现近场平面阵波束形成,然后通过二维解卷积技术对任意距离切片的二维波束形成结果进行解卷积处理,去除阵列指向性函数的影响,改善波束响应非理想冲击函数所造成波束形成主瓣宽及旁瓣级高的问题。通过计算机仿真分析,新算法可以有效的提高水下三维成像的空间分辨率,抑制旁瓣级,并能够在较宽频带和不同阵列孔径内保持与常规波束形成相当的稳定性。通过试验研究,新方法比常规波束形成实际目标成像分辨率提高一倍,最高旁瓣级下降20 dB,验证了该算法在实际系统中的有效性. 相似文献
976.
Study on the optical limiting properties of the mixed liquid of carbon black suspensions and
green tea solution by multi-pulse laser 下载免费PDF全文
The optical limiting properties of the mixed liquid of carbon black
suspensions (CBS) and green tea solution were studied by using an 8
ns laser pulse at 532\,nm. The optical limiting effects of the CBS
and mixed liquid have been compared between 5 and 10\,Hz repetition
frequencies with nanosecond laser pulse. The experimental results
indicate that the optical limiting threshold of the sample with the
incidence laser at 10\,Hz repetition frequency is lower than at
5\,Hz repetition frequency. The possible reasons for the influence
of the repetition frequency on the samples are discussed. And by
observing the optical radiant distributions when the laser pulse
passing through different samples, a possible mechanism for the
observed effects is suggested. At the same time, the result shows
that the optical limiting of CBS is the dominant factor to optical
limiting of the mixed liquid. 相似文献
977.
提出一种针对水下稀疏目标的时域压缩合成孔径声呐成像方法(TC-SAS),实现了水声目标高分辨实时成像。通过多子阵的孔径合成,在时域上构造出成像网格格点到有效孔径内逐帧阵列的格林函数,并给出成像区域散射强度到数据域的映射矩阵;然后利用该区域空域稀疏的先验知识,通过正交匹配追踪的稀疏重构方式,解算出成像区域散射系数矩阵,实现了稀疏目标高分辨成像.同时,针对线性调频信号提出数据缩减的方法,通过对观测数据和字典矩阵同时脉压后截取,减小了数据规模;进一步结合二维矩阵数表查表的方法,以空间换时间,实现了区块实时成像。数值仿真以及湖试试验表明,所提算法能分辨出传统的时延求和算法难以分辨的目标,并且在图像清晰度指标上平均提升4.9 dB.改善了合成孔径声呐的成像质量. 相似文献
978.
Jian Zhou Xi Li Linlin Yang Songlin Yan Mengmeng Wang Dan Cheng Qi Chen Yulin Dong Peng Liu Weiquan Cai Chaocan Zhang 《Analytica chimica acta》2015
A novel electrochemical sensor based on Cu-MOF-199 [Cu-MOF-199 = Cu3(BTC)2 (BTC = 1,3,5-benzenetricarboxylicacid)] and SWCNTs (single-walled carbon nanotubes) was fabricated for the simultaneous determination of hydroquinone (HQ) and catechol (CT). The modification procedure was carried out through casting SWCNTs on the bare glassy carbon electrode (GCE) and followed by the electrodeposition of Cu-MOF-199 on the SWCNTs modified electrode. Cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) were performed to characterize the electrochemical performance and surface characteristics of the as-prepared sensor. The composite electrode exhibited an excellent electrocatalytic activity with increased electrochemical signals towards the oxidation of HQ and CT, owing to the synergistic effect of SWCNTs and Cu-MOF-199. Under the optimized condition, the linear response range were from 0.1 to 1453 μmol L−1 (RHQ = 0.9999) for HQ and 0.1–1150 μmol L−1 (RCT = 0.9990) for CT. The detection limits for HQ and CT were as low as 0.08 and 0.1 μmol L−1, respectively. Moreover, the modified electrode presented the good reproducibility and the excellent anti-interference performance. The analytical performance of the developed sensor for the simultaneous detection of HQ and CT had been evaluated in practical samples with satisfying results. 相似文献
979.
980.
Peng Sun Zihan Xia Zhongfang Li Ziwei Fan Fengqi He Qiang Liu Xiaoyan Yin 《Materials Today Chemistry》2022
A high-temperature proton exchange membrane with high proton conductivity over a wide humidity range still remains a challenge. PBI dendrimer containing triazine rings (TPBI) was synthesized to approach this aim considering its high content of hygroscopic terminal groups and of larger free volume. A novel proton conductor previously synthesized (zirconium 3-sulfopropyl phosphonate, ZrSP) was doped due to its good proton conductivity over a wide humidity range. TPBI was post-crosslinked with a tetrafunctional epoxy resin (N,N,N′,N′-tetraglycidyl-4,4′-diaminodiphenylmethane, TGDDM) to enhance the mechanical stability at low cross-linking degrees, which allowed high doping levels of ZrSP, and thus, high conductivity. The prepared membranes (TPBI-TGDDM/ZrSP) showed good thermal stability, high proton conductivity over wide humidity range, and good dimensional stability. At suitable degrees of branching, TPBI-TGDDM/ZrSP exhibited superior mechanical property, oxidative stability, methanol barrier property, and membrane selectivity than its linear analog (mPBI-TGDDM/ZrSP). As ZrSP instead of PA was applied as the proton conductor, TPBI-TGDDM/ZrSP showed good durability of proton conductivity, especially in comparison with TPBI-TGDDM/PA, which highly retarded decline in conductivity caused by PA leaking. The proton conductivity at 180 °C of TPBI(20)-TGDDM(10)/ZrSP(50) achieved 142, 84.2 and 23.6 mS cm?1 at 100%, 50%, and 0 RH, respectively. 相似文献