全文获取类型
收费全文 | 3330篇 |
免费 | 79篇 |
国内免费 | 22篇 |
专业分类
化学 | 2080篇 |
晶体学 | 11篇 |
力学 | 145篇 |
数学 | 495篇 |
物理学 | 700篇 |
出版年
2024年 | 4篇 |
2023年 | 35篇 |
2022年 | 78篇 |
2021年 | 115篇 |
2020年 | 101篇 |
2019年 | 80篇 |
2018年 | 58篇 |
2017年 | 45篇 |
2016年 | 129篇 |
2015年 | 92篇 |
2014年 | 136篇 |
2013年 | 170篇 |
2012年 | 223篇 |
2011年 | 254篇 |
2010年 | 144篇 |
2009年 | 125篇 |
2008年 | 199篇 |
2007年 | 194篇 |
2006年 | 212篇 |
2005年 | 195篇 |
2004年 | 148篇 |
2003年 | 128篇 |
2002年 | 127篇 |
2001年 | 53篇 |
2000年 | 23篇 |
1999年 | 30篇 |
1998年 | 32篇 |
1997年 | 38篇 |
1996年 | 36篇 |
1995年 | 21篇 |
1994年 | 22篇 |
1993年 | 17篇 |
1992年 | 7篇 |
1991年 | 15篇 |
1990年 | 9篇 |
1989年 | 9篇 |
1988年 | 12篇 |
1987年 | 9篇 |
1986年 | 11篇 |
1985年 | 9篇 |
1984年 | 10篇 |
1983年 | 9篇 |
1982年 | 12篇 |
1981年 | 15篇 |
1980年 | 7篇 |
1979年 | 10篇 |
1978年 | 5篇 |
1977年 | 4篇 |
1976年 | 2篇 |
1975年 | 9篇 |
排序方式: 共有3431条查询结果,搜索用时 11 毫秒
91.
Denote by γ the Gauss measure on ℝ
n
and by ${\mathcal{L}}${\mathcal{L}} the Ornstein–Uhlenbeck operator. In this paper we introduce a Hardy space
\mathfrakh1g{{\mathfrak{h}}^1}{{\rm \gamma}} of Goldberg type and show that for each u in ℝ ∖ {0} and r > 0 the operator (rI+L)iu(r{\mathcal{I}}+{\mathcal{L}})^{iu} is unbounded from
\mathfrakh1g{{\mathfrak{h}}^1}{{\rm \gamma}} to L
1γ. This result is in sharp contrast both with the fact that (rI+L)iu(r{\mathcal{I}}+{\mathcal{L}})^{iu} is bounded from H
1γ to L
1γ, where H
1γ denotes the Hardy type space introduced in Mauceri and Meda (J Funct Anal 252:278–313, 2007), and with the fact that in the Euclidean case (rI-D)iu(r{\mathcal{I}}-\Delta)^{iu} is bounded from the Goldberg space
\mathfrakh1\mathbbRn{{\mathfrak{h}}^1}{{\mathbb{R}}^n} to L
1ℝ
n
. We consider also the case of Riemannian manifolds M with Riemannian measure μ. We prove that, under certain geometric assumptions on M, an operator T{\mathcal{T}}, bounded on L
2
μ, and with a kernel satisfying certain analytic assumptions, is bounded from H
1
μ to L
1
μ if and only if it is bounded from
\mathfrakh1m{{\mathfrak{h}}^1}{\mu} to L
1
μ. Here H
1
μ denotes the Hardy space introduced in Carbonaro et al. (Ann Sc Norm Super Pisa, 2009), and
\mathfrakh1m{{\mathfrak{h}}^1}{\mu} is defined in Section 4, and is equivalent to a space recently introduced by M. Taylor (J Geom Anal 19(1):137–190, 2009). The case of translation invariant operators on homogeneous trees is also considered. 相似文献
92.
Stefano Longhi 《Annalen der Physik》2023,535(11):2300291
Strongly-correlated systems in non-Hermitian models are an emergent area of research. Herein, a non-Hermitian Hubbard model is considered, where the single-particle hopping amplitudes on the lattice are not reciprocal, and provide exact analytical results of the spectral structure in the two-particle sector of Hilbert space under different boundary conditions. The analysis unveils some interesting spectral and dynamical effects of purely non-Hermitian nature and that deviate from the usual scenario found in the single-particle regime. Specifically, a spectral phase transition of the Mott-Hubbard band on the infinite lattice is predicted as the interaction energy is increased above a critical value, from an open to a closed loop in complex energy plane, and the dynamical dissociation of doublons, i.e., instability of two-particle bound states, in the bulk of the lattice, with a sudden revival of the doublon state when the two particles reach the lattice edge. Particle dissociation observed in the bulk of the lattice is a clear manifestation of non-Hermitian dynamics arising from the different lifetimes of single-particle and two-particle states, whereas the sudden revival of the doublon state at the boundaries is a striking burst edge dynamical effect peculiar to non-Hermitian systems with boundary-dependent energy spectra, here predicted for the first time for correlated particles. 相似文献
93.
Journal of Statistical Physics - We characterize the non equilibrium stationary states in two classes of systems where phase transitions are present. We prove that the interface in the limit is a... 相似文献
94.
