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11.
Xiao Chi Ma Bao Jing Zhang Sha Deng Shan Shan Huang Ke Xin Liu Jing Ming Jia 《中国化学快报》2009,20(3):317-319
A new ent-labdane diterpenoid lactone with a new natural product was isolated from Andrographis paniculata. Their structures were elucidated on the basis of spectral evidences including 2D NMR. 相似文献
12.
E. F. Schwier C. Monney N. Mariotti Z. Vydrovà M. García-Fernández C. Didiot M. G. Garnier P. Aebi 《The European Physical Journal B - Condensed Matter and Complex Systems》2011,81(4):399-403
We explore the interplay between the elastic scattering of photoelectrons and the surface core level shifts with regard to
the determination of core level binding energies in Au(111) and Cu3Au(100). We find that an artificial shift is created in the binding energies of the Au 4f core levels, that exhibits a dependence on the emission angle, as well as on the spectral intensity of the core level emission
itself. Using a simple model, we are able to reproduce the angular dependence of the shift and relate it to the anisotropy
in the electron emission from the bulk layers. Our results demonstrate that interpretation of variation of the binding energy
of core-levels should be conducted
with great care and must take into account the possible influence of artificial shifts induced by elastic scattering. 相似文献
13.
René Garnier 《Annali di Matematica Pura ed Applicata》1962,58(1):1-34
Résumé Soit Γ un quadrilatère variable, dont deux c?tés opposés A2A3, A1A4 sont dans les plans x3=c, x3=−c. Quand c tend vers0, Γ tend vers un quadrilatèreΓ
0 présentant un point double, A0. Le travail étudie la représentation conforme sur le demi-plan R(ix)<0 (ou sur le cercle - unité) de la surface minimale
∑ passant par Γ. Il montre (§ I) que si les affixes x de A1, A2, A4 sont 0, 1, ∞, l'affixe de A3 sera ɛ−2, où ɛ tend vers 0 avec c. Il étudie (§ II) l'allure pour ɛ tendant vers 0 des intégrales canoniques de l'équation linéaire
du problème. La forme de la relation entre ɛ et c est indiquée au no 19; on montre que dans la région de striction ɛ |x| reste borné et que la surface ∑ y est assimilable à une surface minimale
simple: la surface de vis à filet carré. La représentation conforme de l'une des deux régions de ∑ qui tendent à se séparer
l'une de l'autre tend à envahir tout le demi-plan (ou tout le cercle-unité). Les représentations conformes de ∑ pour c>0 et
c<0 ne sont pas analytiquement distinctes (n0 20). A titre d'exemple, on étudie (n0 21) le cas où ∑ possède un axe de symétrie.
A M. Enrico Bompiani pour son Jubilé scientifique 相似文献
14.
15.
We present new results for the time reversal of weakly nonlinear pulses traveling in a random dissipative environment. Also we describe a new theory for calculating the eddy viscosity for weakly nonlinear waves propagating over a random surface. The turbulent viscosity is calculated from first principles, namely, without imposing any stress-strain hypothesis. A viscous shallow water model is considered and its effective viscosity characterized. We also show that weakly nonlinear waves can still be time reversed under weak dissipation. Incoherently scattered signals are recompressed, both for time reversal in transmission as well as in reflection. Under the weakly nonlinear, weakly dissipative regime, dissipation only affects the refocused pulse profile regarding its amplitude, but its shape is not corrupted. Numerical experiments are presented. 相似文献
16.
We have performed a series of measurements to study the low temperature dynamics of an interacting magnetic nanoparticle system. The results obtained demonstrate striking memory effects in the dc magnetization and magnetic relaxation that support the existence of a spin-glass-like phase in interacting magnetic nanoparticles. Moreover, we observe an asymmetric response with respect to temperature change that supports a hierarchical picture, rather than the droplet model discussed in other works on nanoparticle systems. 相似文献
17.
Gamblin DP Garnier P Ward SJ Oldham NJ Fairbanks AJ Davis BG 《Organic & biomolecular chemistry》2003,1(21):3642-3644
Controlled site-selective glycosylation can be achieved by combining site-directed cysteine mutagenesis with chemical modification of the introduced thiol; a new class of more efficient chemoselective reagents, glycosyl phenylthiosulfonates, allow rapid glycosylations of representative simple thiols, peptides and proteins. 相似文献
18.
R.J. Panlener R.N. Blumenthal J.E. Garnier 《Journal of Physics and Chemistry of Solids》1975,36(11):1213-1222
Thermogravimetric measurements were performed on nonstoichiometric CeO2?x in the temperature range 750–1500°C and from oxygen pressures of 10?2 to 10?26 atm. From this data the deviation from stoichiometry x = x(T, Po2) was determined. The thermodynamic quantities Δo2 and Δo2 were calculated in the region 0.001? x ? 0.3 and found to be independent of temperature.In the composition region 0.001< x < 0.006, the variation of Δo2 with x is consistent with a defect model involving randomly distributed doubly ionized oxygen vacancies. The experimental dependence of x and σ (electrical conductivity) is shown to be consistent with this model as Δo2 (≈ -10 eV) exhibits a slight dependence on x. It is postulated that the variation in Δo2 may result from lattice parameter increases with x, while the defects remain essentially randomly distributed.In the composition region 0.006 < x < 0.1, x ∝ with 1 < n < 5, and in the region 0.1 < x < 0.3, x ∝ with n increasing rapidly with x to n? 30. This behavior is believed to result from increasing defect interaction with increasing departures from stoichiometry. It is interesting to note that the ordered phase observed by Bevan and Kordis between CeO1·72 and CeO1·70 was not observed in this study at temperatures between 1300° and 1500°C. 相似文献
19.
Poly(trimethylene terephthalate)(PTT) is an excellent fiber material.Its thermal degradation and isothermal crystalline behaviors were in this study investigated using thermogravimetric analysis(TGA),thermogravimetric analysis-Fourier transform infrared spectroscopy(TGA-FTIR) analysis,differential scanning calorimetry(DSC) and X-ray diffraction(XRD).The thermal degradation mechanism of PTT follows Mclafferty rearrangement principle.The PTTwithintrinsicviscosity(Ⅳ) of 0.74 dL/g has a maximum crystallinity... 相似文献
20.
The interaction of dissolved organic matter (DOM) with copper and zinc in a concentrated seawater sample was characterised by pseudopolarography. Measurements performed at increased concentrations of copper(II) ions showed successive saturation of active DOM sites which indicate possible partition of copper between (i) free or labile complexes, (ii) reduced and released within the potential window of the method, and (iii) electroinactive copper complexes. Pseudopolarograms measured at pH 4 indicate a release of copper which was bound to the active sites of DOM that formed non-labile complexes. Variation of the peak position and half-peak width along the scanned deposition potentials and with the increasing concentration of copper bear the information about the complex electrochemical processes at the electrode surface and in the bulk of the solution. Pseudopolarograms of zinc showed a strong dependence of the peak current and the peak position along the scanned deposition potentials on pH values, indicating preferentially complexation of zinc with carboxylic-like active sites of DOM in the measured sample. Pseudopolarography is a valuable method in the trace metal complexation and speciation studies, serving as a fingerprint of the analysed sample. 相似文献