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91.
Dibakar Sahoo Prosenjit Bhattacharya Hirak Kumar Patra Paulami Mandal Sankar Chakravorti 《Journal of nanoparticle research》2011,13(12):6755-6760
Change of α-helical structure of heme protein (Hb) to a β-sheet and random coil conformation because of the interaction of
glycine capped gold nanoparticles (20–60 nm) as observed from attenuation total reflectance, absorption, Fourier transform
infra red, and Circular Dichroism spectroscopy has been reported in this article. Upon interaction, protein takes a cylindrical
shape of length 12 μm and diameter 0.35 μm as revealed from scanning electron microscopy and transmission electron microscopy.
The Selected-Area Electron beam Diffraction pattern shows change of crystalline structure in GNP to amorphous nature with
the interaction of Hb. 相似文献
92.
D. Bhoi P. Mandal P. Choudhury S. Dash A. Banerjee 《Physica C: Superconductivity and its Applications》2011,471(7-8):258-264
The magnetization of the PrFeAsO0.60F0.12 polycrystalline sample has been measured as functions of temperature and magnetic field (H). The observed total magnetization is the sum of a superconducting irreversible magnetization and a paramagnetic magnetization. Analysis of dc susceptibility χ(T) in the normal state shows that the paramagnetic component of magnetization comes from the Pr3+ magnetic moments. The intragrain critical current density (JL) derived from the magnetization data is large. The JL(H) curve displays a second peak which shifts towards the high-field region with decreasing temperature. In the low-field region, a plateau up to a field H* followed by a power law H?5/8 behavior of JL(H) is the characteristic of the strong pinning. A vortex phase diagram for the present superconductor has been obtained from the magnetization and resistivity data. 相似文献
93.
Dinda E Rashid MH Biswas M Mandal TK 《Langmuir : the ACS journal of surfaces and colloids》2010,26(22):17568-17580
We describe a general one-step facile method for depositing gold nanoparticle (GNP) thin films onto any type of substrates by the in situ reduction of AuCl(3) using a newly designed redox-active ionic liquid (IL), tetrabutylphosphonium citrate ([TBP][Ci]). Various substrates such as positively charged glass, negatively charged glass/quartz, neutral hydrophobic glass, polypropylene, polystyrene, plain paper, and cellophane paper are successfully coated with a thin film of GNPs. This IL ([TBP][Ci]) is prepared by the simple neutralization of tetrabutylphosphonium hydroxide with citric acid. We also demonstrate that the [TBP][Ci] ionic liquid can be successfully used to generate GNPs in an aqueous colloidal suspension in situ. The deposited GNP thin films on various surfaces are made up of mostly discrete spherical GNPs that are well distributed throughout the film, as confirmed by field-emission scanning electron microscopy. However, it seems that some GNPs are arranged to form arrays depending on the nature of surface. We also characterize these GNP thin films via UV-vis spectroscopy and X-ray diffractometry. The as-formed GNP thin films show excellent stability toward solvent washing. We demonstrate that the thin film of GNPs on a glass/quartz surface can be successfully used as a refractive index (RI) sensor for different polar and nonpolar organic solvents. The as-formed GNP thin films on different surfaces show excellent catalytic activity in the borohydride reduction of p-nitrophenol. 相似文献
94.
The N-heterocyclic carbene, imidazole-2-ylidene, and its main group (13-15) analogues contain cyclically conjugated 6π electrons. Experimental 1H nuclear magnetic resonance (NMR) spectra suggest an increase in aromaticity along a period from left to right. Whereas the order along a group is as follows: period 2 > period 5 > period 4 > period 3 due to change in structure. To understand the order of aromaticity, the magnetically induced ring currents of the molecules are calculated using aromatic ring current shielding, gauge-including magnetically induced currents (GIMIC) method and Stanger's σ-model applying the gauge-including atomic orbitals NMR technique. It is found that GIMIC best describes the order of aromaticity especially along a group where current-profile changes on the bivalent atom down a group due to change in electron density. Moreover, the GIMIC provides the visualization of current by sign modulus and the anisotropy of the induced current density plots. 相似文献
95.
