Synthesis of the insecticidal 1′-acetoxy-mammeins and surangin b

Methods are examined for the synthesis of 4-(1′-acetoxy) alkylcoumarins having hexasubstituted aromatic rings. This has led to synthesis of the three insecticidal coumarins mammea E/BB, mammea E/BA and surangin B.     

A new type of edge-derived vertex coloring

We study the minimum number of weights assigned to the edges of a graph G with no component K₂ so that any two adjacent vertices have distinct sets of weights on their incident edges. The best possible upper bound on this parameter is proved.     

Identifying defective sets using queries of small size

We examine the following version of a classic combinatorial search problem introduced by Rényi: Given a finite set $X$ of $n$ elements we want to identify an unknown subset $Y$ of $X$, which is known to have exactly $d$ elements, by means of testing, for as few as possible subsets $A$ of $X$, whether $A$ intersects $Y$ or not. We are primarily concerned with the non-adaptive model, where the family of test sets is specified in advance, in the case where each test set is of size at most some given natural number $k$. Our main results are nearly tight bounds on the minimum number of tests necessary when $d$ and $k$ are fixed and $n$ is large enough.     

Search for massive photon pair production at the CERN intersecting storage rings

A search for massive photon pair production at \(\sqrt s = 63 GeV\) has been carried out on the data sample previously employed for the electron pair production study. Positive evidence is reported form _γγ>6GeV, with a production cross-section similar to Drell-Yan electron pairs. The ratio γγ/π⁰π⁰ was measured to be ～10^?3 for ap _T of each γ or γ or π⁰ above 3 GeV/c.     

Conformational effects on the performance and selectivity of a polymeric pseudostationary phase in electrokinetic chromatography

The effect of the conformation of a polymeric pseudostationary phase on performance and selectivity in electrokinetic chromatography was studied using an amphiphilic pH-responsive polymer that forms compact intramolecular aggregates (unimer micelles) at low pH and a more open conformation at high pH. The change in conformation was found to affect the electrophoretic mobility, retention, selectivity, and separation efficiency. The low-pH conformer has higher electrophoretic mobility and greater affinity for most solutes. The unimer micelle conformation was also found to provide a solvation environment more like that of micelles and other amphiphilic self-associative polymers studied previously. It was not possible to fully characterize the effect of conformation on efficiency, but very hydrophobic solutes with long alkyl chains appeared to migrate with better efficiency when the unimer micelle conformation was employed. The results imply that polymers with a carefully optimized lipophilic-hydrophilic balance that allow self-association will perform better as pseudostationary phases. In addition, the results show that electrokinetic chromatography is a useful method for determining the changes in solvation environment provided by stimuli-responsive polymers with changes in the conditions.