全文获取类型
收费全文 | 222篇 |
免费 | 8篇 |
专业分类
化学 | 176篇 |
晶体学 | 1篇 |
力学 | 8篇 |
数学 | 22篇 |
物理学 | 23篇 |
出版年
2023年 | 2篇 |
2022年 | 7篇 |
2021年 | 14篇 |
2020年 | 10篇 |
2019年 | 11篇 |
2018年 | 7篇 |
2016年 | 12篇 |
2015年 | 3篇 |
2014年 | 8篇 |
2013年 | 16篇 |
2012年 | 18篇 |
2011年 | 18篇 |
2010年 | 12篇 |
2009年 | 8篇 |
2008年 | 11篇 |
2007年 | 17篇 |
2006年 | 14篇 |
2005年 | 7篇 |
2004年 | 10篇 |
2003年 | 6篇 |
2002年 | 1篇 |
2001年 | 3篇 |
2000年 | 5篇 |
1999年 | 1篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1991年 | 2篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有230条查询结果,搜索用时 15 毫秒
41.
Pamela de Oliveira Rossini Fabiana S. Felix Lúcio Angnes 《Central European Journal of Chemistry》2012,10(6):1842-1849
Losartan is an antihypertensive agent that lost its patent protection in 2010, and, consequently, it has been available in generic form. The latter motivated the search for a rapid and precise alternative method. Here, a simple conductometric titration in aqueous medium is described for the losartan analysis in pharmaceutical formulations. The first step of the titration occurs with the protonation of losartan producing a white precipitate and resulting in a slow increase in conductivity. When the protonation stage is complete, a sharp increase in conductivity occurs which was determined to be due to the presence of excess of acid. The titrimetric method was applied to the determination of losartan in pharmaceutical products and the results are comparable with values obtained using a chromatographic method recommended by the United States Pharmacopoeia. The relative standard deviation for successive measurements of a 125 mg L?1 (2.71×10?4 mol L?1) losartan solution was approximately 2%. Recovery study in tablet samples ranged between 99 and 102.4%. The procedure is fast, simple, and represents an attractive alternative for losartan quantification in routine analysis. In addition, it avoids organic solvents, minimizes the risk of exposure to the operator, and the waste treatment is easier compared to classical chromatographic methods. 相似文献
42.
Ali Ghasemi Andrea Paesano Jr. Carla Fabiana Cerqueira Machado 《Journal of magnetism and magnetic materials》2012
Co1−xNix/2Srx/2Fe2O4 (x=0–0.5 in steps of 0.1) ferrite nanoparticles have been synthesized at room temperature, without calcination, using a reverse micelle process. The site preference was determined by Mössbauer spectroscopy at 300 K. The hyperfine parameters were obtained, for the whole series of solid solutions. For the X≤0.20 samples, the spectra were fitted with two discrete sextets and for the X>0.20 samples, a magnetic hyperfine field distribution and a doublet were also imposed in the fit procedure. Hysteresis loops were measured using a superconducting quantum interference device magnetometer at 2 K and 300 K. The results indicate that the relative decrease in saturation magnetization of nanoparticles compared to the submicron particles could be attributed to a surface spin termination and disorder. Magnetic dynamics of the nanoparticles was studied by the measurement of ac magnetic susceptibility versus temperature at different frequencies and it is found that the results are well described by the Vogel–Fulcher model. 相似文献
43.
Valentina Noemi Madia Walter Toscanelli Daniela De Vita Marta De Angelis Antonella Messore Davide Ialongo Luigi Scipione Valeria Tudino Felicia Diodata DAuria Roberto Di Santo Stefania Garzoli Annarita Stringaro Marisa Colone Magda Marchetti Fabiana Superti Lucia Nencioni Roberta Costi 《Molecules (Basel, Switzerland)》2022,27(12)
Influenza viruses are transmitted from human to human via airborne droplets and can be transferred through contaminated environmental surfaces. Some works have demonstrated the efficacy of essential oils (EOs) as antimicrobial and antiviral agents, but most of them examined the liquid phases, which are generally toxic for oral applications. In our study, we describe the antiviral activity of Citrus bergamia, Melaleuca alternifolia, Illicium verum and Eucalyptus globulus vapor EOs against influenza virus type A. In the vapor phase, C. bergamia and M. alternifolia strongly reduced viral cytopathic effect without exerting any cytotoxicity. The E. globulus vapor EO reduced viral infection by 78% with no cytotoxicity, while I. verum was not effective. Furthermore, we characterized the EOs and their vapor phase by the head-space gas chromatography–mass spectrometry technique, observing that the major component found in each liquid EO is the same one of the corresponding vapor phases, with the exception of M. alternifolia. To deepen the mechanism of action, the morphological integrity of virus particles was checked by negative staining transmission electron microscopy, showing that they interfere with the lipid bilayer of the viral envelope, leading to the decomposition of membranes. We speculated that the most abundant components of the vapor EOs might directly interfere with influenza virus envelope structures or mask viral structures important for early steps of viral infection. 相似文献
44.
