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961.
Measurements of stable carbon isotopic composition (delta13C) of carbonates or carbonate-rich soils are seldom performed in a continuous-flow isotope ratio mass spectrometer (IRMS) using an elemental analyzer (EA) as an online sample preparation device. Such analyses are routinely carried out with an external precision better than 0.1 per thousand using a GasBench II (GB) sample preparation device coupled online with a continuous-flow IRMS. In this paper, we report and compare delta13C analyses (86 total analyses) of calcium carbonates obtained by using both the GB and the EA. Using both techniques, the delta13C compositions of two in-house carbonate standards (MERCK carbonate and NR calcite) and ten selected carbonate-rich paleosol samples (of variable CaCO3 content) were analyzed, and data are reported in the VPDB scale calibrated against international standards, NBS 18 and 19. For the in-house standards analyzed by both techniques, a precision better than 0.08 per thousand is achieved. The analytical errors (1sigma) computed from multiple analyses of the delta13C of both the MERCK and NR obtained by the above two techniques are nearly identical. In general, the 1sigma (internal error) of paleosol analyses obtained in the GB is better than 0.06 per thousand, whereas that for the analyses in the EA (three repetitive analyses of the same sample) varies in the range 0.05-0.21 per thousand. However, for paleosols having more than 85% CaCO3, 1sigma is better than 0.15 per thousand (similar to the instrument precision), and in this case the delta13C(VPDB) of samples obtained by the GB is similar to that obtained by the EA. Our results suggest that the delta13C of pure calcium carbonate samples can also be analyzed using the EA technique. 相似文献
962.
Carolina Toloza Porras Dagmar R. D'hooge Paul H. M. Van Steenberge Marie‐Françoise Reyniers Guy B. Marin 《大分子反应工程》2013,7(7):311-326
Kinetic Monte Carlo simulations are performed to investigate the capability of ICAR ATRP for the synthesis of well‐defined poly(isobornyl acrylate‐b‐styrene) block(‐like) copolymers using one‐pot semi‐batch and two‐pot batch procedures. The block copolymer quality is quantified via a block deviation (〈BD〉) value. For 〈BD〉 values lower than 0.30, the quality is defined as good and for well‐chosen polymerization conditions the formation of homopolymer chains upon addition of the second monomer can be suppressed. A better block quality is obtained when isobornyl acrylate is polymerized first. For lower Cu levels a one‐pot semi‐batch procedure allows a much faster ATRP and better control over the polymer properties than a two‐pot batch procedure.
963.
Proteomic analysis of the Arabidopsis thaliana cell wall 总被引:1,自引:0,他引:1
Chivasa S Ndimba BK Simon WJ Robertson D Yu XL Knox JP Bolwell P Slabas AR 《Electrophoresis》2002,23(11):1754-1765
With the completion of the Arabidopsis genome, many hypothetical proteins have been predicted without any information on their expression, subcellular localisation and function. We have performed proteomic analysis of proteins sequentially extracted from enriched Arabidopsis cell wall fractions and separated by two-dimensional gel electrophoresis (2-DE). The proteins were identified by peptide mass fingerprinting using matrix-assisted laser desorption/ionisation-time of flight (MALDI-TOF) mass spectrometry and genomic database searches. This is part of a targeted exercise to establish the entire Arabidopsis secretome database. We report evidence for new proteins of unknown function whose existence had been predicted from genomic sequences and, furthermore, localise them to the cell wall. In addition, we observed an unexpected presence in the cell wall preparations of proteins whose known biochemical activity has never been associated with this compartment hitherto. We discuss the implications of these findings and present results suggesting a possible involvement of cell wall kinases in plant responses to pathogen attack. 相似文献
964.
965.
966.
Reductions in leaf growth are a commonly observed response to ultraviolet radiation, but the underlying mechanisms remain poorly defined. This study examined the response of leaves exposed to a UV environment across a range of organizational scales, including leaf expansion rate, epidermal cell size and number, biomechanical properties, leaf–water relations and activity of cell-wall peroxidases. Two experimental approaches were used; Lettuce ( Lactuca sativa L.) plants were propagated under (a) supplementary UV-B (9 kJ m−2 day−1 ) in controlled environment (CE) conditions, and (b) field conditions, where plants were placed under three horticultural films with differing UV transmissions. In both experiments, UV-B caused the greatest reductions in leaf expansion and final leaf size, with some reductions attributable to UV-A wavelengths. In supplementary UV-B conditions, adaxial cell size was reduced, while in field plants, both cell size and cell number were lower in an increased UV environment, as was the case with abaxial cells in CE plants. Although leaf turgor and leaf extensibility were not affected by UV wavelengths, breaking strain of leaf tissue was decreased under supplementary UV-B. Cell-wall peroxidase activity was increased in both supplementary UV conditions and in the field, where only a zero UV environment showed no upregulation of cell-wall peroxidase. 相似文献
967.
