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81.
R.?K.?Roy S.?K.?Mandal D.?Bhattacharyya A.?K.?PalEmail author 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,34(1):25-31
Dielectric properties of silver/SiO2 nanocomposite thin films grown by high-pressure d.c. sputtering technique were studied by spectroscopic ellipsometry (300-800 nm). The dielectric behavior of the nanocomposite thin films largely depended on the particle size, its number density and the surrounding environments. The films showed semiconductor-like behavior up to a critical particle size and concentration, beyond which the films exhibited the typical surface plasmon resonance characteristics in their optical properties. The refractive index was also found to have a strong dependence on the particle size and its dispersion in the matrix. The results were found to be consistent with those obtained from UV-VIS optical absorbance data. Bruggeman effective medium theory was used to explain the experimental results.Received: 3 April 2002, Published online: 23 July 2003PACS:
78.67.-n Optical properties of nanoscale materials and structures
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78.67.Bf Nanocrystals and nanoparticles 相似文献
82.
John Kallikat Augustine Rajesha KumarAgnes Bombrun Ashis Baran Mandal 《Tetrahedron letters》2011,52(10):1074-1077
An efficient method for the Beckmann rearrangement of ketoximes to amides mediated by a catalytic amount (15 mol %) of propylphosphonic anhydride (T3P®) is described. Aldoximes underwent second order Beckmann rearrangement to provide the corresponding nitriles in excellent yields on reacting with T3P (15 mol %) at room temperature. The main advantages of this environmentally friendly protocol include procedural simplicity, and particularly ease of isolation of the products. 相似文献
83.
84.
Samit Mandal J Gerl H Geissel K Hauschild M Hellström Z Janas I Kojouharov Y Kopatch RC Lemmon P Mayet Z Podolyak PH Regan H Schaffner C Schlegel J Simpson HJ Wollersheim 《Pramana》2001,57(1):161-164
Feasibility of gamma-ray spectroscopy at relativistic energies with exotic heavy-ions and new generation of germanium detectors
(segmented Clover) is discussed. An experiment with such detector array and radioactive is discussed. 相似文献
85.
Swapan K. Bose † Krishnagopal Mandal Bireswar Chakrabarti 《Photochemistry and photobiology》1986,43(5):525-528
Abstract— Photolysis of α-crystallin in the presence of riboflavin under both aerobic and anaerobic conditions causes a rapid decrease in Trp emission; photooxidation most likely occurs via non-covalent complex formation between the sensitizer molecule and the substrate. However, the change in the tertiary structure of the protein, as manifested in the near-UV CD, is very different between aerobic and anaerobic photolysis. Riboflavin-sensitized reaction under aerobic condition causes a major change in the microenvironments of thiol groups as well as in the near-UV CD, whereas under anaerobic condition the change in the near-UV CD is much less and SH-group environments remain unaltered. The sensitizer in this photoinduced change in conformation of the protein is very selective and specific. 相似文献
86.
Sarifuddin Santabrata Chakravarty Prashanta Kumar Mandal Helge I. Andersson 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2009,56(Z2):299-323
The present investigation deals with a mathematical model representing the mass transfer to blood streaming through the arteries
under stenotic condition. The mass transport refers to the movement of atherogenic molecules, that is, blood-borne components,
such as oxygen and low-density lipoproteins from flowing blood into the arterial walls or vice versa. The blood flowing through
the artery is treated to be Newtonian and the arterial wall is considered to be rigid having differently shaped stenoses in
its lumen arising from various types of abnormal growth or plaque formation. The nonlinear unsteady pulsatile flow phenomenon
unaffected by concentration-field of the macromolecules is governed by the Navier–Stokes equations together with the equation
of continuity while that of mass transfer is controlled by the convection-diffusion equation. The governing equations of motion
accompanied by appropriate choice of the boundary conditions are solved numerically by MAC(Marker and Cell) method and checked
numerical stability with desired degree of accuracy. The quantitative analysis carried out finally includes the respective
profiles of the flow-field and concentration along with their distributions over the entire arterial segment as well. The
key factors like the wall shear stress and Sherwood number are also examined for further qualitative insight into the flow
and mass transport phenomena through arterial stenosis. The present results show quite consistency with several existing results
in the literature which substantiate sufficiently to validate the applicability of the model under consideration. 相似文献
87.
