全文获取类型
收费全文 | 506篇 |
免费 | 21篇 |
专业分类
化学 | 372篇 |
力学 | 1篇 |
数学 | 28篇 |
物理学 | 126篇 |
出版年
2023年 | 10篇 |
2022年 | 19篇 |
2021年 | 20篇 |
2020年 | 17篇 |
2019年 | 13篇 |
2018年 | 13篇 |
2017年 | 7篇 |
2016年 | 20篇 |
2015年 | 13篇 |
2014年 | 17篇 |
2013年 | 47篇 |
2012年 | 33篇 |
2011年 | 29篇 |
2010年 | 22篇 |
2009年 | 17篇 |
2008年 | 32篇 |
2007年 | 22篇 |
2006年 | 24篇 |
2005年 | 23篇 |
2004年 | 26篇 |
2003年 | 17篇 |
2002年 | 20篇 |
2001年 | 11篇 |
2000年 | 5篇 |
1999年 | 9篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1992年 | 1篇 |
1991年 | 4篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1982年 | 1篇 |
1981年 | 8篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有527条查询结果,搜索用时 15 毫秒
61.
Well-defined nanoparticles composed of a tetraphenylmethane-based microporous polymer network with an average particle diameter of 30-60 nm were fabricated by a miniemulsion polymerization technique. Strong green emission was observed and efficient excitation energy transfer from nanoparticles to surface-bound dye molecules was explored. 相似文献
62.
Patra D Barakat C 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,79(5):1823-1828
Hydrophilic ionic liquid, 1-butyl-3-methylimidazolium tetrafluoroburate, modified the properties of aqueous surfactant solutions associated with curcumin. Because of potential pharmaceutical applications as an antioxidant, anti-inflammatory and anti-carcinogenic agent, curcumin has received ample attention as potential drug. The interaction of curcumin with various charged aqueous surfactant solutions showed it exists in deprotonated enol form in surfactant solutions. The nitro and hydroxyl groups of o-nitrophenol interact with the carbonyl and hydroxyl groups of the enol form of curcumin by forming ground state complex through hydrogen bonds and offered interesting information about the nature of the interactions between the aqueous surfactant solutions and curcumin depending on charge of head group of the surfactant. IL[bmin][BF4] encouraged early formation of micelle in case of cationic and anionic aqueous surfactant solutions, but slightly prolonged micelle formation in the case of neutral aqueous surfactant solution. However, for curcumin IL [bmin][BF4] favored strong association (7-fold increase) with neutral surfactant solution, marginally supported association with anionic surfactant solution and discouraged (~2-fold decrease) association with cationic surfactant solution. 相似文献
63.
Study of magnetoresistance and conductance of bicrystal grain boundary in La0.67Ba0.33MnO3 thin film
La0.67Ba0.33MnO3 (LBMO) thin film is deposited on a 36.7°C SrTiO3 bicrystal substrate using laser ablation technique. A microbridge is created across bicrystal grain boundary and its characteristics
are compared with a microbridge on the LBMO film having no grain boundary. Presence of grain boundary exhibits substantial
magnetoresistance ratio (MRR) in the low field and low temperature region. Bicrystal grain boundary contribution in MRR disappears
at temperature T>175 K. At low temperature, I-V characteristic of the microbridge across bicrystal grain boundary is nonlinear. Analysis of temperature dependence of dynamic
conductance-voltage characteristics of the bicrystal grain boundary indicates that at low temperatures (T<175 K) carrier transport across the grain boundary in LBMO film is dominated by inelastic tunneling via pairs of manganese
atoms and tunneling through disordered oxides. At higher temperatures (T>175 K), magnetic scattering process is dominating. Decrease of bicrystal grain boundary contribution in magnetoresistance
with the increase in temperature is due to enhanced spin-flip scattering process. 相似文献
64.
Michael Patra Mikko Karttunen 《Numerical Methods for Partial Differential Equations》2006,22(4):936-953
We derive stencils, i.e., difference schemes, for differential operators for which the discretization error becomes isotropic in the lowest order. We treat the Laplacian, Bilaplacian (= biharmonic operator), and the gradient of the Laplacian both in two and three dimensions. For three dimensions ??(h2) results are given while for two dimensions both ??(h2) and ??(h4) results are presented. The results are also available in electronic form as a Mathematica file. It is shown that the extra computational cost of an isotropic stencil usually is less than 20%. © 2005 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2006 相似文献
65.
Dipak Ghosh Argha Deb Swarup Ranjan Sahoo Kanchan Kumar Patra Prabir Kumar Haldar Jayita Ghosh 《Czechoslovak Journal of Physics》2002,52(6):789-794
An analysis of data of target fragments of 28Si-AgBr (at 14.5 AGeV) reveals the existence of emission asymmetry in the azimuthal plane, which is found to depend on the number of target fragments. The comparison with the data of 32S-AgBr (at 200 AGeV) and 16O-AgBr (at 60 AGeV) interactions indicates that emission asymmetry depends on the projectile mass and energy. 相似文献
66.
Amarendra Patra Apurba K. Mukhopadhyay Alok K. Mitra 《Magnetic resonance in chemistry : MRC》1981,17(3):166-168
Carbon-13 signal assignments of taraxasteryl acetate, taraxasteryl palmitate, taraxasterol and epi-friedelinyl acetate are reported. Some signal assignments of the friedelanones, reported recently by others, are inconsistent and require revision. 相似文献
67.
68.
69.
A. Patra A. K. Mitra S. R. Mitra C. L. Kirtaniya N. Adityachaudhury 《Magnetic resonance in chemistry : MRC》1980,14(1):58-60
Carbon-13 NMR spectra of a number of (?)-ent-kauranoids have been studied. An unambiguous selfconsistent assignment of resonances has been made by considering the changes in chemical shifts produced by the change of substituent(s). 相似文献
70.
Amarendra Patra Alok K. Mitra Saroj Ghosh Amitava Ghosh A. K. Barua 《Magnetic resonance in chemistry : MRC》1981,15(4):399-400
Carbon-13 NMR signal assignment of a number of polyoxygenated triterpenes of the olean-12-ene and urs-12-ene series, carried out by considering the changes in chemical shift produced by the change of oxygenation pattern(s), and using methyl oleanolate as a model, are reported. 相似文献