Methodologies for the quantification of measurement uncertainties associated with the determination of 210Pb- and 210Po-specific activities by liquid scintillation counting (LSC) and alpha-particle spectrometry are presented, and are demonstrated
using the soil reference material IAEA-326. Major contributors to the combined uncertainty associated with the measurement
result of 210Pb were the uncertainties of net count rates in the 210Pb energy region of the sample spectrum and in the 210Bi energy region of the blank spectrum. The predominant sources of uncertainty in the measurement of 210Po were the uncertainties of net count rates in the regions of interest of 209Po and 210Po. The relative standard uncertainty of 210Po exponentially increases with the time interval between the sampling date and the separation date of Po, and this effect
is strongly dependent on the 210Po/210Pb activity ratio. When the specific activity of 210Pb is much higher than that of 210Po in the sample, the relative standard uncertainty of the 210Po determination increases significantly within a short time interval between the sampling date (or reference date) and the
separation date of Po in samples. 相似文献
968.
Nonlinear Dynamics - Control of spatially extended systems is an important and challenging topic of research. Previous control techniques rely on local or global feedback control. In this paper,... 相似文献
969.
John B. Cunniff Paul Vouros 《Journal of the American Society for Mass Spectrometry》1995,6(12):1175-1182
A method has been developed that takes advantage of the formation of noncovalent compounds in electrospray mass spectrometry. Mixtures of proteins and peptides are shown to produce an intense ion that corresponds to a 1:1 complex with a crown ether (18-crown-6). Although the crown ether may be added directly to the solution, for the current experiments it is introduced via the methanol liquid sheath. The spacing of these complexed species in the mass spectrum allows unambiguous determination of the charge state of the ions and their actual mass. Through constant neutral loss scans, charge state may be determined, mass assigned, spectra simplified, and chemical noise may be reduced for the analysis of complex peptide samples without chromatographic separation. Finally, the prevalence of single complexation permits mass assignments based on the mass difference of a single protein ion and its complexed form at any charge state. In essence, the method performs a separation based on charge state. It can be used to complement chromatographic separation and deconvolution algorithms for the electrospray mass spectrometry analysis of peptide-protein mixtures. 相似文献
970.
Paul J. Galley Gary M. Hieftje 《Spectrochimica Acta Part B: Atomic Spectroscopy》1993,48(14):E1725-E1742
This article is an electronic publication in Spectrochimica Acta Electronica (SAE), the electronic section of Spectrochimica Acta Part B (SAB). The hardcopy text is accompanied by three disks with data files with the hardcopy paper in Word 5.0 and ASCII format, and a disclaimer. The text details the purpose of the work and the structure of the three-dimensional Ar ionization temperature and electron number density data files. The line-to-continuum method was used to evaluate the spatial distribution of Ar ionization temperatures, Tion, and electron number densities, ne, within a dry Ar inductively coupled plasma (ICP). The emission measurements were spatially resolved in three dimensions by reconstruction algorithms for computed tomography. The 40.68 MHz Ar ICP was operated at applied r.f. power levels of 0.75 and 1.0 kW. The reconstructed distributions of Ar I line emission (430.0 nm) and continuum emission (428.6 nm) show good reproducibility over a series of five replicate runs. Argon ionization temperatures remain within a 6500–8500 K range throughout the continuum-emission cone of the plasma. Deviations from this temperature range occur in the central channel and around the outer edge of the plasma. Low in the plasma, the central-channel Tion is cooler than 6000 K. Along the outer edge of the plasma, the line-to-continuum ratio becomes small; this low ratio results in erroneously high temperatures (> 12000 K). The errors in Tion appear to be due to reproducible artifacts in the reconstruction process that lead to low Ar I line-emission readings along the outer edge of the plasma. Electron densities show a maximum of 8.5 × 1014 cm−3 and 1.2 × 1015 cm−3 at 0.75 and 1.0 kW, respectively. Electron number densities were much better behaved than Tion due to their dependence on the square-root of continuum measurements and only the fourth-root of Tion. 相似文献