Gautam Mandal 《Physics letters. [Part B]》1989,220(4):533-538
We consider the implications of the existence of continuous families of classically degenerate vacua in constructing quantum string theory in compact toroidal spacetimes. We show that in the presence of unbroken supersymmetry when quantum corrections do not lift the degeneracy, symmetries of particular compactifications can be broken by the presence of the neighbouring vacua. We explicitly demonstrate this in case of the heterotic string where the gauge group SO(32) or E8×E8 breaks down to U(1)16 due to neighbouring configurations of arbitrary Wilson lines. 相似文献
88.
Santanu Mandal Ashok Kumar Rout Anupam Ghosh Guillaume Pilet Debasis Bandyopadhyay 《Polyhedron》2009,28(17):3858-3862
Two new mononuclear complexes of manganese(III) viz. [MnL2(LH)2]ClO4 (1) and [MnL2(N3)]·0.5CH3OH (2) have been synthesized by reacting manganese perchlorate with furfurylamine and salicylaldehyde (plus sodium azide in 2) where L = (2-hydroxybenzyl-2-furylmethyl)imine, an asymmetric bidentate Schiff base formed in situ to bind the Mn(III) ion. The complexes have been characterized by elemental analysis, IR spectroscopy, TGA and single crystal X-ray diffraction studies. Structural studies reveal that the complexes 1 and 2 adopt an octahedral and a square pyramidal geometry, respectively. The antibacterial activity of the complexes has been tested against Gram(+) and Gram(?) bacteria. 相似文献
89.
Dinda E Rashid MH Biswas M Mandal TK 《Langmuir : the ACS journal of surfaces and colloids》2010,26(22):17568-17580
We describe a general one-step facile method for depositing gold nanoparticle (GNP) thin films onto any type of substrates by the in situ reduction of AuCl(3) using a newly designed redox-active ionic liquid (IL), tetrabutylphosphonium citrate ([TBP][Ci]). Various substrates such as positively charged glass, negatively charged glass/quartz, neutral hydrophobic glass, polypropylene, polystyrene, plain paper, and cellophane paper are successfully coated with a thin film of GNPs. This IL ([TBP][Ci]) is prepared by the simple neutralization of tetrabutylphosphonium hydroxide with citric acid. We also demonstrate that the [TBP][Ci] ionic liquid can be successfully used to generate GNPs in an aqueous colloidal suspension in situ. The deposited GNP thin films on various surfaces are made up of mostly discrete spherical GNPs that are well distributed throughout the film, as confirmed by field-emission scanning electron microscopy. However, it seems that some GNPs are arranged to form arrays depending on the nature of surface. We also characterize these GNP thin films via UV-vis spectroscopy and X-ray diffractometry. The as-formed GNP thin films show excellent stability toward solvent washing. We demonstrate that the thin film of GNPs on a glass/quartz surface can be successfully used as a refractive index (RI) sensor for different polar and nonpolar organic solvents. The as-formed GNP thin films on different surfaces show excellent catalytic activity in the borohydride reduction of p-nitrophenol. 相似文献
90.
Kinsuk Das Tarak Nath Mandal Somnath Roy Samik Gupta Anil Kumar Barik Partha Mitra Arnold L. Rheingold Susanta Kumar Kar 《Polyhedron》2010
The varying coordination modes of the title ligand, L [5-methyl-1-(pyridin-2-yl)-N′-[pyridin-2-ylmethylidene]pyrazole-3-carbohydrazide] towards the different metal centers is reported by preparation and characterization of Cu(II), Zn(II) and Cd(II) complexes, [Cu(L)NO3.H2O](NO3) (1) [Zn(L)2](ClO4)2·2DMF (2) and [Cd(L)(I)2] (3) respectively. In 1, the neutral ligand serves as tetradentate 4 N donor where both pyridine and pyrazole nitrogen atoms of pyridyl–pyrazole part are coordinatively active, leaving the carbonyl oxygen of the carbohydrazide part inactive. The same pyridine and pyrazole N atoms remain abstained from the coordination process towards the Zn(II) and Cd(II) metal centers. For 2 and 3 the ligand behaves as a tridentate NNO donor where the two nitrogen atoms come from azomethine, pyridine of pyridine-2-carbaldehyde parts and O from carbonyl oxygen atoms (carbohydrazide part). The complex 1 and 2 are distorted octahedral while complex 3 adopts distorted square pyramidal geometry. All the complexes are X-ray crystallographically characterized. 相似文献