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91.
Dr. Wentao Xu Dr. Nikita Hanikel Dr. Kirill A. Lomachenko Dr. Cesare Atzori Dr. Alicia Lund Dr. Hao Lyu Zihui Zhou Prof. Dr. C. Austen Angell Prof. Dr. Omar M. Yaghi 《Angewandte Chemie (International ed. in English)》2023,62(16):e202300003
We report a synthetic strategy to link titanium-oxo (Ti-oxo) clusters into metal-organic framework (MOF) glasses with high porosity though the carboxylate linkage. A new series of MOF glasses was synthesized by evaporation of solution containing Ti-oxo clusters Ti16O16(OEt)32, linkers, and m-cresol. The formation of carboxylate linkages between the Ti-oxo clusters and the carboxylate linkers was confirmed by Fourier-transform infrared (FT-IR) spectroscopy. The structural integrity of the Ti-oxo clusters within the glasses was evidenced by both X-ray absorption near edge structure (XANES) and 17O magic-angle spinning (MAS) NMR. After ligand exchange and activation, the fumarate-linked MOF glass, termed Ti-Fum, showed a N2 Brunauer–Emmett–Teller (BET) surface areas of 923 m2 g−1, nearly three times as high as the phenolate-linked MOF glass with the highest BET surface area prior to this report. 相似文献
92.
Sheng Xianxian Xu Zhiqiang Liu Yulong Wang Peng Dong Jiaqi Lu Zhanpeng Shan Ali Lyu Shuguang 《Research on Chemical Intermediates》2022,48(4):1645-1663
Research on Chemical Intermediates - In this study, the removal performance and degradation mechanisms of fluoranthene (FLT) in sodium percarbonate (SPC) activated by Fe(II) system were... 相似文献
93.
Depei Meng Yichong Lyu Dr. Chuanfa Ni Dr. Min Zhou Prof. Dr. Yang Li Prof. Dr. Jinbo Hu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(13):e202104395
S-(Trifluoromethyl)benzothioate (TFBT) has been developed as an inexpensive, bench-stable, and user-friendly trifluoromethylthiolation reagent, which can be easily synthesized by using KF as the only fluorine source. By using TFBT, trifluoromethylthiolates with various counterions can be readily obtained. The synthetic application of TFBT was demonstrated by trifluoromethylthiolation-halogenation of arynes, bis(trifluoromethylthiolation)–halogenation of 1,2-benzdiynes, nucleophilic substitution of alkyl halides, deoxytrifluoromethylthiolation of alcohols, and cross-coupling with aryl and vinyl boronic acids. 相似文献
94.
Head–Tail Asymmetry as the Determining Factor in the Formation of Polymer Cubosomes or Hexasomes in a Rod–Coil Amphiphilic Block Copolymer 下载免费PDF全文
Xiaolin Lyu Anqi Xiao Wei Zhang Pingping Hou Kehua Gu Zhehao Tang Hongbing Pan Fan Wu Prof. Zhihao Shen Prof. Xing‐He Fan 《Angewandte Chemie (International ed. in English)》2018,57(32):10132-10136
The self‐assembly of a rod–coil amphiphilic block copolymer (ABCP) led to Im m and Pn m polymer cubosomes and p6mm polymer hexasomes. This is the first time that these structures are observed in a rod–coil system. By varying the hydrophobic chain length, the initial concentration of the polymer solution, or the solubility parameter of the mixed solvent, head–tail asymmetry is adjusted to control the formation of polymer cubosomes or hexasomes. The formation mechanism of the polymer cubosomes was also studied. This research opens up a new way for further study of the bicontinuous and inverse phases in different ABCP systems. 相似文献
95.
96.
G.?S.?Sur H.?L.?Sun T.?J.?Lee S.?G.?Lyu J.?E.?MarkEmail author 《Colloid and polymer science》2003,281(11):1040-1045
Mesoporous silica was synthesized by hydrolysis of tetraethylorthosilicate (TEOS, formula Si(OCH2CH3)4) at ambient temperature in a basic ethanol-water solution, with cetyltrimethyl ammonium bromide as a template. It had a surface area of approximately 1,400 m2/g, and an average pore diameter of approximately 40 Å. Portions were blended into three samples of poly(ethylene oxide) (PEO) of varying molecular weights, in the hope of making novel composites by penetrating some of the PEO chains into the silica channels. Differential Scanning Calorimetry (DSC) and X-ray diffraction (XRD) were used to characterize the structures of the PEO/mesoporous silica composites after they were held at 100 °C for up to 30 min. In both experiments, the melting temperature of the PEO decreased and ultimately disappeared. These results suggest that the PEO chains did penetrate into the silica pores, and since they were constrained in the pores, their crystallization was suppressed. This provides an interesting parallel to the disappearance of the glass transition temperatures of polymers constrained in the cavities of zeolites or in the galleries of intercalated clays. 相似文献
97.
