全文获取类型
收费全文 | 507篇 |
免费 | 17篇 |
专业分类
化学 | 289篇 |
晶体学 | 3篇 |
力学 | 23篇 |
数学 | 119篇 |
物理学 | 90篇 |
出版年
2022年 | 8篇 |
2021年 | 18篇 |
2020年 | 3篇 |
2019年 | 9篇 |
2018年 | 5篇 |
2017年 | 3篇 |
2016年 | 15篇 |
2015年 | 10篇 |
2014年 | 17篇 |
2013年 | 40篇 |
2012年 | 31篇 |
2011年 | 35篇 |
2010年 | 17篇 |
2009年 | 29篇 |
2008年 | 27篇 |
2007年 | 25篇 |
2006年 | 17篇 |
2005年 | 20篇 |
2004年 | 24篇 |
2003年 | 13篇 |
2002年 | 9篇 |
2001年 | 5篇 |
2000年 | 3篇 |
1999年 | 10篇 |
1998年 | 5篇 |
1997年 | 4篇 |
1996年 | 6篇 |
1993年 | 2篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 5篇 |
1979年 | 5篇 |
1976年 | 4篇 |
1974年 | 4篇 |
1929年 | 2篇 |
1921年 | 4篇 |
1911年 | 3篇 |
1907年 | 2篇 |
1906年 | 3篇 |
1875年 | 2篇 |
排序方式: 共有524条查询结果,搜索用时 968 毫秒
51.
Pasquale Candito Giuseppina D'Aguì 《Journal of Mathematical Analysis and Applications》2011,375(2):594-601
Using critical point theory, we study the existence of at least three solutions for a perturbed nonlinear Dirichlet boundary value problem for difference equations depending on two positive parameters. 相似文献
52.
Di Maria F Olivelli P Gazzano M Zanelli A Biasiucci M Gigli G Gentili D D'Angelo P Cavallini M Barbarella G 《Journal of the American Chemical Society》2011,133(22):8654-8661
Functional supramolecular architectures for bottom-up organic nano- and microtechnology are a high priority research topic. We discovered a new recognition algorithm, resulting from the combination of thioalkyl substituents and head-to-head regiochemistry of substitution, to induce the spontaneous self-assembly of sulfur overrich octathiophenes into supramolecular crystalline fibers combining high charge mobility and intense fluorescence. The fibers were grown on various types of surfaces either as superhelices or straight rods depending on molecular structure. Helical fibers directly grown on a field effect transistor displayed efficient charge mobility and intrinsic 'memory effect'. Despite the fact that the oligomers did not have chirality centers, one type of hand-helicity was always predominant in helical fibers, due to the interplay of molecular atropisomerism and supramolecular helicity induced by terminal substituents. Finally, we found that the new sulfur overrich oligothiophenes can easily be prepared in high yields through ultrasound and microwave assistance in green conditions. 相似文献
53.
In this work, we consider a new combination of vibrational analysis and normal-like mode decomposition of Debye-Waller factors of solvated ions entirely based on molecular dynamics data. Such a novel time-dependent analysis procedure provides a direct link between x-ray absorption fine structure parameters and normal mode contributions for an ion-solvent system. The potentialities of such a methodology rely on two fundamental aspects which distinguish it from already available tools. First, a general vibrational analysis that does not require any Gaussian or harmonic model for describing atomic fluctuations in liquids. Second, a very accurate sampling of the short range motions around the structural probe via the recently developed atom centered density matrix propagation/general liquid optimized boundary method. This novel molecular dynamics methodology is based on an integrated ab initio/classical potential using localized basis functions and nonperiodic boundary conditions. As a case study we have chosen the Zn(II) ion in aqueous solution. The consistency of our results and the observed good agreement with experiments show how the key support to advanced structural techniques from molecular dynamics can be further expanded and investigated. 相似文献
54.
Cera G Crispino P Monari M Bandini M 《Chemical communications (Cambridge, England)》2011,47(27):7803-7805
A reliable synthetic route to fused polycyclic indolines is documented by the development of a stereoselective gold catalyzed cascade cyclization of indole propargylic alcohols. 相似文献
55.
Mesoporous carbon catalyst supports are attractive due to their wide chemical stability while potentially increasing mass-transport through and providing a path for larger molecules to access catalytic sites. Herein we report the synthesis of a phosphorylated mesoporous carbon solid-acid catalyst characterized by NH(3)-TPD and isopropanol dehydration. 相似文献
56.
Solid state 1H, 29Si and 31P MAS NMR have been used to investigate the microstructure of phosphosilicate gels prepared by a modified sol-gel method involving hydrolysis of silicon precursors in a solely aqueous environment at 50 °C. Gels with molar compositions 5, 10, 20 and 30 mol% P2O5 in P2O5-SiO2 were studied. After drying to 400 °C the gels have very similar structures formed by a siloxane framework containing silanol groups and trapped molecules of orthophosphoric acid together with a very small amount, of pyrophosphoric acid. Unlike the gel samples previously synthesized by the hydrolysis of the silicon precursor in alcoholic solution at room temperature, the co-polymerization of phosphorus and silicon is much reduced. Although co-polymerization increases with phosphorus content, it still represents less than 50% of the phosphorus in the 30 mol% P2O5 gel. Furthermore there is no evidence for six-coordinated silicon in the glassy matrix. 相似文献
57.
58.
59.
Jorge Horas Cristina Di Pasquale Ezio Marchi 《Journal of Mathematical Analysis and Applications》1982,89(1):107-128
The growth of microbial cultures is studied by means of stochastic processes. A compartment structure is used to take into account cell maturation stages, having an inflow of cells from one compartment to the next. Dilution and cell division are also considered. A differential equation, first proposed by Kiefer, is studied and the expected number of cells in each compartment is found for several interesting cases. 相似文献
60.
Ruggieri F Fanelli M Di Pasquale D Burri E Petitta M Mazzeo P 《Annali di chimica》2005,95(9-10):607-616
In the present work are reported the results of a monitoring on a vast scale, carried out through evaluation of opportune chemical parameters, of the pollution state of the agricultural-industrial settlement of the Fucino Plain. The parameters took into consideration have been the presence of wide consumption pesticides and of ionic species as Cl-, NO2-, NO3-, NH4+, the quantification of the dissolved oxygen, of the temperature, of the conductivity, of pH and eH. Collected data are used for chemometric elaboration. The water systems examined, by means of drawing campaigns carried out at regular intervals in winter, spring, summer, and autumnal seasons, are represented by superficial waters constituting a network of irrigation canals fed by stratum and meteoric waters. In this work are reported the results relative to the drawing campaigns. 相似文献