Alessandra Borrelli Maria Cristina Patria 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1984,35(3):373-386
Summary In this paper we study the propagation of discontinuity waves of any order through an elastic solid saturated with an inviscid fluid by using the linear theory derived in [1] by G. Szefer. By means of the singular surfaces theory we obtain the possible normal speeds of propagation of the wave front and the evolution law along the normal trajectories for transverse and longitudinal propagation.
This work was supported by the G. N. F. M. of C. N. R. 相似文献
Riassunto In questo lavoro studiamo la propagazione di onde di discontinuità di ogni ordine in un mezzo elastico poroso saturato da un fluido non viscoso nell'ambito della teoria lineare formulata da G. Szefer in [1]. Usando il metodo delle superfici singolari otteniamo le possibili velocità normali di avanzamento del fronte d'onda e la legge di evoluzione delle discontinuità lungo le corrispondenti traiettorie normali sia per propagazione trasversale, sia per propagazione longitudinale.
This work was supported by the G. N. F. M. of C. N. R. 相似文献
45.
A. Borrelli M. C. Patria 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1996,47(6):880-893
The aim of this paper is to investigate the behaviour of the total energy of a magnetoelastic conductor occupying a semi-infinite prismatic cylinder in dynamical conditions. Precisely, we deduce some estimates for the energyW(x
3,t) of the portion of the medium at distance greater thanx
3 from the base in terms of the data. First of all, we prove that the total energyW(0,t) is finite for allt > 0 providedW(0, 0) is finite. Then, using the first Korn inequality, we obtain that the estimate forW(x
3,t) depends only on the initial data ift<x
3/V (V=computable positive material constant); ift>x
3/V then the bound forW(x
3,t) depends on all the data of the problem. 相似文献
46.
Francesco Barbato Maria Immacolata La Rotonda Agnese Miro Patrizia Morrica Fabiana Quaglia 《Journal of inclusion phenomena and macrocyclic chemistry》2000,38(1-4):423-433
This study was carried out with the aim ofinvestigating the interactions between-cyclodextrin and carbaryl, a carbamatepesticide, and their effect on some physico-chemicalproperties of carbaryl, such as aqueous solubility andlipophilicity. The interactions between carbaryl and-cyclodextrin were thoroughly investigated bothin solution and in the solid state. The effect of-cyclodextrin on the aqueous solubility ofcarbaryl was evaluated by the phase solubility method.The amount of carbaryl dissolved increased linearlywith the addition of -cyclodextrin according toan AL type plot and without precipitation of thecomplex. The apparent stability constant of thecomplex was 289 ± 21 M-1, assuming a 1 : 1stoichiometry; this value was confirmed by a methodbased on circular dichroism measurements.Equimolar carbaryl/-cyclodextrin solid systemswere prepared by physical-mixing and freeze-drying,and fully characterised by Differential ScanningCalorimetry, X-ray powder diffractometry and FourierTransform Infra-Red analysis. The results of the solidstate study demonstrated that the freeze-drying methodyields a system with a high degree of amorphisationand yields an inclusion complex.The dissolution profile of the pesticide was affectedby the physico-chemical properties of each solidsystem, the freeze-dried form dissolving more rapidly. However, the physical association of-cyclodextrin and carbaryl enhanced the aqueoussolubility of the insecticide as well. 相似文献
47.
