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171.
Paul W. Percival Kim M. Adamson-Sharpe Jean-Claude Brodovitch Siu-Keung Leung Kenneth E. Newman 《Chemical physics》1985,95(2):321-330
Muon spin precession signals arising from both muonium and a diamagnetic muon species have been studied in single crystal of ice over the temperature range 90–263 K. Conversion of initial signal amplitudes to fractions of muon polarization reveals that for temperatures above 200 K part of the original muon polarization is unaccounted for. Such a missing fraction is well known for liquid water. but was not found in earlier work on polycrystalline ice. Muonium signals in Polycrystalline ice were reanalyzed using a non-exponential decay function appropriate to the powder pattern spectrum. Smaller muonium fractions were found. consistent with those determined for single crystall, thus confirming the existence of the missing fraction. The origin of the missing fraction is discussed, and it is proposed that non-reactive spin exchange encounters between muonium and hydrogen atoms may be the cause. 相似文献
172.
The reflectivity of picosecond pulses from a Nd: glass laser on Ge has been measured. A marked increase (∽ 20%) has been found at excitation intensities just below the damage threshold. The effect is discussed in terms of the contribution to the dielectric constant of the crystal, arising from direct intraband transitions within the branches of the valence band. The relevance of these transitions to explain the “plateau” observed in the transmission experiment, is also briefly pointed out. 相似文献
173.
A.Y.-T. Leung 《Journal of sound and vibration》1980,72(4):451-467
The natural vibration analysis of a periodic structure with repeated identical substructures may be simplified by using some symmetrical properties of the substructure dynamic matrices, resulting in a set of linear difference equations in the displacements. These equations are readily solved for cyclic symmetric systems, simply supported systems and infinite systems. The order of the overall frequency equations is at most equal to one half of the total number of degrees of freedom retained for a single substructure regardless of the number of substructures in the system. With these natural modes, the system with general boundary conditions at end stations is analyzed by a fast converging method. 相似文献
174.
Guangdong Province of China is the highest incidence place of naso-pharyngeal cancer in the world. The concentrations of 19 trace elements in hair of 90 naso-pharyngeal cancer patients in Guangdong Province have been measured by the PIXE technique. By using the Maximum Probable Discrimination Method to distinguish naso-pharyngeal cancer patients from healthy people, we get up to 91.1% validity of differential diagnosis and get some indication that special trace elements participate in carcinogenesis. 相似文献
175.
States with private correlations but little or no distillable entanglement were recently reported. Here, we consider the secure distribution of such states, i.e., the situation when an adversary gives two parties such states and they have to verify privacy. We present a protocol which enables the parties to extract from such untrusted states an arbitrarily long and secure key, even though the amount of distillable entanglement of the untrusted states can be arbitrarily small. 相似文献
176.
We investigate the liquid structure, ion hydration, and some thermodynamic properties associated with the rigid geometry approximation to water by applying ab initio molecular dynamics simulations (AIMD) with the Perdew-Burke-Ernzerhof (PBE) exchange-correlation functional at T = 320 K. We vary the rigid water geometry in order to locate a class of practical water models that yield reasonable liquid structure and dynamics, and to examine the progression of AIMD-predicted water behavior as the OH bond length varies. Water constrained at the optimal PBE gas phase geometry yields reasonable pair correlation functions. The predicted liquid phase pressure, however, is large ( approximately 8.0 kbar). Although the O-H bond in water should elongate when transferred from gas to the condensed phase, when it is constrained to 0.02, or even just 0.01 A longer than the optimal gas phase value, liquid water is predicted to be substantially overstructured compared to experiments. Zero temperature calculations of the thermodynamic properties of cubic ice underscore the sensitivity toward small variations in the O-H bond length. We examine the hydration structures of potassium, chloride, and formate ions in one rigid PBE water model. The results are in reasonable agreement with unconstrained AIMD simulations. 相似文献
177.