Ojah Namita Thakur Susmita Gogoi Dolly Ahmed Gazi Ameen Mandal Manabendra Doley Robin Choudhury Arup Jyoti 《Plasma Chemistry and Plasma Processing》2022,42(1):147-162
Plasma Chemistry and Plasma Processing - This work reports an investigation of the discharge characteristics of atmospheric dielectric barrier discharge (DBD) plasma in terms of I-V curves and... 相似文献
96.
Carboxylated peptide‐functionalized gold nanoparticles (peptide‐GNPs) self‐assemble into two‐ and three‐dimensional nanostructures in the presence of various heavy metal ions (i.e. Pb2+, Cd2+, Cu2+, and Zn2+) in aqueous solution. The assembly process is monitored by following the changes in the surface plasmon resonance (SPR) band of gold nanoparticles in a UV/Vis spectrophotometer, which shows the development of a new SPR band in the higher‐wavelength region. The extent of assembly is dependent on the amount of metal ions present in the medium and also the time of assembly. TEM analysis clearly shows formation of two‐ and three‐dimensional nanostructures. The assembly process is completely reversible by addition of alkaline ethylenediaminetetraacetic acid (EDTA) solution. The driving force for the assembly of peptide‐GNPs is mainly metal ion/carboxylate coordination. The color and spectral changes due to this assembly can be used for detection of these heavy‐metal ions in solution. 相似文献
97.
An order-level inventory model is developed for deteriorating items with uniform rate of production and stock-dependent demand. Shortages are allowed, and excess demand is backlogged. Results are illustrated with numerical examples.
相似文献98.
99.
We report new ab initio results for the interaction-induced dipole moments Δμ of hydrogen molecules colliding with helium atoms. These results are needed in order to calculate collision-induced absorption spectra at high temperatures; applications include modeling the radiative profiles of very cool white dwarf stars, with temperatures from 3500 K to 9000 K. We have evaluated the dipoles based on finite-field calculations, with coupled cluster methods in MOLPRO 2006 and aug-cc-pV5Z (spdfg) basis sets for both the H and He centers. We have obtained values of Δμ for eight H(2) bond lengths ranging from 0.942 a.u. to 2.801 a.u., for 15 intermolecular separations R ranging from 2.0 a.u. to 10.0 a.u., and for 19 different relative orientations. In general, our values agree well with earlier ab initio results, for the geometrical configurations that are treated in common, but we have determined more points on the collision-induced dipole surface by an order of magnitude. These results make it possible to calculate transition probabilities for molecules in excited vibrational states, overtones, and rotational transitions with ΔJ > 4. We have cast our results in the symmetry-adapted form needed for absorption line shape calculations, by expressing Δμ as a series in the spherical harmonics of the orientation angles of the intermolecular vector and of a unit vector along the H(2) bond axis. The expansion coefficients depend on the H(2) bond length and the intermolecular distance R. For large separations R, we show that the ab initio values of the leading coefficients converge to the predictions from perturbation theory, including both classical multipole polarization and dispersion effects. 相似文献
100.
Márton Zwillinger Dr. Post Sai Reddy Dr. Barbara Wicher Dr. Pradeep K. Mandal Dr. Márton Csékei Dr. Lucile Fischer Dr. András Kotschy Prof. Dr. Ivan Huc 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(72):17366-17370
Helically folded aromatic oligoamide foldamers have a size and geometrical parameters very distinct from those of α-helices and are not obvious candidates for α-helix mimicry. Nevertheless, they offer multiple sites for attaching side chains. It was found that some arrays of side chains at the surface of an aromatic helix make it possible to mimic extended α-helical surfaces. Synthetic methods were developed to produce quinoline monomers suitably functionalized for solid phase synthesis. A dodecamer was prepared. Its crystal structure validated the initial design and showed helix bundling involving the α-helix-like interface. These results open up new uses of aromatic helices to recognize protein surfaces and to program helix bundling in water. 相似文献