Kinetic equations for a density matrix describing nonlinear effects in spectral line wings

Kinetic quantum equations are derived for a density matrix with collision integrals describing nonlinear effects in spectra line wings. These equations take into account the earlier established inequality of the spectral densities of Einstein coefficients for absorption and stimulated radiation emission by a two-level quantum system in the far wing of a spectral line in the case of frequent collisions. The relationship of the absorption and stimulated emission probabilities with the characteristics of radiation and an elementary scattering event is found.     

Dynamic Deformations of the Crystal Lattice of Sphalerite in the Zn<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Co<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Se(<Emphasis Type="Italic">x</Emphasis>=0.01) Compound

Local distortions of the crystal lattice of the semiconductor compound Zn_{1 − x} Co _x Se (x = 0.01) have been investigated using thermal neutron diffraction. It has been found that the diffraction patterns of the crystal contain regions of diffuse scattering in the vicinity of strong Bragg peaks at 300 K. As the temperature decreases, the intensity of diffuse scattering effects substantially decreases. Arguments in favor of the assumption that the origin of the diffuse scattering is caused by the Jahn-Teller vibronic effect are presented.     

Study of the frequency distribution of secondary radiation resonances of small-sized pilotless vehicles

Computer simulation of a typical small-sized pilotless vehicle is carried out. Three-dimensional diagrams of the secondary radiation (scattering diagrams) of the vehicles are derived. Frequency dependences of the secondary radiation in the range 50 MHz–4 GHz are plotted. The possibilities of the object model simplification are discussed. The polarization features of object detection are studied. The possibility of object recognition against the bird’s background is evaluated.     

Extraction products from <Emphasis Type="Italic">Miscanthus</Emphasis> var. ‘Soranovskii’

The chemical structures of Miscanthus var. ‘Soranovskii’ lignin fractions released via extraction of lignin from the lignocellulosic feedstock using moderately heated acetone under atmospheric pressure, without acidic and alkaline catalysts, were studied. A blend of Miscanthus stems and leaves was pretreated with water under thermobaric conditions. The acetone organosolv process subsequently afforded a substance related to a lignin-like matter-acetone organosolv Miscanthus lignin (AOML). Non-destructive analytical techniques such as FTIR spectroscopy, gas chromatography-mass spectrometry, size-exclusion chromatography, and 2D NMR were used. The IR and NMR spectroscopies revealed the AOML structure to comprise all the three major types of phenylpropane units: guaiacyl (G), syringyl (S), and p-hydroxyphenyl (H). The resultant acetone-organosolv lignin exhibits good solubility in polar solvents, moderate solubility in aromatic chemicals, and is insoluble in non-polar solvents, exhibiting the physicochemical properties of a thermoplastic polymer with a softening point of 67.0°C (onset 33.0°C, endset 81.5°C).     

Structural state of a radiation-modified Ti50Ni47Fe3 single crystal in the low-temperature range

The structural state of a Ti₅₀Ni₄₇Fe₃ single crystal irradiated by fast neutrons has been investigated using thermal neutron diffraction at a temperature of 78 K. The current interest expressed in this problem is caused by the search for a radiation-resistant material with the shape memory effect. It has been found that the main structural motif of the crystal exposed to irradiation is retained but martensitic transformations are absent. The radiation resistance of crystals of this class has been evaluated.     

Central limit theorem for nonlinear transforms of gaussian random vector fields

We prove a central limit theorem for integral functionals of nonlinear transforms of homogeneous, isotropic Gaussian random vector fields.Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 42, No. 8, pp. 1057–1063, August, 1990.     

Anomalies in resonant absorption line profiles of atoms with large hyperfine splitting

We examine a monochromatic absorption line in the velocity-nonselective excitation of atoms when the components of the hyperfine stricture of the electronic ground states are optically pumped. We show that the absorption lines possess unusual substructures for some values of the hyperfine splitting of the ground state (which exceed the Doppler absorption linewidth severalfold). These substructures in the absorption spectrum are most apparent if the hyperfine structure of the excited electronic state is taken into account. We calculate the absorption spectra of monochromatic light near the D ₁ and D ₂ lines of atomic rubidium ^85,87Rb. With real hyperfine splitting taken into account, the D ₁ and D ₂ lines are modeled by 4-and 6-level diagrams, respectively. Finally, we show that atomic rubidium vapor can be successfully used to observe the spectral features experimentally. Zh. éksp. Teor. Fiz. 111, 93–106 (January 1997)     

Analysis of the coarsening of solid dispersed systems

A method is proposed for computer analysis of the kinetics of coarsening of solid dispersed phases due to the Ostwald ripening of microparticles and its associated processes. The proposed method provides useful information on the occurrence of various processes in a dispersed system as it approaches the equilibrium state. In this method, the similarities and differences between the experimental and theoretical size distributions of microparticles are preliminarily determined by comparing the characteristics of the microparticle size distributions with the corresponding moments. The quality and reliability of identifying the density function of the microparticle size distribution are evaluated from an analysis of the relationships between these characteristics.     

Probe field spectroscopy in two-level systems with arbitrary phase memory in collisions

The spectrum of weak probe field absorption (amplification) by two-level atoms experiencing collisions with buffer gas atoms in a strong resonance laser field is studied theoretically. Analysis is carried out for systems with a weak Doppler broadening under relatively mild constraints on the strong field intensity for the general case of an arbitrary change in the phase of the radiation-induced dipole moment in elastic collisions of gas particles. It is shown that, in spite of uniform broadening of the absorption line, the probe field spectrum exhibits a clearly manifested anisotropy to mutual orientation of the wavevectors of strong and probe radiation. It is found that the width of resonances in the probe field spectrum under definite conditions (that can easily be created in experiments) is proportional to the diffusion coefficient for atoms interacting with radiation. This fact can form the basis of the spectroscopic method for measuring the transport frequencies of collisions between particles absorbing radiation and buffer particles. It is shown that phase memory effects in collisions strongly modify the probe field spectrum both qualitatively and quantitatively. Simple operative formulas proposed for the probe field spectrum are convenient for experimental data processing.