[Structure: see text] The versatility of supramolecular chemistry has been exploited in constructing nanovalves based on mesoporous silica MCM-41 and the mutual recognition between secondary dialkylammonium ions and dibenzo[24]crown-8 (DB24C8). Naphthalene-containing dialkylammonium threads were tethered to the MCM-41, followed by loading with coumarin 460 and capping with DB24C8. Controlled release of coumarin 460 from the pores of MCM-41 was demonstrated using different bases. The rate of release of coumarin 460 from the nanovalves depends on the size of the base. 相似文献
178.
C. W. Chen L. S. Liao H.-P. Chiang P. T. Leung 《Applied physics. B, Lasers and optics》2010,99(1-2):223-227
The effects of temperature variation on the electric polarizability of mesoscopic metallic nanoparticles is studied via a theoretical model in which the temperature dependence of the electron–phonon and electron–electron scattering rates are taken into account. Furthermore, the nonlocal response of the metal, which is significant for particles of mesoscopic dimensions, is also included. It is found that the significance of the nonlocal effects can be very different with different metals, for the same smallness in size of the nanoparticles. In addition, while the imaginary part of the polarizability in general increases with temperature, the real part can both decrease or increase as temperature rises—in contrast to the case with the static polarizability of atomic clusters, which most of the time increases with temperature. 相似文献
179.
The room-temperature adsorption and thermal evolution of allylamine on Si(100)2 × 1 have been investigated by using temperature-dependent X-ray photoelectron spectroscopy (XPS) and thermal desorption spectrometry (TDS). The presence of a broad N 1 s feature at 398.9 eV, attributed to a N―Si bond, indicates N―H dissociative adsorption. On the other hand, the presence of C 1 s features at 284.6 eV and 286.2 eV, corresponding to C═C and C―N, respectively, and the absence of the Si―C feature expected at 283.2 eV shows that [2 + 2] C═C cycloaddition does not occur at room temperature. These XPS data are consistent with the unidentate staggered and eclipsed allylamine conformer adstructures arising from N―H dissociation and not [2 + 2] C═C cycloaddition. The apparent conversion of the N 1 s feature for Si―N(H)―C at 398.9 eV to that for Si―N(H) at 397.7 eV and the total depletion of C 1 s feature for C―N at 286.2 eV near 740 K indicates cleavage of the C―N bond, leaving behind a Si―N(H) radical. Furthermore, the C═C C 1 s feature at 284.6 eV undergoes steep intensity reduction between 740 K and 825 K, above which a new C 1 s feature at 283.2 eV corresponding to SiC is found to emerge. These spectral changes suggest total dissociation of the ethenyl fragment and the formation of SiC. Moreover, while the total N 1 s intensity undergoes a minor reduction (24%) upon annealing up to 1090 K, a considerable reduction (43%) is found in the overall C 1 s intensity. This observation is consistent with our TDS data, which shows the desorption of C-containing molecules including propene and ethylene at 580 K and of acetylene at 700 K. The lack of N-containing desorbates suggests that the dissociated N species are likely bonded to multiple surface Si atoms or diffused into the bulk. Interestingly, both the staggered and eclipsed N―H dissociative adstructures are found to have a less negative adsorption energy than the [N, C, C] tridentate or the [2 + 2] C═C cycloaddition adstructures by our DFT calculations, which suggests that the observed formation of N―H dissociative adstructures is kinetically favored on the Si(100)2 × 1 surface. 相似文献
180.
Xiangshun Kong Mingyao Ai Kwok Leung Tsui 《Annals of the Institute of Statistical Mathematics》2018,70(3):631-646
Sliced Latin hypercube designs are popularly adopted for computer experiments with qualitative factors. Previous constructions require the sizes of different slices to be identical. Here we construct sliced designs with flexible sizes of slices. Besides achieving desirable one-dimensional uniformity, flexible sliced designs (FSDs) constructed in this paper accommodate arbitrary sizes for different slices and cover ordinary sliced Latin hypercube designs as special cases. The sampling properties of FSDs are derived and a central limit theorem is established. It shows that any linear combination of the sample means from different models on slices follows an asymptotic normal distribution. Some simulations compare FSDs with other sliced designs in collective evaluations of multiple computer models. 相似文献