Sol-Gel Method for Preparation of LiLaNiO/γ-Al_2O_3 Catalyst over Monoliths used in POM Reaction

Partial oxidation of methane (POM) has several advantages over the traditional industrial method of steam reforming, such as much higher space velocity, reduced capital and operation cost and optimized the ratio of the products (H2/CO). Many investigators are interested in the POM reaction over monolith now1-3. Monolith is a kind of ceramic-like metal oxide material. It has relative high surface to volume ratio compared to commercial pellets, low pressure drop during the reaction process2,…     

An efficient synthesis of N-methyl amino acids by way of intermediate 5-oxazolidinones

N-Methyl amino acids occur in many natural products. Experimental strategies are presented for a unified approach to the synthesis of N-methyl derivatives through 5-oxazolidinones of the 20 common l-amino acids. The amino acids with reactive side chains that required protecting groups or devoted syntheses for side chain construction for N-methylation to proceed included serine, threonine, tyrosine, cysteine, methionine, tryptophan, asparagine, histidine, and arginine. The studies have provided improved methods for the preparation of N-methyl serine, threonine, and tyrosine. All 20 of the common l-amino acids are now available in suitable forms for solid or solution-phase peptide synthesis.     

羧甲基交联魔芋葡甘聚糖微球的制备与表征

采用交联魔芋葡甘聚糖颗粒(CKGG)合成了羧甲基交联魔芋葡甘聚糖微球(CMCKGG)，讨论了羧甲基化过程中的影响因素．用正交设计的方法确定了具有较好交换容量的CMCKGG制备奈件．当碱用量为CKGG量的20％，氯乙酸钠用量为CKGG量的10倍，温度55℃，反应时间8h时，制得的CMCKGG阳离子交换容量为0．7389mmol／g．红外光谱．光学显微镜和扫描电镜的结果表明，该颗粒为蜂窝状多孔微球，粒度均匀．     

Structure-Lipophilicity Relationships of Neutral and Protonated β-Blockers,Part I,Intra- and Intermolecular Effects in Isotropic Solvent Systems

The objectives of this study were to validate new experimental techniques used to measure the log P of protonated drugs, and to investigate the inter- and intramolecular forces influencing the partitioning behavior of β-blockers in isotropic biphasic solvent systems. The lipophilicity parameters of a number of β-blockers were measured by two-phase titration, centrifugal partition chromatography (CPC), and cyclic voltammetry (CV) in one or more of the following solvent systems: octanol/water, 1,2-dichloroethane/water, and dibutyl ether/water. CV proved to be a promising technique for measuring the lipophilicity of protonated β-blockers. Derived parameters such as Δlog P (difference between log P in two different solvent systems, a parameter valid for a given solute in a given electrical form) and diff (difference between log P of two different electrical forms of a given solute, in the same system) yielded insights into inter- and intramolecular interactions characteristic of β-blockers. The relevance of these parameters in structure-permeation relationships is explored.     

一台小型强流脉冲离子束加速器

 介绍了一台小型强流脉冲离子束加速器的结构组成,采用箍缩反射型离子二极管,可以稳定工作的峰值电压为200kV,得到了峰值为1.5kA、脉宽约20ns的离子束流,平均离子流密度110A/cm²。     

毛细管放电复合X光激光机制的理论研究

 以毛细管放电泵浦产生的C等离子体中,复合机制产生类H-C离子3d_5/2-2p_3/2跃迁激光线为例,研究毛细管放电复合X光激光中的物理机制。提出在C气中掺入适量的惰气来抑制等离子体被压得过细以至密度过高;在设计实验方案时 ,应该使等离子体在电流峰值之后进入膨胀冷却阶段;还要适当降低毛细管中等离子体初始 密度以增大毛细管半径,使工艺上更容易实现。     

高能闪光照相X射线能谱的理论研究

 用Monte-Carlo方法模拟球对称客体系统的闪光照相中X光光子的输运过程。分别在单客体情况和全系统情况下,给出了记录平面上各种光子谱及其在记录平面上的空间分布。结果表明：记录区边缘的谱形与源光子谱形很相似;深穿透区各点之间的谱形差别不大,谱平均光子能量近似相同,并且位于使高Z材料的光子线吸收系数最小的能量范围内。 结果还表明,高能闪光照相的光子能谱会因客体中光子的光程不同而有较大的差别。     

光学速调管磁场测量和磁场误差分析

 给出了储存环光学速调管磁场的测量结果,包括轴向分布、横向分布均匀度以及积分场分布;分析了磁场分布的随机误差和系统误差,计算了积分多极场的大小; 讨论了非零积分场引起的闭轨畸变和对储存环工作点的影响。     

碘密度对COIL激光频率的影响

 假设处于碘原子同一电子能级的不同超精细子能级上的粒子处于热平衡状态,推导了化学氧碘激光器（COIL）中增益系数在饱和状态附近的表达式,分析了稳定激光振荡谱线的中心频率随碘密度变化的定性规律。     

闪光－I加速器的预脉冲电压研究

分析了闪光－Ｉ的预脉冲电压和降低预脉冲电压的效果,采用容性电压探测器实现了对阴阳极之间预脉冲电压的测量。在比较实测波形和预计波形后,提出了改进的等效电路模型,并指出了Ｂｌｕｍｌｅｉｎ中筒与二极管之间耦合电容的影响,提出了进一步降低预脉冲电压的途径。