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961.
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Abdul Rouf Pankaj Gupta Mushtaq A. Aga Brijesh Kumar Asha Chaubey Rajinder Parshad Subhash C. Taneja 《Tetrahedron: Asymmetry》2012,23(22-23):1615-1623
The synthesis of both enantiomers of 1,4-benzodioxan-2-carboxylic acid 1, a key synthetic intermediate for the therapeutic agents piperoxan, prosympal, dibozane, and doxazosin was achieved with good yields and high enantioselectivities via the Arthrobacter sp. lipase catalyzed kinetic resolution of ester (±)-17a. The influence of the co-solvents and the immobilization of the lipase upon kinetic resolution demonstrated that immobilized whole cells, in the presence of n-butanol as a co-solvent, resulted in the optimal resolution of the substrate (ee ~99%, E = 535) at 258 mmol (50 g/L) substrate concentration. 相似文献
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A novel synthetic method for the synthesis of 1,2,4-triazoles have been described starting from 1,3,4-thiadiazoles by adsorbing on acidic alumina under microwave irradiations (MWI). 相似文献
966.
Baruah Bhargav Kataki Rupam Thakur Parash Tiwari Pankaj 《Journal of Thermal Analysis and Calorimetry》2019,138(2):1221-1232
Journal of Thermal Analysis and Calorimetry - The present work provides a detailed characterization and kinetic study of oil shale of Upper Assam, India. The physicochemical characteristics of oil... 相似文献
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In this paper, the generalized stacking fault (GSF) energies in different slip planes of TiN and MgO are calculated using highly reliable first-principles density functional theory (DFT) calculations. During DFT calculations, the issue of different ways to calculate the GSF energetics in ceramic materials containing more than one element was addressed and applied. For 〈1?1?0〉/{1?1?1} slip, a splitting of saddle point in TiN was observed. For 〈1?1?2〉/{1?1?1} slip, a stable stacking fault at a0/3〈1?1?2〉 displacement was formed in TiN. For synchroshear mechanism where the slip was accompanied by a cooperative motion of the interfacial nitrogen atoms within the slip plane, a second stable stacking fault was formed at a0/6〈1?1?2〉 displacement. The energy barrier for the shuffling of nitrogen atoms from one state to another is calculated to be 0.70 eV per atom. In contrast, such features are absent in MgO. These differences highlight the influence of complex bonding nature (mixed covalent, ionic, and metallic bondings) of TiN, which is substantially different than that in MgO (simple ionic bonding) on GSF shapes. 相似文献
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Building on our earlier work (Misra and Shukla, Nucl. Phys. B 827:112, 2010; Phys. Lett. B 685:347–352, 2010), we show the possibility of generating “light” fermion mass scales of MeV–GeV range (possibly related to the first two generations
of quarks/leptons) as well as eV (possibly related to first two generations of neutrinos) in type IIB string theory compactified
on Swiss-Cheese orientifolds in the presence of a mobile space-time filling D3-brane restricted to (in principle) stacks of fluxed D7-branes wrapping the “big” divisor Σ
B
. This part of the paper is an expanded version of the latter half of Sect. 3 of a published short invited review (Misra,
Mod. Phys. Lett. A 26:1, 2011) written by one of the authors [AM]. Further, we also show that there are no SUSY GUT-type dimension-five operators corresponding
to proton decay, and we estimate the proton lifetime from a SUSY GUT-type four-fermion dimension-six operator to be 1061 years. Based on GLSM calculations in (Misra and Shukla, Nucl. Phys. B 827:112, 2010) for obtaining the geometric K?hler potential for the “big divisor,” using further the Donaldson’s algorithm, we also briefly
discuss in the first of the two appendices the metric for the Swiss-Cheese Calabi–Yau used, which we obtain and which becomes
Ricci flat in the large-volume limit. 相似文献
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