Alessandra Borrelli Maria Cristina Patria 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1987,38(1):65-78
Summary In the present paper we study the propagation into a constant state of the induced discontinuities associated with a first order discontinuity wave for a quasi-linear hyperbolic system. Making use of the theory of singular surfaces and the ray-theory, we derive and solve completely the equations which the induced discontinuity vector
must obey along the rays associated with the wave front. So we determine the evolution law of
and find that it depends non-linearly on the first order discontinuities and on the geometrical features of the wave front; thus the behaviour of the induced discontinuities is known once the evolution law of the first order discontinuity wave is obtained explicitly.
Work performed under the auspices of C.N.R. (G.N.F.M.) and supported by M.P.I. of Italy. 相似文献
Riassunto In questa nota studiamo la propagazione, in uno stato costante, delle discontinuità indotte associate a un'onda di discontinuità del primo ordine per un sistema iperbolico quasi-lineare. Adottando un'opportuna combinazione della teoria delle superfici singolari e delle teoria dei raggi, determiniamo in maniera completa il comportamento del vettore delle discontinuità indotte lungo i raggi associati al fronte d'onda. Troviamo che la legge di evoluzione di dipende non linearmente dalle discontinuità del primo ordine e dalle caratteristiche geometriche del fronte d'onda. L'andamento di è perciò noto una volta nota esplicitamente la legge di evoluzione delle discontinuità del primo ordine.
Work performed under the auspices of C.N.R. (G.N.F.M.) and supported by M.P.I. of Italy. 相似文献
48.
Nadia Manzo Fabiana Pizzolongo Alessandra Aiello Raffaele Romano 《Natural product research》2019,33(13):1835-1841
Heat treatments can cause degradation in tomatoes of lycopene which has important antioxidant effects. No information about decimal reduction time (D100) of lycopene is available. D-value is the time required at a given temperature to reduce 90% of the molecule. This study for the first time determine the kinetic of lycopene thermal degradation. The content was measured at regular intervals of pasteurization using canned tomato paste to determinate D value. Microbiological analysis was carried out to verify product stability after packaging. Yeasts, molds and lactic acid bacteria were determined. The pasteurization time allowed to observe a loss of the red color. Lycopene content, after an increase at 8 min, decreased at 32 min of pasteurization. D100 value was calculated at 75 min; a diminution of 90% in lycopene content in the concentrated tomato paste was observed. Microbiological analysis confirmed the stability of products after 8 min of pasteurization. 相似文献
49.
Dr. Fabiana E. García Prof. Marta I. Litter Prof. Isabella Natali Sora 《ChemistryOpen》2021,10(8):790-797
The catalytic performance of a perovskite-type lanthanum ferrite LaFeO3 to remove arsenic from water has been investigates for the first time. LaFeO3 was prepared by citrate auto-combustion of dry gel obtained from a solution of the corresponding nitrates poured into citric acid solution. Kinetic studies were performed in the dark with As(V) and in the dark and under UV-C irradiation at pH 6–7 with As(III) (both 1 mg L−1), and As : Fe molar ratios (MR) of 1 : 10 and 1 : 100 using the LaFeO3 catalyst. As(V) was removed from solution after 60 min in the dark in 7 % and in 47 % for MR=1 : 10 and MR=1 : 100, respectively, indicating the importance of the amount of the iron material on the removal. Oxidation of As(III) in the dark was negligible after 60 min in contact with the solid sample, but complete removal of As(III) was observed within 60 min of irradiation at 254 nm, due to As(III) photooxidation to As(V) and to As(III) sorption to a minor extent. Morphological and microstructural studies of the catalyst complement the catalytic testing. This work demonstrates that LaFeO3 can be used for the removal of As(III) from highly arsenic contaminated water. 相似文献
50.
Zino Boisdenghien Stijn Fias Fabiana Da Pieve Frank De Proft Paul Geerlings 《Molecular physics》2015,113(13-14):1890-1898
We investigate the local polarisability or polarisability density using both a conceptual density functional theory approach based on the linear response function and time-dependent density functional theory. Using a zero frequency in the latter, we can immediately compare both approaches. Using an analytical expression for the linear response kernel, we are able to systematically analyse α(r) throughout the periodic table. An extension to molecules is also made with a study of the CO molecule retrieving the connection between local softness and local polarisability. 相似文献