A novel hydrophilic nanocomposite additive (PVP-g-MMT), coupling of hydrophilic modifier, self-dispersant, and pore-forming agent (porogen), was synthesized by the surface modification of montmorillonite (MMT) with N-vinylpyrrolidone (NVP) via "grafting from" polymerization in the presence of H(2)O(2)-NH(3)·H(2)O as the initiator, and then the nanocomposite membrane of poly(vinylidene fluoride) (PVDF) and PVP-g-MMT was fabricated by wet phase inversion onto clean glass plates. The existence and dispersion of PVP-g-MMT had a great role on structures, morphologies, surface composition, and chemistry of the as-prepared nanocomposite membranes confirmed by varieties of spectroscopic and microscopic characterization techniques, all of which were the correlated functions of PVP-g-MMT content in casting solution. By using the dead-end filtration of protein aqueous solution, the performance of the membrane was evaluated. It was seen that all of the nanocomposite membranes showed obvious improvement of water flux and proper BSA rejection ratio, compared to the control PVDF membrane. Meanwhile, dynamic BSA fouling resistance and flux recovery properties were also greatly enhanced due to the changes of surface hydrophilicity and morphologies. All the experimental results indicated that the as-prepared PVDF nanocomposite membranes showed better separation performances than the control PVDF membrane. Hopefully, the demonstrated method of hydrophilic nanocomposite additive synthesis would be applied for commonly hydroxyl group-containing inorganic nanoparticles, which was favorable to fabricate hydrophilic nanoparticle-enhanced polymer membranes for water treatment. 相似文献
A new condensed form of the Fukui function, the natural orbital Fukui function (NOFF), is proposed and derived from natural bond orbital occupancy. It is defined as the change in natural bond orbital occupancy upon electronic perturbation (electron addition to, or depletion from, a molecular system). Applying NOFF to a series of cycloaddition reactions (e.g., [4 + 2] and [2 + 1] cycloadditions) illustrates the effectiveness of the concept in interpreting bond breakage and formation mechanisms. 相似文献
Gong et al. (2010) and Xiao et al. (2010) have proposed the notion of bijective soft set and exclusive disjunctive soft set, respectively, which is a subtype of soft set. On the basis of their work, this paper extends these notions to fuzzy environments, and formulates the concept of bijective fuzzy soft set, which can deal with more uncertain problems. Moreover, this paper proposes two parameters reduction algorithms: one (Algorithm 1) is based on bijective fuzzy soft system, and the other (Algorithm 2) takes weight of an element into consideration. Since the threshold plays an important role in these algorithms, we proposed an algorithm (Algorithm 3) to decide the optimal value of threshold specially. Afterwards, an example analysis of the two parameters reduction algorithms is given and the result shows that the two algorithms lead to the same parameters reduction of a bijective fuzzy soft system. Since Algorithm 2 considers the detail weights of elements, thus it can be used in more uncertain problems, such as time series analysis problems, than Algorithm 1. 相似文献
Rhodium‐catalyzed C7‐selective decarbonylative arylation, olefination, and methylation of indoles with carboxylic acids or anhydrides by C?H and C?C bond activation have been developed. Furthermore, C7‐acylation products can also be generated selectively at a lower reaction temperature in the developed system. The key to the high reactivity and regioselectivity of this transformation is the appropriate choice of an indole N‐PtBu2 chelation‐assisted group. This method has many advantages, including easy access and removal of the directing group, the use of cheap and widely available coupling agents, no requirement of an external ligand or oxidant, a broad substrate scope, high efficiency, and the formation of a sole regioisomer. 相似文献
C-doped Nb2O5 with abundant mesopores has been successfully synthesized through a facile solvothermal synthetic strategy followed by calcination treatment. The resulting C-doped Nb2O5 displayed the highest BET surface area(345 m2/g) and large mesopore size(ca. 4.2 nm), capable of offering more accessible active sites as well as faster mass transfer for catalysis. Besides, the doping of C(2.21%, molar fraction) at the O sites in Nb2O5 lattice greatly enhanced visible-light response by lowering the band gap, thereby making the material a photocatalyst under visible-light irradiation. Typically, the C-doped Nb2O5 exhibited a high H2 evolution rate of ca. 39.10 μmol·g-1·h-1 and also degraded RhB dye completely after 30 min of visible light exposure, which turned out to be much better than Degussa P25 and pure Nb2O5 catalysts. 相似文献
A method for Cu(Ⅱ)-catalyzed dehydrogenative amidation of azoarene using air as the terminal oxidant was developed. Various amides, such as arylamides, alkylamides, lactams, and imides, are all effective amidation reagents and provide the desired products in moderate to excellent yields. Notably, good yields can also be obtained on a gram-scale with this amidation reaction.In this protocol of azoarene amidation, the catalyst(Cu(OAc)_2) and oxidant(air) are inexpensive and readily available, and the process is highly efficient and atom economical. 相似文献
China’s rapid development in economy has intensified many problems. One of the most important issues is the problem of environmental pollution. In this paper, a new DEA approach is proposed to measure the environmental efficiency of thermoelectric power plants, considering undesirable outputs. First, we assume that the total amount of undesirable outputs of any particular type is limited and fixed to current levels. In contrast to previous studies, this study requires fixed-sum undesirable outputs. In addition, the common equilibrium efficient frontier is constructed by using different input/output multipliers (or weights) for each different decision making unit (DMU), while previous approaches which considered fixed-sum outputs assumed a common input/output multiplier for all DMUs. The proposed method is applied to measure the environmental efficiencies of 30 thermoelectric power plants in mainland China. Our empirical study shows that half of the plants perform well in terms of environmental efficiency.