用时间分辨简并四波混频研究液晶相变前行为

我们采用时间分辨简并四波混频研究了MBBA液晶相变前分子取向弛豫时间随温度的变化。实验结果与Landau-de Gennes模型的理论预测基本相符。 关键词：     

EXACT RESULTS FOR A SYMMETRIC 27-VERTEX MODEL

Wu study a symmetric 3-state 27-vertex model and summarize three ways con-tributing to obtaining information of a higher-spin (more-vertex) model in terms of lower-spin (less-vertex) models. We find that this model is equivalent to a symmet-ric 2-state 8-vertex model or an arbitrary 3-state spin models on Kagome lattice in different eases. And 21 exact critical lines and a multicritical point (add something that I cannot recognize) are obtained in ten-dimensional weight space.     

Novel One-step Preparation of Functional Ionic Liquids Using Epoxides as Alkylation Reagents

Owing to their unique chemical and physical properties, ionic liquids (ILs) have received focus attention for application as solvent alternatives. ILs can be used in place of organic solvents in synthesis, catalysis, electrochem istry and liquid/liquid extractions. The commonly reported ILs have relied on pyridinium or imidazolium cations bearing simple alkyl groups.     

Na6In4[P7O24(OH)5]·4H2O的水热合成与表征

具有开放骨架结构的金属酸盐在作为微孔材料、非线性光学材料、催化剂载体和离子交换剂等方面具有应用前景 [1] .自从报道第一个具有微孔结构的磷酸铝 [2 ]以来 ,许多其它具有开放骨架结构的金属磷酸盐被合成出来 ,它们的性质和潜在的应用研究也备受关注 [3～ 8] .本文采用温和条件下的水热法 ,合成得到了具有螺旋链状结构的磷酸铟钠盐 [Na6 In4 [P7O2 4 ( OH) 5]· 4H2 O,并采用 X射线单晶衍射方法进行结构测定 ,其结构中包含了共顶角的多面体连接成的螺旋链 ,链间的连接形成多面体四元环和八元环 ,3个四元环围成了一个三配位氧为中心…     

两步液液萃取-固相萃取净化结合高效液相色谱-串联质谱法测定猪肉中11种磺胺类兽药残留

建立了猪肉中11种常见的磺胺类兽药残留的两步液液萃取-固相萃取净化-高效液相色谱-串联质谱（LC-MS/MS）检测方法。猪肉样品经乙酸乙酯（含2%（v/v）甲酸）及丙酮分两步液液萃取，正己烷脱脂，Oasis MCX混合阳离子固相萃取小柱净化，氮吹浓缩，定容，过滤膜后进行高效液相色谱-串联质谱分析。采用多反应监测正离子模式进行检测，以基质校准曲线外标法定量。结果表明，在20~400 μg/L范围内11种磺胺类药物均呈现良好的线性关系（相关系数（r²）≥ 0.99），检出限（LODs）（S/N=3）和定量限（LOQs）（S/N=10）分别为0.1~1.0 μg/kg和0.2~3.0 μg/kg。对阴性猪肉样品，在50、100、200 μg/kg 3个水平下分别进行加标回收试验，测得各待测物的平均回收率为79.3%~105.5%之间，相对标准偏差为1.3%~11.6%（n=6）。该方法比采用一步液液萃取法具有更高的提取效率，同时结合固相萃取净化方法进一步富集目标化合物，降低了基质干扰，提高了检测灵敏度。     

L-S coupling and the magnetic moment of6Li from three-body models

Recently, the shell structure of⁶Li was calculated from three-body models (pn) where the only input is the required nucleon-nucleon and alpha-nucleon interactions. There it was learned, within the framework ofj-j coupling for the two valence nucleons with their coordinate's origin on the alpha particle, that orbitals beyond thep-shell, e.g. thes-d shell, play a significant role in the structure of⁶Li. In the present work, we extend these calculations to thef-shell. Thef-shell orbital probabilities add 4% to the normalization, thus bring all the models to within 3–5% of complete convergence. We then use thej-j coupling orbital amplitudes up to thef-shell to construct the corresponding amplitudes forL-S coupling. We find theL-S orbital probabilities, and compare them with theL-S component probabilities calculated directly by recoupling the three-body wave function from its natural Jacobi-coordinate form. The⁶Li magnetic moment is determined from the directL-S probabilities. The most realistic models yield magnetic moments about 2.5% higher than experiment.     

手性噁唑硼烷结构与还原苯基乙基甲酮的对映选择性研究~≠

本文以苯基乙基甲酮为还原底物,研究了原地(in situ)制备的在3、4、5位具有不同取代基的手性1,3,2-(口恶)唑硼烷催化剂的结构与不对称催化效应关系。研究结果表明,在不对称催化硼烷还原反应中(CBS方法),产物的构型和对映选择性主要受手性(口恶)唑硼烷的4位取代基控制。