Mesoporous titania‐Nafion composite doped with carbon nanotube (CNT) has been used for the immobilization of tris(2,2′‐bipyridyl)ruthenium(II) (Ru(bpy)32+) and alcohol dehydrogenase on an electrode surface to yield a highly sensitive and stable electrogenerated chemiluminescence (ECL) ethanol biosensor. The presence of CNT in the composite film increases not only the sensitivity of the ECL biosensor but also the long‐term stability of the biosensor. The present biosensor responds linearly to ethanol in the wide concentration ranges from 1.0×10?5 M to 1.0×10?1 M with a detection limit of 5.0×10?6 M (S/N=3). The present ECL ethanol biosensor exhibited higher ECL response compared to that obtained with the ECL biosensor based on the corresponding composite without CNT. The present CNT‐based ECL biosensor showed good long‐term stability with 75% of its initial activity retained after 2 weeks of storage in 50 mM phosphate buffer at pH 7.0. 相似文献
98.
Neural auto-regressive sequence-to-sequence models have been dominant in text generation tasks, especially the question generation task. However, neural generation models suffer from the global and local semantic semantic drift problems. Hence, we propose the hierarchical encoding–decoding mechanism that aims at encoding rich structure information of the input passages and reducing the variance in the decoding phase. In the encoder, we hierarchically encode the input passages according to its structure at four granularity-levels: [word, chunk, sentence, document]-level. Second, we progressively select the context vector from the document-level representations to the word-level representations at each decoding time step. At each time-step in the decoding phase, we progressively select the context vector from the document-level representations to word-level. We also propose the context switch mechanism that enables the decoder to use the context vector from the last step when generating the current word at each time-step.It provides a means of improving the stability of the text generation process during the decoding phase when generating a set of consecutive words. Additionally, we inject syntactic parsing knowledge to enrich the word representations. Experimental results show that our proposed model substantially improves the performance and outperforms previous baselines according to both automatic and human evaluation. Besides, we implement a deep and comprehensive analysis of generated questions based on their types. 相似文献
99.
Journal of Visualization - In this paper, the hydrodynamic characteristics associated with oblique water entry of two tandem spheres were experimentally investigated using high-speed photography.... 相似文献
100.
Jia-Ling Lyu Yi-Jung Liu Kuo-Ching Wen Chen-Yuan Chiu Yung-Hsiang Lin Hsiu-Mei Chiang 《Molecules (Basel, Switzerland)》2022,27(7)
Skin aging is a complex process involving photoaging and glycation stress, which share some fundamental pathways and have common mediators. They can cause skin damage and collagen degradation by inducing oxidative stress and the accumulation of reactive oxygen species (ROS). Chenopodium formosanum (CF), also known as Djulis, is a traditional cereal in Taiwan. This study investigated the protection mechanisms of CF extract against ultraviolet (UV) radiation and advanced glycation end products (AGEs)-induced stress. The results indicated that CF extract had strong antioxidant and free radical scavenging effects. It could reduce UV-induced intracellular ROS generation and initiate the antioxidant defense system by activating the nuclear factor erythroid 2-related factor 2 (Nrf2)/heme oxygenase-1 (HO-1) signaling pathway in human skin fibroblasts. CF extract modulated mitogen-activated protein kinase (MAPK) and transformed growth factor-beta (TGF-β) signaling pathways to alleviate oxidative stress-induced skin aging. Moreover, the results revealed that CF extract not only promoted collagen synthesis but also improved aging-induced collagen degradation. CF extract attenuated AGEs-induced ROS production and the upregulation of receptor for AGEs (RAGE). The overall results suggest that CF extract provides an effective anti-aging strategy by preventing skin damage from oxidative stress and collagen loss with potent antioxidant, anti-photoaging, and antiglycation activities. 相似文献