Dr. Francesco Della Monica Dr. Veronica Paradiso Prof. Dr. Alfonso Grassi Dr. Stefano Milione Prof. Dr. Luigi Cavallo Prof. Dr. Carmine Capacchione 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(24):5347-5353
A new chromium(III) complex, bearing a bis-thioether-diphenolate [OSSO]-type ligand, was found to be an efficient catalyst in the copolymerization of CO2 and epoxides to achieve poly(propylene carbonate), poly(cyclohexene carbonate), poly(hexene carbonate) and poly(styrene carbonate), as well as poly(propylene carbonate)(cyclohexene carbonate) and poly(propylene carbonate)(hexene carbonate) terpolymers. 相似文献
95.
József Fritz Carlangelo Liverani Stefano Olla 《Communications in Mathematical Physics》1997,189(2):481-496
The set of stationary measures of an infinite Hamiltonian system with noise is investigated. The model consists of particles
moving in with bounded velocities and subject to a noise that does not violate the classical laws of conservation, see [OVY]. Following
[LO] we assume that the noise has also a finite radius of interaction, and prove that translation invariant stationary states
of finite specific entropy are reversible with respect to the stochastic component of the evolution. Therefore the results
of [LO] imply that such invariant measures are superpositions of Gibbs states.
Received: 26 September 1996 / Accepted: 3 January 1997 相似文献
96.
Stefano De Leo Waldyr A. Rodrigues Jayme Vaz 《International Journal of Theoretical Physics》1998,37(9):2415-2431
Complex geometry represents a fundamentalingredient in the formulation of the Dirac equation bythe Clifford algebra. The choice of appropriate complexgeometries is strictly related to the geometricinterpretation of the complex imaginary unit
. We discuss two possibilities which appearin the multivector algebra approach: the123 and 21 complexgeometries. Our formalism provides a set of rules which allows an immediate translation between thecomplex standard Dirac theory and its version withingeometric algebra. The problem concerning a doublegeometric interpretation for the complex imaginary unit
is also discussed. 相似文献
97.
The thorny issue of relating information theory to cosmology is here addressed by assuming a possible connection between quantum entanglement measures and observable universe. In particular, we propose a cosmological toy model, where the equation of state of the cosmological fluid, which drives the today observed cosmic acceleration, can be inferred from quantum entanglement between different cosmological epochs. In such a way the dynamical dark energy results as byproduct of quantum entanglement. 相似文献
98.
Francesco Andreatta Alex Lanzutti Stefano Maschio Lorenzo Fedrizzi 《Surface and interface analysis : SIA》2019,51(12):1240-1250
AA8xxx alloys employed in the HVAC&R sector (heating, ventilating, air conditioning, and refrigerating) were investigated to highlight the effect of active surface layers in heat-exchanger fins. The local behavior of the surface and the bulk of the alloy sheets was studied by means of an electrochemical microcell in combination with glow-discharge optical-emission spectrometry. Surface layers strongly enhance the electrochemical activity of the fin material. This is related to the segregation of Mg and other elements (Sn) strongly impairing the protective behavior of the oxide film generated during thermomechanical processing. 相似文献
99.
De Stefano C Milea D Porcino N Sammartano S 《Analytical and bioanalytical chemistry》2006,386(2):346-356
Interactions between myo-inositol 1,2,3,4,5,6-hexakis(dihydrogen phosphate) (phytic acid) and cadmium(II) were studied by using potentiometry (at
25 °C with the ISE-H+ glass electrode) in different metal to ligand (Phy) ratios (1:1≤Cd2+:Phy≤4:1) in NaClaq at different ionic strengths (0.1≤I/mol L−1≤1). Nine CdiHjPhy(12−2i−j)− species are formed with i=1 and 2 and 4≤j≤7; and trinuclear Cd3H4Phy2−. Dependence of complex formation constants on ionic strength was modeled by using Specific ion Interaction Theory (SIT) equations.
Phytate and cadmium speciation are also dependent on the metal to ligand ratio. Stability of CdiHjPhy(12−2i−j)− species was modeled as a function of both the ligand protonation step (j) and the number of metal cations bound to phytate
(i), and relationships found were used for the prediction of species other than those experimentally determined (mainly di-
and tri-protonated complexes), allowing the possibility of modeling Phy and Cd(II) behavior in natural waters and biological
fluids. A critical evaluation of phytate sequestering ability toward cadmium(II) has been made under several experimental
conditions, and the determination of an empirical parameter has been proposed for an objective “quantification” of this ability.
A thorough analysis of literature data on phytate–cadmium(II) complexes has been performed.
Previous contributions to this series: [1–8] 相似文献
100.
Ongoing efforts to model P2Y receptors for extracellular nucleotides, i.e., endogenous ADP, ATP, UDP, UTP, and UDP-glucose, were summarized and correlated for the eight known subtypes. The rhodopsin-based homology modeling of the P2Y receptors is supported by a growing body of site-directed mutagenesis data, mainly for P2Y1 receptors. By comparing molecular models of the P2Y receptors, it was concluded that nucleotide binding could occur in the upper part of the helical bundle, with the ribose moiety accommodated between transmembrane domain (TM) 3 and TM7. The nucleobase was oriented towards TM1, TM2, and TM7, in the direction of the extracellular side of the receptor. The phosphate chain was oriented towards TM6, in the direction of the extracellular loops (ELs), and was coordinated by three critical cationic residues. In particular, in the P2Y1, P2Y2, P2Y4, and P2Y6 receptors the nucleotide ligands had very similar positions. ADP in the P2Y12 receptor was located deeper inside the receptor in comparison to other subtypes, and the uridine moiety of UDP-glucose in the P2Y14 receptor was located even deeper and shifted toward TM7. In general, these findings are in agreement with the proposed binding site of small molecules to other class A GPCRs. 相似文献